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Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants

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Abstract

The effect of the second ligand and surfactant micelles on the solid-phase time-resolved fluorescence of europium sensitized by doxycycline on Silasorb 600 is studied. A procedure of the sorption-luminescence determination of doxycycline using micelles of Triton X-100 nonionic surfactant is developed; the detection limit is 1.1 × 10−7. The analytical range for doxycycline is 3 × 10−7 to 3 × 10−5 M. The procedure is tested on a doxycycline pharmaceutical drug; RSD was no worse than 4%.

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Authors and Affiliations

  1. Institute of Chemistry, Saratov State University, ul. Astrakhanskaya 83, Saratov, 410012, Russia

    I. I. Parashchenko, T. D. Smirnova & S. N. Shtykov

  2. Department of Physics, Saratov State University, ul. Astrakhanskaya 83, Saratov, 410012, Russia

    V. I. Kochubei

  3. NITA FARM Joint-Stock Company, ul. Pugachevskaya 161, Saratov, 410030, Russia

    N. N. Zhukova

Authors
  1. I. I. Parashchenko
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  2. T. D. Smirnova
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  3. S. N. Shtykov
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  4. V. I. Kochubei
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  5. N. N. Zhukova
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Original Russian Text © I.I. Parashchenko, T.D. Smirnova, S.N. Shtykov, V.I. Kochubei, N.N. Zhukova, 2013, published in Zhurnal Analiticheskoi Khimii, 2013, Vol. 68, No. 2, pp. 125–129.

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Parashchenko, I.I., Smirnova, T.D., Shtykov, S.N. et al. Doxycycline-sensitized solid-phase fluorescence of europium on silica in the presence of surfactants. J Anal Chem 68, 112–116 (2013). https://doi.org/10.1134/S1061934813020123

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  • DOI: https://doi.org/10.1134/S1061934813020123

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