Abstract
Geochemical features of copper and zinc in soils of background landscapes of northeastern European Russia have been revealed. Soils of accumulative landscapes are enriched with copper and zinc compounds compared to those of eluvial landscapes. Humus horizons serve as a geochemical barrier for elements. Analysis of the sorption parameters of humic acids (HAs) shows that the actual content of the studied heavy metals (HMs) in soils is far from the maximum sorption capacity. The contribution of HAs to the total sorption of metals makes up 4% for copper and 21% for zinc. The distribution of HMs among the genetic horizons is more contrast in loamy automorphic soils than in sandy semihydromorphic and hydromorphic soils. Paired correlations have been revealed between the contents of copper and zinc in sandy and loamy soils, which points to the similarity of their biogeochemical migration in landscapes. An actual database has been created, which is foundational to schematic maps of the spatial distribution of elements in background soils. The geochemical assessment of the environmental status of soils has allowed establishing norms for the regional background contents of copper and zinc in taiga and tundra soils.
Similar content being viewed by others
REFERENCES
I. I. Alekseev, E. V. Abakumov, G. A. Shamilishvili, and E. D. Lodygin, “Heavy metals and hydrocarbons content in soils of settlements of the Yamal-Nenets autonomous okrug,” Gig. Sanit. 95 (9), 818–821 (2016). doi 10.1882/0016-9900-2016-9-818-821
Soil Atlas of the Komi Republic, Ed. by G. V. Dobrovol’skii, A. I. Taskaev, and I. V. Zaboeva (Komi Resp. Tipogr., Syktyvkar, 2010) [in Russian].
V. A. Beznosikov, E. D. Lodygin, and S. N. Chukov, “Landscape-geochemical evaluation of the background content of heavy metals in taiga soils,” Vestn. S.-Peterb. Univ., Ser. 3: Biol., No. 2, 114–128 (2010).
R. S. Vasilevich, V. A. Beznosikov, and B. M. Kondratenok, “Mercury in environmental objects of background and technogenic areas,” Izv. Vyssh. Uchebn. Zaved., Neft Gaz (Tyumen), No. 3, 116–122 (2009).
Yu. N. Vodyanitskii, “Contamination of soils with heavy metals and metalloids and its ecological hazard (analytic review),” Eurasian Soil Sci. 46, 793–801 (2013). doi 10.1134/S1064229313050153
Yu. N. Vodyanitskii, “Standards for the contents of heavy metals and metalloids in soils,” Eurasian Soil Sci. 45, 321–328 (2012).
Yu. N. Vodyanitskii, “Natural and technogenic compounds of heavy metals in soils,” Eurasian Soil Sci. 47, 255–265 (2014). doi 10.1134/S1064229314040103
Yu. N. Vodyanitskii and I. O. Plekhanova, “Biogeochemistry of heavy metals in contaminated excessively moistened soils (analytical review),” Eurasian Soil Sci. 47, 153–161 (2014). doi 10.1134/S1064229314030090
G. O. Gambashidze, T. F. Urushadze, W. E. Blum, and A. F. Mentler, “Heavy metals in some soils of Western Georgia,” Eurasian Soil Sci. 47, 834–843 (2014). doi 10.1134/S1064229314080031
N. A. Gashkina, Yu. G. Tatsii, V. N. Udachin, and P. G. Aminov, “Biogeochemical indication of environmental contamination: a case study of a large copper smelter,” Geochem. Int. 53 253–264 (2015). doi 10.1134/S0016702915030076
V. V. Dobrovol’skii, “Monitoring and protection of soils,” Pochvovedenie, No. 12, 14–17 (1986).
T. T. Efremova, S. P. Efremov, K. P. Kutsenogii, A. A. Onuchin, and V. F. Peresedov, “Biogeochemistry of Fe, Mn, Cr, Ni, Co, Ti, V, Mo, Ta, W, and U in a low moor peat deposit of the Ob’-Tom’ interfluve,” Eurasian Soil Sci. 36, 501–510 (2003).
B. N. Zolotareva and I. I. Skripnichenko, “Geochemical monitoring of heavy metals in soils,” in Regional Ecological Monitoring (Nauka, Moscow, 1983), pp. 93–114.
V. B. Il’in, A. I. Syso, N. L. Baidina, G. A. Konarbaeva, and A. S. Cherevko, “Background concentrations of heavy metals in soils of southern Western Siberia,” Eurasian Soil Sci. 36, 494–500 (2003).
N. E. Kosheleva, N. S. Kasimov, and D. V. Vlasov, “Factors of the accumulation of heavy metals and metalloids at geochemical barriers in urban soils,” Eurasian Soil Sci. 48, 476–492 (2015). doi 10.1134/ S1064229315050038
N. V. Kuz’menkova, N. E. Kosheleva, and E. E. Asadulin, “Heavy metals in soils and lichens of tundra and forest-tundra zones (northwest of the Kola Peninsula),” Pochvovedenie, No. 2, 244–256 (2015). doi 10.7868/S0032180X14100062
T. M. Minkina, A. V. Soldatov, D. G. Nevidomskaya, G. V. Motuzova, Yu. S. Podkovyrina, and S. S. Mandzhieva, “New approaches to studying heavy metals in soils by X-ray absorption spectroscopy (XANES)) and extractive fractionation,” Geochem. Int. 54 197–204 (2016). doi 10.1134/S001670291512006X
N. P. Nevedrov, E. P. Protsenko, and I. V. Glebova, “The relationship between bulk and mobile forms of heavy metals in soils of Kursk,” Eurasian Soil Sci. 51, 112–119 (2018). doi 10.7868/S0032180X18010112
A. I. Perel’man, E. N. Borisenko, A. E. Vorob’ev, S. M. Kravchenko, V. N. Levin, I. V. Mel’nikov, and A. E. Samonov, “Geochemistry of landscapes of Russia and radiogeoecology,” Geoekol., Inzh. Geol., Gidrogeol., Geokriol., No. 3, 3–15 (1996).
“Order of the Ministry of Nature Resources and Environment of the Komi Republic no. 529 of November 25, 2009 on the Standards of background content of chemical elements and hydrocarbons in soils of Komi Republic,” Ved. Norm. Aktov Organov Gos. Vlasti Resp. Komi, No. 46 (923), 87–93 (2009).
E. N. Sever’yanova, “Heavy metals in soils and plants neat coal mines by example of the Komsomolskaya Mine, Vorkuta city, Komi Republic,” Vestn. Krasn. Gos. Agrar. Univ., No. 8, 3–15 (2015).
A. N. Sivukhin and D. S. Markov, “The content of heavy metals in the soil cover of the central zone of the Russian Federation,” Nauch. Zhizn’, No. 12, 87–100 (2016).
Decree of the President of the Russian Federation no. 176 of April 19, 2017 on the Strategy of Ecological Safety of Russian Federation until 2025 (Moscow, 2017) [in Russian].
Q. Ding, G. Cheng, Y. Wang, and D. Zhuang, “Effects of natural factors on the spatial distribution of heavy metals in soils surrounding mining regions,” Sci. Total Environ. 578, 577–585 (2017). doi 10.1016/j.scitotenv.2016.11.001
L. Gulan, B. Milenkovic, T. Zeremski, G. Milic, and B. Vuckovic, “Persistent organic pollutants, heavy metals and radioactivity in the urban soil of Pristina City, Kosovo and Metohija,” Chemosphere 171, 415–426 (2017). doi 10.1016/j.chemosphere.2016.12.064
IUSS Working Group WRB, World Reference Base for Soil Resources 2014, Update 2015, International Soil Classification System for Naming Soils and Creating Legends for Soil Maps, World Soil Resources Reports No. 106 (Food and Agriculture Organization, Rome, 2015).
Y. Teng, J. Wu, S. Lu, Y. Wang, X. Jiao, and L. Song, “Soil and soil environmental quality monitoring in China: a review,” Environ. Int. 69, 177–199 (2014). doi 10.1016/j.envint.2014.04.014
G. Toth, T. Hermann, G. Szatmari, and L. Pasztor, “Maps of heavy metals in the soils of the European Union and proposed priority areas for detailed assessment,” Sci. Total Environ. 565, 1054–1062 (2016). doi 10.1016/j.scitotenv.2016.05.115
J. Zhu, Q. Wang, H. Yu, M. Li, and N. He, “Heavy metal deposition through rainfall in Chinese natural terrestrial ecosystems: evidences from national-scale network monitoring,” Chemosphere 164, 128–133 (2016). doi 10.1016/j.chemosphere.2016.08.105
ACKNOWLEDGEMENTS
The work was performed within the budget-supported theme of the Institute of Biology (project no. AAAA-A17-117122290011-5).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by K. Pankratova
Rights and permissions
About this article
Cite this article
Lodygin, E.D. Content of Acid-Soluble Copper and Zinc in Background Soils of Komi Republic. Eurasian Soil Sc. 51, 1309–1316 (2018). https://doi.org/10.1134/S1064229318110054
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1064229318110054