Skip to main content
Log in

Increase in the Strength and Electrical Conductivity of a Cu–0.8Hf Alloy after Rotary Swaging and Subsequent Aging

  • STRUCTURE AND PROPERTIES OF THE DEFORMED STATE
  • Published:
Russian Metallurgy (Metally) Aims and scope

Abstract—The structure, electrical conductivity, and mechanical properties (including fatigue strength) of a Cu–0.8% Hf alloy after rotary swaging (RS) at various strains and subsequent aging are investigated. RS is shown to cause the formation of a microstructure elongated in the deformation direction. When the strain increases, the average grain width decreases and grains acquire an increasingly elongated shape. After RS at ε = 2.77, the formation of an ultrafine-grained structure with an average subgrain size of 173 ± 12 nm is observed inside the elongated grains. When the strain increases, the strength of the alloy increases and the plasticity decreases. Subsequent aging causes an increase in the strength of the quenched alloy and the alloy after RS at ε = 0.58 and 1.39; hardening is absent after RS at ε = 2.77. In all cases, aging increases the electrical conductivity of the alloy as a result of the decomposition of a supersaturated solid solution and the precipitation of the Cu5Hf phase. The best combination of the mechanical and functional properties is achieved after RS at ε = 2.77 and subsequent aging at 475°C for 2 h: the ultimate tensile strength is 461 ± 28 MPa, the ductility is 12.5 ± 2.4%, the fatigue limit is 325 MPa, and the electrical conductivity is 90.4 ± 1.9% IACS.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

REFERENCES

  1. T. Wang, K. Lu, T. Qiu, X. Zeng, H. Ning, Z. Yang, Y. Li, Q. Ye, R. Yao, and J. Peng, “Highly conductive and adhesive ternary Cu–Cr–Zr alloy electrode for flexible optoelectronic applications,” Superlat. Microstruct. 157, 106989 (2021).

    Article  CAS  Google Scholar 

  2. C. Xia, W. Zhang, Z. Kang, Y. Jia, Y. Wu, R. Zhang, G. Xu, and M. Wang, “High strength and high electrical conductivity Cu–Cr system alloys manufactured by hot rolling–quenching process and thermomechanical treatments,” Mater. Sci. Eng., A 538, 295–301 (2012).

    Article  CAS  Google Scholar 

  3. D. K. Orlova, T. I. Chashchukhina, L. M. Voronova, and M. V. Degtyarev, “Influence of the temperature–rate deformation conditions in Bridgman anvils on the structure formation in commercial-purity copper,” Fiz. Met. Metalloved. 116 (9), 1–8 (2015).

    Google Scholar 

  4. C. Y. Ho, M. W. Ackerman, K. Y. Wu, T. N. Havill, R. H. Bogaard, R. A. Matula, S. G. Oh, and H. M. James, “Electrical resistivity of ten selected binary alloy systems,” J. Phys. Chem. Ref. Data 12 (2), 183–322 (1983).

    Article  CAS  Google Scholar 

  5. X. Zhang, Y. Yuan, S. Zhao, J. Zhang, and Q. Yan, “Microstructure stability, softening temperature and strengthening mechanism of pure copper, CuCrZr and Cu–Al2O3 up to 1000°C,” Nucl. Mater. Energy 30, 101123 (2022).

    Article  CAS  Google Scholar 

  6. N. R. Bochvar, O. V. Rybalchenko, D. V. Shangina, and S. V. Dobatkin, “Effect of equal-channel angular pressing on the precipitation kinetics in Cu–Cr–Hf alloys,” Mater. Sci. Eng., A 757, 84–87 (2019).

    Article  CAS  Google Scholar 

  7. X. Wu, R. Wang, C. Peng, and G. Jiang, “Microstructure stability and tensile properties of Cu–3Ag–1Zr alloy fabricated by rapid solidification and cold rolling,” Mater. Character. 160, 110091 (2020).

    Article  CAS  Google Scholar 

  8. A. Meng, J. Nie, K. Wei, H. Kang, Z. Liu, and Y. Zhao, “Optimization of strength, ductility and electrical conductivity of a Cu–Cr–Zr alloy by cold rolling and aging treatment,” Vacuum 167, 329–335 (2019).

    Article  CAS  Google Scholar 

  9. H. Feng, H. Jiang, D. Yan, and L. Rong, “Thermal stability of ultrafine grained CuCrZr alloy produced by continuous extrusion,” Trends J. Sci. Res. 4 (1), 1–8 (2019).

    Article  Google Scholar 

  10. D. Liang, X. Mi, L. Peng, H. Xie, G. Huang, and Z. Yang, “Relationship between microstructure and properties of Cu–Cr–Ag alloy,” Materials 13 (1), 732 (2020).

    Article  CAS  Google Scholar 

  11. A. Bodyakova, A. Pilipenko, A. Lugovskaya, A. Belyakov, and R. Kaibyshev, “Thermal stability of gradient microstructure in a low-alloyed Cu–Cr–Zr alloy,” Mater. Lett. 304, 130531 (2021).

    Article  CAS  Google Scholar 

  12. J. Li, J. Wongsa-Ngam, J. Xu, D. Shan, B. Guo, and T. G. Langdon, “Wear resistance of an ultrafine-grained Cu–Zr alloy processed by equal-channel angular pressing,” Wear 326327, 10–19 (2015).

  13. R. Kužel, Z. Matěj, and M. Janeček, “In situ X-ray diffraction study of thermal stability of Cu and Cu–Zr samples processed by ECAP,” Mater. Sci. Forum 753, 279–284 (2013).

  14. D. V. Shan’gina, N. I. Ivanov, N. R. Bochvar, and S. V. Dobatkin, “Resistance of contact welding electrodes made of a Cu–0.7% Cr–0.9% Hf alloy with an ultrafine-grained structure,” Metally, No. 5, 26–31 (2018).

    Google Scholar 

  15. Yu. S. Radyuchenko, Rotary Swaging (Mashgiz, Moscow, 1962).

    Google Scholar 

  16. Q. Mao, L. Wang, J. Nie, and Y. Zhao, “Enhancing strength and electrical conductivity of Cu–Cr composite wire by two-stage rotary swaging and aging treatments,” Composites Part B: Eng. 231, 109567 (2022).

    Article  CAS  Google Scholar 

  17. A. H. Huang, Y. F. Wang, M. S. Wang, L. Y. Song, Y. S. Li, L. Gao, C. X. Huang, and Y. T. Zhu, “Optimizing the strength, ductility and electrical conductivity of a Cu–Cr–Zr alloy by rotary swaging and aging treatment,” Mater. Sci. Eng., A 746, 211–216 (2019).

    Article  CAS  Google Scholar 

  18. P. R. Subramanian and D. E. Laughlin, “The Cu–Hf (copper–hafnium) system,” Bull. Alloy Phase Diagrams 9, 51–56 (1988).

    Article  Google Scholar 

  19. A. K. Nikolaev and V. M. Rozenberg, Alloys for Contact Welding Electrodes (Metallurgiya, Moscow, 1978).

    Google Scholar 

  20. Y. Yang, G. Kuang, and R. Li, “Optimizing the electrical and mechanical properties of Cu–Cr alloys by Hf microalloying,” Metals 12, 485 (2022).

    Article  CAS  Google Scholar 

  21. R. G. Chembarisova, A. V. Galaktionova, and A. M. Yamileva, “Evolution of the secondary phase particles in Cu–Cr–Zr alloys with an extremely low solid solution concentration during deformation and heat treatment,” Fiz. Met. Metalloved. 122 (1), 45–52 (2021).

    Google Scholar 

Download references

ACKNOWLEDGMENTS

The studies of the fracture surfaces of fatigue failure of the samples after fatigue tests were conducted using the research equipment of the Shared Facility Center at P.N. Lebedev Physical Institute of the Russian Academy of Science.

Funding

This work was carried out within the framework of state task no. 075-01176-23-00.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. S. Martynenko.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by K. Shakhlevich

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Martynenko, N.S., Bochvar, N.R., Rybalchenko, O.V. et al. Increase in the Strength and Electrical Conductivity of a Cu–0.8Hf Alloy after Rotary Swaging and Subsequent Aging. Russ. Metall. 2023, 466–474 (2023). https://doi.org/10.1134/S0036029523040158

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036029523040158

Navigation