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X-ray diffraction study of multicomponent oxides in the Zn2 − x (Ti a Zr b )1 − x Fe2x O4 system

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Abstract

The multicomponent refractory oxide system Zn2 − x (Ti a Zr b )1 − x Fe2x O4 (a + b = 1; a: b = 1: 5, 1: 4, 1: 3, 1: 2, 1: 1, 2: 1, 3: 1, 4: 1; x = 0–1.0; Δx = 0.05) has been studied by X-ray diffraction, using samples prepared by melting appropriate metal oxide mixtures in a low-temperature hydrogen-oxygen plasma. Two phases, both with wide homogeneity ranges, have been identified: α-phase, with a cubic inverse spinel structure, and β-phase, with a tetragonal inverse spinel structure. The phase boundaries in the system have been determined. Structural data are presented for about 100 solid solutions.

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Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Institutskaya ul. 8, Chernogolovka, Noginskii raion, Moscow oblast, 142432, Russia

    R. A. Grigoryan

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, pr. Akademika Semenova 1, Chernogolovka, Noginskii raion, Moscow oblast, 142432, Russia

    L. A. Grigoryan

Authors
  1. R. A. Grigoryan
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  2. L. A. Grigoryan
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Correspondence to R. A. Grigoryan.

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Original Russian Text © R.A. Grigoryan, L.A. Grigoryan, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 3, pp. 368–374.

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Grigoryan, R.A., Grigoryan, L.A. X-ray diffraction study of multicomponent oxides in the Zn2 − x (Ti a Zr b )1 − x Fe2x O4 system. Inorg Mater 47, 317–323 (2011). https://doi.org/10.1134/S0020168511030101

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  • DOI: https://doi.org/10.1134/S0020168511030101

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