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Oligomeric hydroxy-aryloxy phosphazene based on cyclic chlorophosphazenes

  • Macromolecular Compounds and Polymeric Materials
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Abstract

Reaction of hexachlorocyclotriphosphazene and a mixture of cyclic chlorophosphazene [NPCl2] n = 3–8 with an excess of diphenylolpropane under different conditions affords corresponding oligomeric hydroxy-aryloxy phosphazenes, which were characterized by gas chromatography-mass spectrometry, laser mass spectrometry, 31P and 1H NMR spectroscopy. Side reactions was found with participation of decomposition products of diphenylolpropane.

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Authors and Affiliations

  1. Mendeleev University of Chemical Technology of Russia, Moscow, Russia

    I. S. Sirotin, Yu. V. Bilichenko, K. A. Brigadnov, V. V. Kireev & O. V. Suraeva

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    R. S. Borisov

Authors
  1. I. S. Sirotin
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  2. Yu. V. Bilichenko
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  3. K. A. Brigadnov
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  4. V. V. Kireev
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  5. O. V. Suraeva
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  6. R. S. Borisov
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Corresponding author

Correspondence to V. V. Kireev.

Additional information

Original Russian Text © I.S. Sirotin, Yu.V. Bilichenko, K.A. Brigadnov, V.V. Kireev, O.V. Suraeva, R.S. Borisov, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 12, pp. 1956–1965.

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Sirotin, I.S., Bilichenko, Y.V., Brigadnov, K.A. et al. Oligomeric hydroxy-aryloxy phosphazene based on cyclic chlorophosphazenes. Russ J Appl Chem 86, 1903–1912 (2013). https://doi.org/10.1134/S1070427213120161

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  • DOI: https://doi.org/10.1134/S1070427213120161

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