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Influence of bismuth and calcium on the luminescence intensity of NaY1 − x Eu x (MoO4)2 phosphors

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Abstract

We have studied the effect of Bi3+ and Ca2+ cation additions and partial Si, P, and V substitutions for Mo on the photoluminescence of NaY1−x Eu x (MoO4)2 scheelite-like red phosphors. The results demonstrate that the photoluminescence intensity in NaY1 − x Eux(MoO4)2 doped with Bi3+ and Ca2+ increases with europium concentration, up to x = 0.5, without concentration quenching. When the atomic fraction of Bi3+ is 0.2, it has a sensitizing effect on Eu3+. Ca2+ doping to an atomic fraction of 0.45 also increases the photoluminescence intensity. Partial Si, P, and V substitutions for Mo have little effect on the photoluminescence intensity.

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References

  1. Sokolov, V.V. and Uskov, E.M., High-Color-Rendering Bright Red Phosphor Based on NaY1 − x Eux(MoO4)2, Khim. Interesakh Ustoich. Razvit., 2000, vol. 8, nos. 1–2, pp. 281–284.

    CAS  Google Scholar 

  2. Liua Jie, Liana Hongzhou, and Shia Chunshan, Improved Optical Photoluminescence by Charge Compensation in the Phosphor System CaMoO4:Eu3+, Opt. Mater., 2007, vol. 29, no. 12, pp. 1591–1594.

    Article  Google Scholar 

  3. Wanga Zhengliang, Liang Hongbin, Gong Menglian, and Sua Qiang, Luminescence Investigation of Eu3+ Activated Double Molybdates Red Phosphors with Scheelite Structure, J. Alloys Compd., 2007, vol. 432, nos. 1–2, pp. 308–312.

    Article  Google Scholar 

  4. Yan Bing and Wua Jian-Hua, NaY(MoO4)2:Eu3+ and NaY0.9Bi0.1(MoO4)2:Eu3+ Submicrometer Phosphors: Hydrothermal Synthesis Assisted by Room Temperature Solid State Reaction, Microstructure and Photoluminescence, Mater. Chem. Phys., 2009, vol. 116, no. 1, pp. 67–71.

    Article  CAS  Google Scholar 

  5. Haque Masuqul, Lee Hong-In, and Kim Dong-Kuk, Luminescent Properties of Eu3+-Activated Molybdate-Based Red-Emitting Phosphors for LEDs, J. Alloys Compd., 2009, vol. 481, nos. 1–2, pp. 792–796.

    Article  CAS  Google Scholar 

  6. Tsybulya, S.V., Cherepanova, S.V., and Solov’eva, S.P., Polikristall Software Package for IBM/PC, Zh. Strukt. Khim., 1996, vol. 37, no. 2, pp. 379–382.

    CAS  Google Scholar 

  7. Chi, L.S., Liu, R.S., and Lee, B.G., Synthesis of Y2O3:Eu,Bi Red Phosphors by Homogeneous Coprecipitation and Their Photoluminescence Behaviors, J. Electrochem. Soc., 2005, vol. 152, no. 8, pp. 93–98.

    Article  Google Scholar 

  8. Strel’tsov, A.V., Dmitrienko, V.P., Akmaeva, T.A., et al., The Influence of Activation of Y2O3 Polycrystalline Matrices by Bi3+ Ions on the Luminescence of Y2O3:Eu3+, Inorg. Mater., 2009, vol. 45, no. 8, pp. 889–893.

    Article  Google Scholar 

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    E. S. Zolotova, M. I. Rakhmanova, V. V. Sokolov & E. M. Uskov

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  1. E. S. Zolotova
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  2. M. I. Rakhmanova
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  3. V. V. Sokolov
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  4. E. M. Uskov
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Correspondence to E. S. Zolotova.

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Original Russian Text © E.S. Zolotova, M.I. Rakhmanova, V.V. Sokolov, E.M. Uskov, 2011, published in Neorganicheskie Materialy, 2011, Vol. 47, No. 11, pp. 1368–1371.

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Zolotova, E.S., Rakhmanova, M.I., Sokolov, V.V. et al. Influence of bismuth and calcium on the luminescence intensity of NaY1 − x Eu x (MoO4)2 phosphors. Inorg Mater 47, 1249–1252 (2011). https://doi.org/10.1134/S0020168511100244

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  • DOI: https://doi.org/10.1134/S0020168511100244

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