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Electrocatalytic determination of penicillamine using multiwall carbon nanotubes paste electrode and chlorpromazine as a mediator

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Abstract

In this study, we describe the application of carbon paste electrode modified with multiwall carbon nanotubes as a voltammetric sensor for determination of penicillamine (PA) in the presence of chlorpromazine as a mediator. This modified electrode showed very efficient electrocatalytic activity for the anodic oxidation of PA. The peak current of linear sweep voltammograms of PA increased linearly with it’s concentration in the range of 0.5–500 μM PA. The detection limit for PA was 0.2 μM. The RSDs for 1.0 and 10.0 μM PA were 1.1 and 1.7%, respectively. The proposed sensor was successfully applied for the determination of PA in human urine and tablet.

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References

  1. Walshe, J.M., Am. J. Med., 1956, vol. 21, p. 487.

    Article  CAS  Google Scholar 

  2. Sarkar, B., Chem. Rev., 1999, vol. 99, p. 2535.

    Article  CAS  Google Scholar 

  3. Gooneratne, S.R. and Christensen, D.A., Vet. J., 1997, vol. 153, p. 171.

    Article  CAS  Google Scholar 

  4. LeRoy, E.C., Trojanowska, M., and Smith, E.A., Clin. Exp. Rheumatol., 1991, vol. 9, p. 173.

    CAS  Google Scholar 

  5. Jaffe, I.A., Am. J. Med., 1983, vol. 75, p. 63.

    Article  CAS  Google Scholar 

  6. Stephens, A.D., J. Inherited Metab. Dis., 1989, vol. 12, p. 197.

    Article  CAS  Google Scholar 

  7. Cervantes, G., Moreno, V., Molins, E., and Quiros, M., Polyhedron, 1998, vol. 17, p. 3343.

    Article  CAS  Google Scholar 

  8. Liang, S.C., Wang, H., Zhang, Z.M., and Zhang, H.S., Anal. Bioanal. Chem., 2005, vol. 381, p. 1095.

    Article  CAS  Google Scholar 

  9. Saetre, R. and Rabenstein, D.L., Anal. Chem., 1978, vol. 50, p. 276.

    Article  CAS  Google Scholar 

  10. Ensafi, A.A., Karimi-Maleh, H., and Mallakpour, S., Electroanalysis, 2011, vol. 23, p. 1478.

    Article  CAS  Google Scholar 

  11. Khalilzadeh, M.A., Karimi-Maleh, H., Amiri, A., Gholami, F., and Motaghed, M., Chin. Chem. Lett., 2010, vol. 21, p. 1467.

    Article  CAS  Google Scholar 

  12. Ensafi, A.A. and Karimi-Maleh, H., J. Electroanal. Chem., 2010, vol. 640, p. 75.

    Article  CAS  Google Scholar 

  13. Ensafi, A.A. and Karimi-Maleh, H., Electroanalysis, 2010, vol. 22, p. 2558.

    Article  CAS  Google Scholar 

  14. Karimi-Maleh, H., Tahernejad-Javazmi, F., Atar, N., Yola, M.L., Gupta, V.K., and Ensafi, A.A., Ind. Eng. Chem. Res., 2015, vol. 54, p. 3634.

    Article  CAS  Google Scholar 

  15. Karimi-Maleh, H., Tahernejad-Javazmi, F., Ensafi, A.A., Moradi, R., Mallakpour, S., and Beitollahi, H., Biosens. Bioelectron., 2014, vol. 60, p. 1.

    Article  CAS  Google Scholar 

  16. Karimi-Maleh, H., Biparva, P., and Hatami, M., Biosens. Bioelectron., 2013, p. 270.

    Google Scholar 

  17. Moradi, R., Sebt, S.A., Karimi-Maleh, H., Sadeghi, R., Karimi, F., Bahari, A., and Arabi, H., Phys. Chem. Chem. Phys., 2013, vol. 15, p. 5888.

    Article  CAS  Google Scholar 

  18. Afsharmanesh, E., Karimi-Maleh, H., Pahlavan, A., and Vahedi, J., J. Mol. Liq., 2013, vol. 181, p. 8.

    Article  CAS  Google Scholar 

  19. Beitollah, H., Goodarzian, M., Khalilzadeh, M.A., Karimi-Maleh, H., Hassanzadeh, M., and Tajbakhsh, M., J. Mol. Liq., 2012, vol. 173, p. 137.

    Article  CAS  Google Scholar 

  20. Najafi, M., Khalilzadeh, M.A., and Karimi-Maleh, H., Food Chem., 2014, vol. 158, p. 125.

    Article  CAS  Google Scholar 

  21. Raoof, J.B., Ojani, R., and Karimi-Maleh, H., Electroanalysis, 2008, vol. 20, p. 1259.

    Article  CAS  Google Scholar 

  22. Bahari, A., Karimi-Maleh, H., Hosseinzadeh, R., and Mirnia, N., Sens. Actuators, B, 2013, vol. 177, p. 70.

    Article  Google Scholar 

  23. Ensafi, A.A., Karimi-Maleh, H., Ghiaci, M., and Arshadi, M., J. Mater. Chem., 2011, vol. 21, p. 15022.

    Article  CAS  Google Scholar 

  24. Yaghoubian, H., Karimi-Maleh, H., Khalilzadeh, M.A., and Karimi, F., Int. J. Electrochem. Sci., 2009, vol. 4, p. 993.

    Google Scholar 

  25. Karimi-Maleh, H., Mehdipour-Ataei, S., Hatami, M., and Khalilzadeh, M.A., J. Anal. Chem., 2014, vol. 69, p. 162.

    Article  CAS  Google Scholar 

  26. Keyvanfard, M., Ensafi, A.A., and Karimi-Maleh, H., J. Solid State Electrochem., 2012, vol. 16, p. 2949.

    Article  CAS  Google Scholar 

  27. Keyvanfard, M., Rezaei, B., and Alizad, K., Curr. Nanosci., 2014, vol. 10, p. 512.

    Article  Google Scholar 

  28. Keyvanfard, M., Karimi-Maleh, H., and Alizad, K., Chin. J. Catal., 2013, vol. 34, p. 1883.

    Article  CAS  Google Scholar 

  29. Keyvanfard, M., Khosravi, V., Karimi-Maleh, H., Alizad, K., and Rezaei, B., J. Mol. Liq., 2013, vol. 177, p. 182.

    Article  CAS  Google Scholar 

  30. Keyvanfard, M., Sami, S., Karimi-Maleh, H., and Alizad, K., J. Braz. Chem. Soc., 2013, vol. 24, p. 32.

    Article  CAS  Google Scholar 

  31. Keyvanfard, M., Shakeri, R., Karimi-Maleh, H., and Alizad, K., Mater. Sci. Eng., 2013, vol. 33, p. 811.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Majlesi Branch, Islamic Azad University, Isfahan, Iran

    Mohsen Keyvanfard & Khadijeh Alizad

  2. Department of Chemistry, Shahreza Branch, Islamic Azad University, Isfahan, Iran

    Nazila Najjarian

Authors
  1. Mohsen Keyvanfard
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  2. Nazila Najjarian
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  3. Khadijeh Alizad
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Correspondence to Mohsen Keyvanfard.

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Keyvanfard, M., Najjarian, N. & Alizad, K. Electrocatalytic determination of penicillamine using multiwall carbon nanotubes paste electrode and chlorpromazine as a mediator. J Anal Chem 72, 1045–1050 (2017). https://doi.org/10.1134/S1061934817100136

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  • DOI: https://doi.org/10.1134/S1061934817100136

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