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Kinetic features of the reaction of polyvinyl alcohol with epichlorohydrin in an alkaline medium

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Abstract

The kinetics of the reaction of polyvinyl alcohol with epichlorohydrin in an aqueous sodium hydroxide solution has been studied. The process rate has been shown to be diffusion-limited. Size exclusion chromatography data have revealed that polyvinyl alcohol chain branching proceeds slower than the nucleophilic substitution of the hydroxyl groups of polyvinyl alcohol with introduction of glycidyl groups.

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology of Russia, Miusskaya pl. 9, Moscow, 125047, Russia

    M. V. Semenova, Ya. O. Mezhuev, S. V. Osadchenko & M. I. Shtil’man

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  1. M. V. Semenova
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  2. Ya. O. Mezhuev
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  3. S. V. Osadchenko
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  4. M. I. Shtil’man
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Correspondence to Ya. O. Mezhuev.

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Original Russian Text © M.V. Semenova, Ya.O. Mezhuev, S.V. Osadchenko, M.I. Shtil’man, 2017, published in Zhurnal Obshchei Khimii, 2017, Vol. 87, No. 5, pp. 860–865.

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Semenova, M.V., Mezhuev, Y.O., Osadchenko, S.V. et al. Kinetic features of the reaction of polyvinyl alcohol with epichlorohydrin in an alkaline medium. Russ J Gen Chem 87, 1047–1052 (2017). https://doi.org/10.1134/S1070363217050255

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  • DOI: https://doi.org/10.1134/S1070363217050255

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