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Electrochemical Sensors Based on Copper–Cadmium Bimetallic Porphyrin Coordination Polymers with Various Cu/Cd Ratios

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Abstract

Bimetallic porphyrin coordination polymers with various Cu/Cd ratios (Cu–Cd) were synthesized and characterized by X-ray diffraction, infrared spectroscopy, inductively coupled plasma atomic emission spectrometry and transmission electron microscopy. The presence of Cu(II) in the series of bimetallic porphyrin coordination polymers makes them electrochemically active, consequently, they can be used in electrochemical sensing of hydrogen peroxide and sodium nitrite. Their sensing performance was investigated by cyclic voltammetry and chronoamperometry. The performance was affected by Cu/Cd ratio of Cu–Cd, and the optimal Cu–Cd-2 (with Cu/Cd ratio of 1.59) showed the best performance: the detection sensitivities for H2O2 and NaNO2 were 414 and 418 mA/(M cm2), respectively, and detection limits were 2.7 and 3 μM (S/N = 3). These results demonstrate that Cu−Cd offers great prospect for the construction of non-enzymatic sensors for hydrogen peroxide or sodium nitrite.

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Funding

The authors are grateful the financial support of National Natural Science Foundation of China (Grant no. 21175068) and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Authors and Affiliations

  1. Jiangsu Key Laboratory of New Power Batteries, Jiangsu Collaborative Innovation Center of Biomedical Functional Materials, Jiangsu Key Laboratory of Biomedical Materials, College of Chemistry and Materials Science, Nanjing Normal University, 210023, Nanjing, China

    Chunyan Wang, Dan Ding, Xiaoqing Jiang & Bo Zhou

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  1. Chunyan Wang
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  2. Dan Ding
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  3. Xiaoqing Jiang
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  4. Bo Zhou
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Correspondence to Bo Zhou.

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Wang, C., Ding, D., Jiang, X. et al. Electrochemical Sensors Based on Copper–Cadmium Bimetallic Porphyrin Coordination Polymers with Various Cu/Cd Ratios. J Anal Chem 76, 772–778 (2021). https://doi.org/10.1134/S1061934821060137

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  • DOI: https://doi.org/10.1134/S1061934821060137

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