Abstract
The distribution of the acid-base centers on the surface of α-Al2O3 suspension particles was studied by potentiometric titration, and the corresponding pK spectra were constructed. It was inferred that the double electric layer created by the supporting electrolyte substantially affected the screening of the acid-base centers on the particle surface of the suspension.
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References
K. Tanabe, New Solid Acids and Bases (Elsevier, Amsterdam, 1989; Mir, Moscow, 1973).
A. P. Nechiporenko, T. A. Burenina, and S. I. Kol’tsov, Zh. Obshch. Khim. 55, 1907 (1985).
M. A. Ryazanov, Zh. Fiz. Khim. 82, 1999 (2008) [Russ. J. Phys. Chem. A 82, 1794 (2008)].
D. N. Hunston, Anal. Biochem. 63, 99 (1975).
A. K. Thakur, P. J. Munson, D. N. Hunston, and D. Rodbard, Anal. Biochem. 103, 240 (1980).
A. V. Garmash and O. N. Vorob’eva, Zh. Anal. Khim. 53, 258 (1998) [J. Anal. Chem. 53, 228 (1998)].
M. A. Ryazanov and B. N. Dudkin, Kolloidn. Zh. 65, 831 (2003) [Colloid. J. 65, 761 (2003)].
M. A. Ryazanov and B. N. Dudkin, Kolloidn. Zh. 66, 807 (2004) [Colloid. J. 66, 726 (2004)].
R. O. James and G. A. Parks, “Characterization of Aqueous Colloids by Their Electrical Double-Layer and Intrinsic Surface Chemical Properties,” in Surface and Colloid Science, Ed. by E. Mattijevic (Plenum, New York, London, 1982), Vol. 12, p. 119.
Ch. P. Huang and W. Stumm, J. Colloid Interf. Sci. 43, 409 (1973).
A. E. Kuchek and E. V. Gribanova, Zh. Fiz. Khim. 81, 462 (2007) [Russ. J. Phys. Chem. A 81, 387 (2007)].
E. Yu. Nevskaya, I. G. Gorichev, O. V. Kuchkovskaya, et al., Zh. Fiz. Khim. 73, 1585 (1999) [Russ. J. Phys. Chem. A 73, 1421 (1999)].
H. A. C. McKay, J. Inorg. Nucl. Chem. 36, 1767 (1964).
C. Lawson and R. Hanson, Solving Least Squares Problems (Nauka, Moscow, 1986; Prentice Hall, Englewood Cliffs, NJ, 1995).
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Ryazanov, M.A., Dudkin, B.N. Acid-base properties of the surface of the α-Al2O3 suspension. Russ. J. Phys. Chem. 83, 2318–2321 (2009). https://doi.org/10.1134/S0036024409130238
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DOI: https://doi.org/10.1134/S0036024409130238