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Oxidative desulfurization of diesel fraction with hydrogen peroxide in the presence of catalysts based on transition metals

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Abstract

The oxidative desulfurization of a straight-run, nonhydrotreated diesel fraction (boiling range 178–342°C) containing benzothiophene, dibenzothiophene, their alkyl-substituted derivatives, and thioxanthene by the action of hydrogen peroxide in the presence of transition metal compounds (Na2MoO4, Na2WO4, NaVO3, WO3, tungstic acid, and heteropoly tungstate/molybdate H3PMo6W6O40) in a biphasic system followed by the extraction of the oxidation products with dimethylformamide has been studied. The oxidation of the hydrocarbon fraction in the presence of heteropoly tungstate/molybdate under biphasic conditions provides for the removal of up to 82% of total sulfur.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119899, Russia

    E. V. Rakhmanov, A. V. Tarakanova, T. Valieva, A. V. Akopyan, V. V. Litvinova, A. L. Maksimov & A. V. Anisimov

  2. Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences, ul. S. Kovalevskoi 20, Yekaterinburg, 620219, Russia

    S. V. Vakarin, O. L. Semerikova & Yu. P. Zaikov

Authors
  1. E. V. Rakhmanov
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  2. A. V. Tarakanova
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  3. T. Valieva
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  4. A. V. Akopyan
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  5. V. V. Litvinova
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  6. A. L. Maksimov
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  7. A. V. Anisimov
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  8. S. V. Vakarin
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  9. O. L. Semerikova
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  10. Yu. P. Zaikov
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Corresponding author

Correspondence to E. V. Rakhmanov.

Additional information

Original Russian Text © E.V. Rakhmanov, A.V. Tarakanova, T. Valieva, A.V. Akopyan, V.V. Litvinova, A.L. Maksimov, A.V. Anisimov, S.V. Vakarin, O.L. Semerikova, Yu.P. Zaikov, 2014, published in Neftekhimiya, 2014, Vol. 54, No. 1, pp. 49–51.

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Rakhmanov, E.V., Tarakanova, A.V., Valieva, T. et al. Oxidative desulfurization of diesel fraction with hydrogen peroxide in the presence of catalysts based on transition metals. Pet. Chem. 54, 48–50 (2014). https://doi.org/10.1134/S0965544114010101

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  • DOI: https://doi.org/10.1134/S0965544114010101

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