Abstract
Carbon interaction with rhodium (111) surface has been studied by Auger electron spectroscopy in ultrahigh vacuum within a broad temperature interval of 300-1800 K. It has been shown that the graphene monolayer remains stable on the metal surface within a relatively narrow temperature interval of ∼50 K below the carbonization point, and when heated above this point, graphene breaks up gradually by transferring first to the island state, and after that, to chemisorbed carbon “gas.“ As the temperature decreases, a stable multilayer graphite film forms.
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References
A. Ya. Tontegode, Prog. Surf. Sci. 38(3/4), 429 (1991).
N. R. Gall, E. V. Rut’kov, and A. Ya. Tontegode, Int. J. Mod. Phys. B 11(6), 1865 (1997).
V. N. Ageev, E. V. Rut’kov, A. Ya. Tontegode, and N. F. Kholin, Fiz. Tverd. Tela (Leningrad) 23(8), 2248 (1981) [Sov. Phys. Solid State 23 (8), 1315 (1981)].
V. N. Ageev, E. V. Rut’kov, A. Ya. Tontegode, and N. F. Kholin, Fiz. Tverd. Tela (Leningrad) 24,3, 780 (1982).
E. V. Rut’kov and A. Ya. Tontegode, Poverkhnost’, No. 10, 58 (1983).
E. V. Rut’kov and A. Ya. Tontegode, Surf. Sci. 161, 373 (1985).
N. R. Gall’, S. N. Mikhailov, E. V. Rut’kov, and A. Ya. Tontegode, Fiz. Tverd. Tela (Leningrad) 27(8), 2351 (1985) [Sov. Phys. Solid State 27 (8), 1410 (1985)].
N. R. Gall’, S. N. Mikhailov, E. V. Rut’kov, and A. Ya. Tontegode, Poverkhnost’, No. 8, 58 (1986).
N. R. Gall’, S. N. Mikhailov, E. V. Rut’kov, and A. Ya. Tontegode, Zh. Tekh. Fiz. 56(4), 732 (1986) [Sov. Phys. Tech. Phys. 31 (4), 441 (1986)].
N. R. Gall, S. N. Mikhailov, E. V. Rut’kov, and A. Ya. Tontegode, Surf. Sci. 191, 185 (1987).
E. V. Rut’kov, Zh. Tekh. Fiz. 63(3), 122 (1993) [Sov. Phys. Tech. Phys. 38 (3), 220 (1993)].
E. V. Rut’kov and A. Ya. Tontegode, Fiz. Tverd. Tela (St. Petersburg) 38(2), 635 (1996) [Phys. Solid State 38 (2), 351 (1996)].
J. C. Hamilton and J. M. Blakely, Surf. Sci. 91(1), 149 (1980).
J. C. Hamilton and J. M. Blakely, J. Vac. Sci. Technol. 15(2), 559 (1978).
J. C. Shelton, H. R. Patil, and J. M. Blakely, Surf. Sci. 43(2), 493 (1974).
M. Eizenbery and J. M. Blakely, Surf. Sci. 82(1), 228 (1979).
E. V. Rut’kov, A. Ya. Tontegode, and M. M. Usufov, Izv. Akad. Nauk, Ser. Fiz. 58(10), 102 (1994).
E. V. Rut’kov, A. Ya. Tontegode M. M. Usufov, and N. R. Gall’, Zh. Tekh. Fiz. 62(10), 148 (1992) [Sov. Phys. Tech. Phys. 37 (10), 1038 (1992)].
N. R. Gall’, E. V. Rut’kov, and A. Ya. Tontegode, Pis’ma Zh. Eksp. Teor. Fiz. 73(12), 756 (2001) [JETP Lett. 73 (12), 671 (2001)].
N. R. Gall, E. V. Rut’kov, A. Ya. Tontegode, and M. M. Usufov, Appl. Surf. Sci. 78, 179 (1994).
N. R. Gall’, E. V. Rut’kov, and A. Ya. Tontegode, Zh. Tekh. Fiz. 72(4), 113 (2002) [Tech. Phys. 47 (4), 484 (2002)].
T. Aizawa, R. R. Souda, S. Otani, Y. Ishizava, and C. Oshima, Phys. Rev. B: Condens. Matter 42, 1469 (1990).
A. Nadashima, H. Ituh, T. Ichinokava, C. Oshima, and S. Otani, Phys. Rev. B: Condens. Matter 50, 4756 (1994).
H. Goldschmidt, Interstitial Alloys (Butterworths, London, 1967: Mir, Moscow, 1971), Vol. 1, p. 424.
R. Elliott, Constitution of Binary Alloys (McGraw-Hill, New York, 1965; Metallurgiya, Moscow, 1970).
V. S. Fomenko, Emission Properties of Materials: A Handbook (Naukova Dumka, Kiev, 1981) [in Russian].
E. Ya. Zandberg and N. I. Ionov, Surface Ionization (Nauka, Moscow, 1969; Israel Program for Scientific Translation, Jerusalem, 1971).
N. D. Potekhina, N. R. Gall’, E. V. Rut’kov, and A. Ya. Tontegode, Fiz. Tverd. Tela (St. Petersburg) 45(4), 742 (2003) [Phys. Solid State 45 (4), 782 (2003)].
E. V. Rut’kov and N. R. Gall’, Izv. Akad. Nauk, Ser. Fiz. 73(5), 707 (2009) [Bull. Russ. Acad. Sci.: Phys. 73 (5), 667 (2009)].
A. Ya. Tontegode and E. V. Rut’kov, Fiz. Tverd. Tela (Leningrad) 29(5), 1306 (1987) [Sov. Phys. Solid State 29 (5), 747 (1987)].
E. V. Rut’kov and N. R. Gall’, Fiz. Tverd. Tela (St. Petersburg) 51(8), 1639 (2009) [Phys. Solid State 51 (8), 1738 (2009)].
G. V. Samsonov and I. M. Vinitskii, Handbook of Refractory Compounds (Metallurgiya, Moscow, 1976; Plenum, New York, 1980).
N. D. Potekhina, E. Ya. Zandberg, E. V. Rut’kov, and A. Ya. Tontegode, Fiz. Tverd. Tela (Leningrad) 19(7), 2078 (1977) [Sov. Phys. Solid State 19 (7), 1216 (1977)].
E. Ya. Zandberg, E. V. Rut’kov, A. Ya. Tontegode, and N. D. Potekhina, Fiz. Tverd. Tela (Leningrad) 19(6), 1665 (1977) [Sov. Phys. Solid State 19 (6), 972 (1977)].
A. Ya. Tontegode and E. V. Rut’kov, Usp. Fiz. Nauk 163(11), 57 (1993) [Phys.-Usp. 36 (11), 1053 (1993)].
N. R. Gall’, N. P. Lavrovskiya, E. V. Rut’kov, and A. Ya. Tontegode, Zh. Tekh. Fiz. 74(2), 105 (2004) [Tech. Phys. 49 (2), 245 (2004)].
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Original Russian Text © E.V. Rut’kov, A.V. Kuz’michev, N.R. Gall’, 2011, published in Fizika Tverdogo Tela, 2011, Vol. 53, No. 5, pp. 1026–1032.
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Rut’kov, E.V., Kuz’michev, A.V. & Gall’, N.R. Carbon interaction with rhodium surface: Adsorption, dissolution, segregation, growth of graphene layers. Phys. Solid State 53, 1092–1098 (2011). https://doi.org/10.1134/S1063783411050246
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DOI: https://doi.org/10.1134/S1063783411050246