Abstract
Optical emission spectra of Rydberg-excited , , , and , in the range 200–400 nm, are investigated theoretically and compared with the experimental findings of Bruckmeier et al. [Phys. Rev. Lett. 72, 2550 (1994)]. The time-dependent wave packet method combined with the vibronic coupling theory for ( ) Jahn-Teller systems is utilized in order to calculate the corresponding Franck-Condon emission profiles from the upper electronic state to the degenerate ground electronic manifold of those species. We obtain bimodal spectra with two maxima apart in good agreement with the experimental result.
- Received 8 April 1998
DOI:https://doi.org/10.1103/PhysRevLett.81.3116
©1998 American Physical Society