Abstract
Studies devoted to the eco-friendly disposal of hazardous organic substances (OS) and waste through oxidation in supercritical water (SCW) are reviewed. One advantage of using SCW is the possibility of complete and rapid oxidation of OS in closed systems. The oxidation rate is determined by the temperature, proportions between the reagents, bond dissociation energies, and solubility of OS in SCW, decreasing in the series aliphatic > aromatic, heterocyclic > polyaromatic compounds. The main oxidation products are carbon dioxide, nitrogen, and water; sulfur, phosphorus, and halogens are converted into the respective mineral acids. There are a number of difficulties in the implementation of particular processes on the industrial scale, which impede the achievement of an acceptable performance of installations in terms of safety and stability. These difficulties are mainly associated with heterogeneous processes on the reactor walls, such as the corrosion of constructional materials and deposition of salts, which lead with time to changes in the kinetic characteristic of the main and coupled reactions.
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B. Veriansyan and J.-D. Kim, J. Environ. Sci. 19, 513 (2007).
N. B. Thomason and M. Modell, Hazard. Waste 1, 453 (1984).
L. Li, P. Chen, and E. F. Gloyan, AIChE J. 37, 1687 (1991).
V. S. Mishra, V. V. Mahajani, and J. B. Joshi, Ind. Eng. Chem. Res. 34, 2 (1995).
F. Voge, K. A. Smith, J. W. Tester, and W. A. Peters, AIChE J. 48, 1827 (2002).
M. D. Bermejo and M. J. Cocero, AIChE J. 52, 3933 (2006).
M. Goto, J. Supercrit. Fluids 47, 500 (2009).
J. Sanchez-Oneto, J. R. Portela, E. Nebot, and E. M. de la Ossa, J. Hazard. Mater. 144, 639 (2007).
S. Yesodharan, Curr. Sci. 82, 1112 (2002).
E. Gasafi, M. Reinecre, A. Kruse, and L. Scheber, Biomass Bioenergy 32, 1085 (2008).
M. Svanstrom, M. Froling, M. Modell, W. A. Peters, and J. Tester, Resour., Conserv. Recycl. 41, 321 (2004).
V. Marulanda and G. Bolanos, J. Supercrit. Fluids 54, 258 (2010).
P. I. Proesmans, L. Luan, and S. J. Buelow, Ind. Eng. Chem. Res. 36, 1559 (1997).
S.-H. Lee, K. C. Park, and T. Mahiko, K. Sekizawa, Y. Izumizaki, and H. Tomiyasu, J. Supercrit. Fluids 39, 54 (2006).
A. Kruse and E. Dinjus, J. Supercrit. Fluids 41, 361 (2007).
G. Brunner, J. Supercrit. Fluids 47, 382 (2009).
M. Goto, D. Shiramizu, A. Kodama, and T. Nirose, Ind. Eng. Chem. Res. 38, 4500 (1999).
P. C. Dell’Orco, E. F. Gloyna, and S. J. Buelow, Ind. Eng. Chem. Res. 36, 2547 (1997).
J. M. Ploger, M. A. Mock, and J. W. Tester, AIChE J. 53, 941 (2007).
H.-J. Lee, J.-H. In, K.-Y. Hwang, and C.-H. Lee, Ind. Eng. Chem. Res. 43, 3223 (2004).
P. Muthukamaran and R. B. Gupta, Ind. Eng. Chem. Res. 39, 4555 (2000).
K. Stark, E. Plaza, and B. Hultman, Chemosphere 62, 827 (2006).
E. Fauvel, C. Joussot-Dubien, V. Tanneur, S. Moussiere, P. Guichardon, G. Charbit, and F. Charbit, Ind. Eng. Chem. Res. 44, 8968 (2005).
B. Wellig K. Lieball, and P. R. von Rohr, J. Supercrit. Fluids 34, 35 (2005).
C. Narayanan, C. Frouzakis, K. Boulouchos, K. Prikopsky, B. Wellig, and P. R. von Rohr, J. Supercrit. Fluids 46, 149 (2008).
B. Wellig, M. Weber, K. Lieball, K. Prikopsky, and P. R. von Rohr, J. Supercrit. Fluids 49, 59 (2009).
M. J. Cocero, T. Sanz, E. Alonso, and F. Fdez- Polanko, J. Supercrit. Fluids 24, 37 (2002).
M. Uematsu and E. U. Franck, J. Phys. Chem. Ref. Data 9, 1291 (1980).
W. L. Varshall and E. U. Franck, J. Phys. Chem. Ref. Data 10, 295 (1981).
J. Conolly, J. Chem. Eng. Data 11, 13 (1966).
C. J. Rebert and W. B. Kay, AIChE J. 5, 285 (1959).
I. M. Abdulagatov, A. R. Bazaev, R. K. Gasanov, and A. E. Ramazanova, J. Chem. Thermodyn. 28, 1037 (1996).
I. M. Abdelagatov, A. R. Bazaev, R. K. Gasanov, and A. E. Ramazanova, J. Chem. Thermodyn. 28, 1037 (1996).
S. M. Razulov and I. M. Abdulagatov, J. Chem. Eng. Data 55, 3247 (2010).
T. Yiling, T. Michelbergen, and E. U. Franck, J. Chem. Thermodyn. 23, 105 (1991).
M. Haruki, Y. Iwai, S. Nagao, Y. Yahiro, and Y. Anai, Ind. Eng. Chem. Res. 39, 4516 (2000).
A. E. Mather and E. U. Frnack, J. Phys. Chem. 96, 6 (1992).
R. Crovetto and R. H. Wood, Fluid Phase Equilib. 74, 271 (1992).
H. G. Greenwood, Am. J. Sci. 267A, 191 (1969).
M. L. Japas and E. U. Franck, Ber. Bunsenges. Phys. Chem. 89, 1268 (1985).
T. M. Seward and E. U. Franck, Ber. Bunsenges. Phys. Chem. 85, 2 (1981).
S. V. Makaev, T. M. Bitokhov, K. G. Kravchuk, M. A. Urusova, and V. M. Valyashko, Sverkhkrit. Flyuidy Teor. Prakt. 5(4), 75 (2010).
J. F. Galobardes, D. R. Vanhare, and L. B. Rogers, J. Chem. Eng. Data 26, 363 (1981).
P. Dell’Orco, H. Eaton, and T. Reynolds, J. Supercrit. Fluids 8, 217 (1995).
W. T. Wofford, P. C. Dell’Orco, and E. F. Gloyna, J. Chem. Eng. Data 40, 968 (1995).
F. J. Armelini and J. W. Tester, Fluid Phase Equilib. 88, 123 (1993).
M. M. DiPippo, K. Sako, and J. W. Tester, Fluid Phase Equilib. 157, 229 (1999).
M. A. Urusova and M. V. Valyashko, Zh. Neorg. Khim. 50, 1873 (2005).
M. A. Urusova, V. M. Valyashko, and I. M. Grigor’ev, Zh. Neorg. Khim. 52, 456 (2007).
M. S. Khan and S. N. Rogak, J. Supercrit. Fluids 30, 359 (2004).
H. Higashia, Y. Iwaib, K. Matsumoto, F. Okazakib, Y. Shimoyamab, and Y. Araib, Fluid Phase Equalib. 228–229, 547 (2005).
H. Weingarner and E. U. Franck, Angew. Chem. Int. Ed. 44, 2672 (2005).
R. W. Shaw, T. B. Brill, A. A. Clifford, C. A. Eckert, and E. U. Franck, Chem. Eng. News 69, 26 (1991).
P. E. Savage, S. Gopan, T. I. Mizan, C. J. Martino, and E. E. Brock, AIChE J. 41, 1723 (1995).
P. E. Savage, Chem. Rev. 99, 603 (1999).
A. A. Galkin and V. V. Lunin, Usp. Khim. 74(1), 24 (2005).
A. Kruse and E. J. Dinjus, Supercrit. Fluids 39, 362 (2007).
G. J. Brunner, Supercrit. Fluids 47, 373 (2009).
M. D. Bermejo, I. Bielsa, and M. J. Cocero, AIChE J. 52, 3958 (2006).
High Pressure Process Technology: Fundamentals and Applications, Eds. by A. Bertucco and T. Vetter (Elsevier, Amsterdam, 2001).
F. Salvador, M. J. Sanches-Montero, and C. Izquierdo, J. Phys. Chem. C 111, 14011 (2007).
V. Anikeev, A. Yermakova, and M. Goto, Ind. Eng. Chem. Res. 43, 8141 (2004).
J. T. Henrikson, G. R. Grice, and P. E. Savage, J. Phys. Chem. A 110, 3627 (2006).
F. Vogel, J. L. DiNaro Blanchard, P. A. Marrone, S. F. Rice, P. A. Webley, W. A. Peters, K. A. Smith, and J. W. Tester, Supercrit. Fluids 34, 249 (2005).
J. T. Henrikson, Z. Chen, and P. E. Savage, Ind. Eng. Chem. Res. 42, 6303 (2003).
J. T. Herikson and P. E. Savage, Ind. Eng. Chem. Res. 43, 4841 (2004).
J. T. Henrikson and P. E. Savage, AIChE J. 49, 718 (2003).
C. G. Martino and P. E. Savage, Environ. Sci. Technol. 33, 1911 (1999).
M. Krajnc and J. Levec, AIChE J. 42, 1977 (1996).
Y. Oshima, K. Hori, M. Toda, T. Chommanad, and S. J. Koda, Supercrit. Fluids 13, 241 (1998).
Y. Matsumora, T. Nunoura, T. Urase, and K. Yama- moto, J. Hazard. Mater. 73, 245 (2000).
A. A. Vostrikov, D. Yu. Dubov, and S. A. Psarov, Izv. Ross. Akad. Nauk. Ser. Khim., No. 8, 1409 (2001).
A. A. Vostrikov, S. A. Psarov, D. Yu. Dubov, M. Ya. So- kol, and O. N. Fedyaeva, Sverkhkrit. Flyuidy Teor. Prakt. 3(4), 83 (2008).
A. A. Vostrikov and S. A. Psarov, Pis’ma Zh. Tekh. Fiz. 30(3), 24 (2004).
J. A. Onwudili and P. T. Williams, J. Supercrit. Fluids 43, 81 (2007).
G. Anitescu and L. L. Tavlarides, Ind. Eng. Chem. Res. 44, 1226 (2005).
J. A. Onwudili and P. T. Williams, Fuel 85, 75 (2006).
M. J. Angeles-Hernandez, G. A. Leeke, and R. C. D. San- tos, Ind. Eng. Chem. Res. 48, 1208 (2009).
K. M. Benjamin and P. E. Savage, Ind. Eng. Chem. Res. 44, 9785 (2005).
H. Li and Y. Oshima, Ind. Eng. Chem. Res. 44, 8756 (2005).
A. Plugatyr, T. M. Hayward, and I. M. Svishchev, J. Supercrit. Fluids 55, 1014 (2011).
G. Zhang and I. Hua, Ind. Eng. Chem. Res. 42, 285 (2003).
B. Veriansyah, J.-D. Kim, and J.-C. Lee, Ind. Eng. Chem. Res. 44, 9014 (2005).
B. Veriansyah, J.-D. Kim, and J.-C. Lee, J. Ind. Eng. Chem 15, 153 (2009).
A. A. Vostrikov, D. Y. Dubov, S. A. Psarov, and M. Y. Sokol, in Proceedings of the 7th Italian Conference on Supercritical Fluids and Their Applications, Trieste, Italy, 2004, p. 135.
US Patent No. 4338199 (1982).
T. Sako, K. Sugeta, M. Otake, M. Sato, M. Tsugumi, T. Hiaki, and M. Nongo, J. Chem. Eng. Jpn. 30, 744 (1997).
K. C. Swallo and W. R. Killevia, Environ. Sci. Technol. 26, 1849 (1992).
Z. Fang, S. Xu, I. S. Butler, R. I. Smith, Jr., and J. A. Kozinski, Energy Fuels 18, 1257 (2004).
G. Anitescu and L. L. Tavlarides, Ind. Eng. Chem. Res. 41, 9 (2002).
G. Anitescu and L. L. Tavlarides, Ind. Eng. Chem. Res. 39, 583 (2000).
R. Weber, S. Yoshida, and K. Wiwa, Environ. Sci. Technol. 36, 1839 (2002).
H. Zhang, X. Su, D. Sun, R. Znang, and J. Bi, J. Fuel Chem. Technol. 35, 487 (2007).
Y. Park, J. N. Hool, C. W. Curtis, and C. B. Roberts, Ind. Eng. Chem. Res. 40, 756 (2001).
J. A. Onwudili and P. T. Williams, Supercrit. Fluids 49, 356 (2009).
D. Bo, F. Zhang, and L. Zhao, J. Hazard. Mater 170, 66 (2009).
A. Leybros, A. Roubaud, P. Guichardan, and O. Bou- tin, J. Supercrit. Fluids 51, 369 (2010).
F. M. Jin, A. Kishita, T. Moriya, and H. Enomoto, J. Supercrit. Fluids 19, 251 (2001).
L. Calvo and D. Vallejo, Ind. Eng. Chem. Res. 41, 6503 (2002).
M. B. Garcia Jarana, J. Sanchez-Oneto, J. R. Portela, E. Nebot Sanz, and E. J. Martinez de la Ossa, J. Supercrit. Fluids 46, 329 (2008).
H. Erkopak, O. O. Sogut, and M. Akgun, J. Supercrit. Fluids 46, 142 (2008).
T. Mizuno, M. Goto, A. Kodama, and T. Hirose, Ind. Eng. Chem. Res. 39, 2807 (2000).
M. Goto, T. Nada, A. Kodama, and T. Hirose, Ind. Eng. Chem. Res. 38, 1863 (1999).
J. A. Onwudili and P. T. Williams, Energy Fuels 21, 3676 (2007).
X. Xu, Y. Matsumura, J. Stenberg, and M. J. Antal, Ind. Eng. Chem. Res. 35, 2522 (1996).
A. A. Vostrikov, O. N. Fedyaeva, A. V. Shishkin, D. Yu. Dubov, M. Ya. Sokol, Khim. Tverd. Tela, No. 6, 70 (2008).
T. Gungoren, M. Saglam, M. Yuksel, H. Madenoglu, R. Isler, I. H. Metecan, A. R. Ozkan, and L. Ballice, Ind. Eng. Chem. Res. 46, 1051 (2007).
B. Cui, F. Ciu, G. Jing, S. Xu, W. Huo, and S. Liu, J. Hazard. Mater. 165, 511 (2009).
J. Sanchez-Oneto, J. R. Portela, E. Nebot, and E. Martinez de la Ossa, J. Hazard. Mater. 144, 639 (2007).
J. Sanchez-Oneto, F. Mancini, J. R. Portela, E. Nebot, F. Cansell, and E. Martinez de la Ossa Chem. Eng. J. 144, 361 (2008).
W. -J. Gong, F. Li, and D.-L. Xi, Environ. Eng. Sci. 26, 131 (2009).
Y. H. Shin, N. C. Shin, B. Veriansyah, J. Kim, and Y. J. Lee, Hazard. Mater. 163, 1142 (2009).
Y. H. Shin, H.-S. Lee, Y.-H. Lee, J. Kim, J.-D. Kim, and Y.-E. Lee, J. Hazard. Mater. 167, 824 (2009).
B. Veriansyah, T. J. Park, J. S. Lim, and Y. W. Lee, J. Supercrit. Fluids 34, 51 (2005).
V. Sricharoenchaikul, Bioresour. Technol. 100, 638 (2009).
F. L. P. Resende and P. E. Savage, Energy Fuels 23, 6213 (2009).
W.-J. Gong, F. Li, and D.-L. Xi, Water Environ. Res. 80, 186 (2008).
O. O. Sogut and M. Akgun, J. Supercrit. Fluids 43, 106 (2007).
Y. Akai, H. Oomura, K. Yamada, and T. Takada, J. Nucl. Sci. Technol. 44, 1089 (2007).
P. Kritzer, J. Supercrit. Fluids 29, 1 (2004).
D. B. Mitton, J.-H. Yoon, J. A. Cline, H.-S. Kim, N. Eliaz, and R. M. Latanision, Ind. Eng. Chem. Res. 39, 4689 (2000).
Chemistry. Large Encyclopedia, Ed. by I. L. Knunyants (Bol’sh. Ross. Entsikl., Moscow, 1998) [in Russian].
Titanium Alloys. Metallurgy of Titanium and Its Alloys, Ed. by B. A. Kolachev and S. G. Glazunov (Metallurgiya, Moscow, 1992) [in Russian].
P. Ampornrat and G. S. Was, J. Nucl. Mater. 371, 1 (2007).
K. Yin, S. Qui, Q. Zhang, and L. Zhang, J. Supercrit. Fluids 50, 235 (2009).
X. Gao, X. Wu, Z. Zhang, H. Guan, and E. Han, J. Supercrit. Fluids 42, 157 (2007).
H.-C. Lee, S.-H. Son, K.-Y. Hwang, and C.-H. Lee, Ind. Eng. Chem. Res. 45, 3412 (2006).
M. Sun, X. Wu, Z. Zhang, and E.-H. Han, J. Supercrit. Fluids 47, 309 (2008).
Q. Zhang, R. Tang, K. Yin, X. Luo, and L. Zhang, Corros. Sci. 51, 2092 (2009).
M. Fulger, D. Ohai, M. Mihzlache, M. Pantiru, and V. Malinovschi, J. Nucl. Mater. 385, 288 (2009).
A. T. Motta, A. Yilmazbayhan, M. J. Gomes da Silva, R. Comstock, G. S. Was, J. T. Busby, E. Gartner, Q. Peng, Y. H. Jeong, and J. Y. Park, J. Nucl. Mater. 371, 61 (2007).
C. Sun, R. Hui, W. Qu, and S. Yick, Corros. Sci. 51, 2508 (2009).
C. Anghel, PhD Thesis (Univ. Oslo, Oslo, 2006).
A. A. Vostrikov, O. N. Fedyaeva, A. V. Shishkin, and M. Ya. Sokol, Pis’ma Zh. Tekh. Fiz. 36(17), 1 (2010).
M. Nagae, S. Kuwae, T. Yoshio, and K. Oda, Corros. Eng. 53, 601 (2004).
L. Tan, T. R. Allen, and E. Barringer, J. Nucl. Mater. 394, 95 (2009).
M. Nagae, Y. Koyama, S. Yasutake, and T. Yoshio, J. Am. Ceram. Soc. 89, 3550 (2006).
P. Kritzer, N. Boukis, and E. Dinjus, Corrosion 54, 689 (1998).
J.-H. Lee, S.-H. Son, T. T. Viet, and C.-H. Lee, Kor. J. Chem. Eng. 26, 398 (2009).
A. A. Vostrikov, O. N. Fedyaeva, A. V. Shishin, and M. Y. Sokol, J. Supercrit. Fluids 48, 154 (2009).
A. A. Vostrikov and O. N. Fedyaeva, J. Supercrit. Fluids 55, 307 (2010).
A. Hodgson and S. Haq, Surf. Sci. Rep. 64, 381 (2009).
C. Joussot-Dubien, H. A. Turc, and E. Fauvel, J. Supercrit. Fluids 31, 195 (2004).
M. J. Drews, M. Williams, and M. Barr, Ind. Eng. Chem. Res. 39, 4772 (2000).
US Patent No. 5545337 (1996).
M. K. Lei and X. M. Zhu, Surf. Coat. Technol 93, 22 (2005).
K. Sridharan, S. P. Harrington, A. K. Johnson, J. R. Lincht, M. H. Anderson, and T. R. Allen, Mater. Des. 28, 1177 (2007).
L. Tan, K. Sridharan, T. R. Allen, R. Nanstad, and D. McClintock, J. Nucl. Mater. 374, 270 (2008).
L. Tan, K. Sridharan, T. R. Allen, R. Nanstad, and D. McClintock, J. Nucl. Mater. 374, 270 (2008).
L. Tan, X. Ren, K. Sridharan, and T. R. Allen, Corros. Sci. 50, 3056 (2008).
P. A. Marrone, M. Hodes, K. A. Smith, and J.W. Tester, J. Supercrit. Fluids 29, 289 (2004).
M. Hodes, P. A. Marrone, G. T. Hong, K. A. Smith, and J. W. Tester, J. Supercrit. Fluids 29, 265 (2004).
P. Kritzer and E. Dinjus, Chem. Eng. J. 83, 207 (2001).
US Patent No. 5571423 (1996).
US Patent No. 4822497 (1989).
P. A. Marrone, S. D. Cantwell, and D. W. Dalton, Ind. Eng. Chem. Res. 44, 9030 (2005).
M. D. Bernnejo, F. Fdez-Polanko, and M. J. Cocero, Ind. Eng. Chem. Res. 45, 3438 (2006).
M. D. Bernnejo, P. Cabeza, J. P. S. Queiroz, C. Jime- nez, and M. J. Cocero, J. Supercrit. Fluids 56, 21 (2011).
P. J. Crooker, K. S. Ahluwalia, Z. Fan, and J. Prince, Ind. Eng. Chem. Res. 39, 4865 (2000).
V. Casal and H. Schmidt, J. Supercrit. Fluids 13, 269 (1998).
S. Baur, H. Schmidt, A. Kramer, and J. Gerber, J. Supercrit. Fluids 33, 149 (2005).
M. D. Bennejo, D. Rincon, A. Marthin, and M. J. Cocero, Ind. Eng. Chem. Res. 48, 6262 (2009).
A. A. Vostrikov, O. N. Fedyaeva, D. Yu. Dubov, S. A. Psarov, and M. Ya. Sokol, Sverkhkrit. Flyuidy Teor. Prakt. 2(4), 70 (2007).
A. A. Vostrikov, O. N. Fedyaeva, D. Y. Dubov, S. A. Psarov, and M. Y. Sokol, Energy 36, 1948 (2011).
V. I. Anikeev, N. S. Belobrov, R. S. Prosvirin, L. S. Zvolsky, P. E. Mikenin, and A. Yermakova, Ind. Eng. Chem. Res. 45, 7977 (2006).
P. E. Savage, J. Supercrit. Fluids 47, 407 (2009).
K. Arai, R. L. Smith, Jr., and T. N. Aida, J. Supercrit. Fluids 47, 628 (2009).
N. Lior, Energy 32, 281 (2010).
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Original Russian Text © O.N. Fedyaeva, A.A. Vostrikov, 2012, published in Sverkhkriticheskie Flyuidy: Teoriya i Praktika, 2012, Vol. 7, No. 1, pp. 64–88.
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Fedyaeva, O.N., Vostrikov, A.A. Disposal of hazardous organic substances in supercritical water. Russ. J. Phys. Chem. B 6, 844–860 (2012). https://doi.org/10.1134/S1990793112070044
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DOI: https://doi.org/10.1134/S1990793112070044