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Production and dielectric properties of lead-free ceramics with the formula [(Na0.5K0.5)1 − x Li x ](Nb1 − yz Ta y Sb z )O3

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Abstract

The influence of past history on the possibility of obtaining high-density ferroelectric ceramics of solid solutions [(Na0.5K0.5)1 − x Li x ](Nb1 − yz Ta y Sb z )O at x = 0–0.14, y = 0, 0.1, 0.2, and z = 0–0.1 is identified. The dynamics of behavior of materials under a field in the process of polarization is evaluated. The relative dielectric permeability of samples in a wide range of temperatures (20–700°C) and frequencies (25 Hz-1 MHz) of a variable electric field is studied. On the basis of study of dielectric, piezoelectric, and elastic properties of solid solutions, prospective objects for further technological elaboration and modification of chemical composition with the goal of improving the electrophysical parameters are selected.

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References

  1. Cross, E., Lead-Free at Last, NATURE, 2004, vol. 432, No 4, pp. 24–25.

    CAS  Google Scholar 

  2. Directive 2002 / 95 / EC of the European Parliament and of Council of 27 January 2003 on the Restriction of the Use of Certain Hazardous Substances in Electronic Equipment, Off. J. Eur. Union., 2003, No 37, pp. 19–23.

  3. Ivliev, M.P., Raevskiy, I.P., Reznitchenko, L.A., et. al., Phase States and Specificity of Dielectric Properties of Solid Solutions of Natrium-Potassium Niobates, PTT, 2003, vol. 45, No 10, pp. 1886–1891.

    Google Scholar 

  4. Yaffe, B., Cook, U., Yaffe, G., Piezoelectric Ceramics, Moscow, Mir, 1974, 288 p.

    Google Scholar 

  5. Lin, D., Kwok, K.W., Lam, K.H. et al., Structure, Piezoelectric and Ferroelectric Properties of Li- and Sb-Modified K0.5Na0.5NbO3 Lead-Free Ceramics, J. Phys. D: Appl. Phys., 2007, vol. 40, pp. 3500–3505.

    Article  CAS  Google Scholar 

  6. Yang, Z., Chang, Y., Wei, L., Phase Transitional Behavior and Electrical Properties of Lead-Free (K0.44Na0.52Li0.04)(Nb0.96-x TaxSb0.04)O3 Piezoelectric Ceramics, Appl. Phys. Lett., 2007, vol. 90, pp. 042911-1-3.

  7. Guo, Y., Kakimoto, K., Ohsato, H., (Na0.5K0.5)NbO3-LiNbO3 Lead-Free Piezoelectric Ceramics, Mater. Lett., 2005, V. 59, pp. 241–244.

    Article  CAS  Google Scholar 

  8. Verbenko, I.A., Razumovskaya O.N., Shilkina L.A., Lead-Free Ceramics on the Basis of Solid Solutions on Multicomponent System with the Composition [(Na0.5K0.5)1 − x Lix](Nb1 − yz TaySbz)O3, Materials of X Int. Interdiscipl. Symp. “Order, disorder and oxide properties (ODPO-2007)”, Loo vil., Rostov-on-Don, 2007, pp. 140–144.

    Google Scholar 

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Original Russian Text © I.A. Verbenko, O.N. Razumovskaya, L.A. Shilkina, L.A. Reznichenko, K.P. Andryushin, 2009, published in Neorganicheskie Materialy, 2009, Vol. 45, No. 6, pp. 762–768.

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Verbenko, I.A., Razumovskaya, O.N., Shilkina, L.A. et al. Production and dielectric properties of lead-free ceramics with the formula [(Na0.5K0.5)1 − x Li x ](Nb1 − yz Ta y Sb z )O3 . Inorg Mater 45, 702–708 (2009). https://doi.org/10.1134/S0020168509060211

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  • DOI: https://doi.org/10.1134/S0020168509060211

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