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Extruded thermoelectric materials based on Bi2Te3-Bi2Se3 solid solutions

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Abstract

Extruded n-type materials based on Bi2Te3-Bi2Se3 alloys containing 6 to 40 mol % Bi2Se3 have been investigated using microstructural analysis and thermoelectric measurements at room temperature and in the range 100–400 K. Their electrical properties have been compared to those of single-crystal analogs. Compositions have been found at which the extruded materials offer the highest thermoelectric performance in different temperature ranges.

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References

  1. Chizhevskaya, S.N., Shelimova, L.E., Kosyakov, V.I., and Shestakov, V.A., Critical Evaluation and Optimization of Data on the Bi-Te-Se Phase Diagram and Crystal Structure of Bi2Te3-Bi2Se3 Alloys, Neorg. Mater., 1997, vol. 33, no. 8, pp. 903–911 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 12, pp. 757–764].

    Google Scholar 

  2. Sokolov, O.B., Skipidarov, S.Ya., Duvankov, N.I., and Shabunina, G.G., Phase Relations and Thermoelectric Properties of Alloys in the Bi2Te3-Bi2Se3 System, Neorg. Mater., 2007, vol. 43, no. 1, pp. 10–13 [Inorg. Mater. (Engl. Transl.), vol. 43, no. 1, pp. 8–11].

    Article  CAS  Google Scholar 

  3. Gordyakova, G.N., Kokosh, G.V., and Sinani, S.S., Thermoelectric Properties of Bi2Te3-Bi2Se3 Solid Solutions, Zh. Tekh. Fiz., 1958, vol. 28, no. 1, pp. 3–17.

    CAS  Google Scholar 

  4. Gol’tsman, B.M., Kudinov, V.A., and Smirnov, I.A., Poluprovodnikovye termoelektricheskie materialy na osnove Bi2Te3 (Bi2Te3-Based Thermoelectric Semiconductor Materials), Moscow: Nauka, 1972.

    Google Scholar 

  5. Bankina, V.F. and Abrikosov, N.Kh., System Bi2Te3-Bi2Se3, Zh. Neorg. Khim., 1964, vol. 9, no. 4, pp. 931–936.

    CAS  Google Scholar 

  6. Miller, G.R., Che-Yu Li, and Spencer, C.W., Properties of Bi2Te3-Bi2Se3 Alloys, J. Appl. Phys., 1963, vol. 34, no. 5, pp. 1398–1400.

    Article  CAS  Google Scholar 

  7. Svechnikova, T.E., Konstantinov, P.P., and Alekseeva, G.T., Physical Properties of Bi2Te2.85Se0.15 Single Crystals Doped with Cu, Cd, In, Ge, S, or Se, Neorg. Mater., 2000, vol. 36, no. 6, pp. 677–681 [Inorg. Mater. (Engl. Transl.), vol. 36, no. 6, pp. 556–560].

    Google Scholar 

  8. Spitsyn, V.I., Agafonova, L.A., Arakelyan, V.S., et al., Some Aspects of Diffusion in Sb2Te3-Bi2Te3 Materials Plastically Deformed by Hot Extrusion, Dokl. Akad. Nauk SSSR, 1978, vol. 238, no. 3, pp. 569–572.

    CAS  Google Scholar 

  9. Sokolov, O.B., Skipidarov, S.Ya., Duvankov, N.I., and Shabunina, G.G., Physical-Chemical Characterization of the Processes Occurring in Extrusion and Their Effect on Phase Diagram and Thermoelectric Properties of the Materials in Bi2Te3-Bi2Se3 and Sb2Te3-Bi2Te3 Systems, Proc. 5th Eur. Conf. on Thermoelectrics, Odessa, 2007, pp. 140–143.

  10. Ravich, Yu.I., Efimova, B.A., and Smirnov, I.A., Metody issledovaniya poluprovodnikov v primenenii k khal’kogenidam svintsa (Semiconductor Characterization Techniques with Application to the Lead Chalcogenides PbTe, PbSe, and PbS), Moscow: Nauka, 1968.

    Google Scholar 

  11. Ivanova, L.D. and Granatkina, Yu.V., Thermoelectric Properties of Bi2Te3-Sb2Te3 Single Crystals in the Range 100–700 K, Neorg. Mater., 2000, vol. 36, no. 7, pp. 810–816 [Inorg. Mater. (Engl. Transl.), vol. 36, no. 7, pp. 672–677].

    Google Scholar 

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Correspondence to L. D. Ivanova.

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Original Russian Text © L.D. Ivanova, L.I. Petrova, Yu.V. Granatkina, V.S. Zemskov, O.B. Sokolov, S.Ya. Skipidarov, N.I. Duvankov, 2009, published in Neorganicheskie Materialy, 2009, Vol. 45, No. 2, pp. 159–164.

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Ivanova, L.D., Petrova, L.I., Granatkina, Y.V. et al. Extruded thermoelectric materials based on Bi2Te3-Bi2Se3 solid solutions. Inorg Mater 45, 123–128 (2009). https://doi.org/10.1134/S0020168509020034

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  • DOI: https://doi.org/10.1134/S0020168509020034

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