Abstract
Extruded n-type materials based on Bi2Te3-Bi2Se3 alloys containing 6 to 40 mol % Bi2Se3 have been investigated using microstructural analysis and thermoelectric measurements at room temperature and in the range 100–400 K. Their electrical properties have been compared to those of single-crystal analogs. Compositions have been found at which the extruded materials offer the highest thermoelectric performance in different temperature ranges.
Similar content being viewed by others
References
Chizhevskaya, S.N., Shelimova, L.E., Kosyakov, V.I., and Shestakov, V.A., Critical Evaluation and Optimization of Data on the Bi-Te-Se Phase Diagram and Crystal Structure of Bi2Te3-Bi2Se3 Alloys, Neorg. Mater., 1997, vol. 33, no. 8, pp. 903–911 [Inorg. Mater. (Engl. Transl.), vol. 33, no. 12, pp. 757–764].
Sokolov, O.B., Skipidarov, S.Ya., Duvankov, N.I., and Shabunina, G.G., Phase Relations and Thermoelectric Properties of Alloys in the Bi2Te3-Bi2Se3 System, Neorg. Mater., 2007, vol. 43, no. 1, pp. 10–13 [Inorg. Mater. (Engl. Transl.), vol. 43, no. 1, pp. 8–11].
Gordyakova, G.N., Kokosh, G.V., and Sinani, S.S., Thermoelectric Properties of Bi2Te3-Bi2Se3 Solid Solutions, Zh. Tekh. Fiz., 1958, vol. 28, no. 1, pp. 3–17.
Gol’tsman, B.M., Kudinov, V.A., and Smirnov, I.A., Poluprovodnikovye termoelektricheskie materialy na osnove Bi2Te3 (Bi2Te3-Based Thermoelectric Semiconductor Materials), Moscow: Nauka, 1972.
Bankina, V.F. and Abrikosov, N.Kh., System Bi2Te3-Bi2Se3, Zh. Neorg. Khim., 1964, vol. 9, no. 4, pp. 931–936.
Miller, G.R., Che-Yu Li, and Spencer, C.W., Properties of Bi2Te3-Bi2Se3 Alloys, J. Appl. Phys., 1963, vol. 34, no. 5, pp. 1398–1400.
Svechnikova, T.E., Konstantinov, P.P., and Alekseeva, G.T., Physical Properties of Bi2Te2.85Se0.15 Single Crystals Doped with Cu, Cd, In, Ge, S, or Se, Neorg. Mater., 2000, vol. 36, no. 6, pp. 677–681 [Inorg. Mater. (Engl. Transl.), vol. 36, no. 6, pp. 556–560].
Spitsyn, V.I., Agafonova, L.A., Arakelyan, V.S., et al., Some Aspects of Diffusion in Sb2Te3-Bi2Te3 Materials Plastically Deformed by Hot Extrusion, Dokl. Akad. Nauk SSSR, 1978, vol. 238, no. 3, pp. 569–572.
Sokolov, O.B., Skipidarov, S.Ya., Duvankov, N.I., and Shabunina, G.G., Physical-Chemical Characterization of the Processes Occurring in Extrusion and Their Effect on Phase Diagram and Thermoelectric Properties of the Materials in Bi2Te3-Bi2Se3 and Sb2Te3-Bi2Te3 Systems, Proc. 5th Eur. Conf. on Thermoelectrics, Odessa, 2007, pp. 140–143.
Ravich, Yu.I., Efimova, B.A., and Smirnov, I.A., Metody issledovaniya poluprovodnikov v primenenii k khal’kogenidam svintsa (Semiconductor Characterization Techniques with Application to the Lead Chalcogenides PbTe, PbSe, and PbS), Moscow: Nauka, 1968.
Ivanova, L.D. and Granatkina, Yu.V., Thermoelectric Properties of Bi2Te3-Sb2Te3 Single Crystals in the Range 100–700 K, Neorg. Mater., 2000, vol. 36, no. 7, pp. 810–816 [Inorg. Mater. (Engl. Transl.), vol. 36, no. 7, pp. 672–677].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.D. Ivanova, L.I. Petrova, Yu.V. Granatkina, V.S. Zemskov, O.B. Sokolov, S.Ya. Skipidarov, N.I. Duvankov, 2009, published in Neorganicheskie Materialy, 2009, Vol. 45, No. 2, pp. 159–164.
Rights and permissions
About this article
Cite this article
Ivanova, L.D., Petrova, L.I., Granatkina, Y.V. et al. Extruded thermoelectric materials based on Bi2Te3-Bi2Se3 solid solutions. Inorg Mater 45, 123–128 (2009). https://doi.org/10.1134/S0020168509020034
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168509020034