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Thermodynamic properties of Ca1 − x Er x F2 + x and Ca1 − x Yb x F2 + x heterovalent solid solutions

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The heat capacity of single crystals of the Ca1 − x Er x F2 + x (x = 0.05, 0.10) and Ca0.95Yb0.05F2.05 fluorite solid solutions was determined by adiabatic calorimetry in the temperature range 55–300 K. The results were used to obtain temperature dependences of the Debye characteristic temperature, entropy, and enthalpy for the solid solutions.

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Correspondence to N. V. Moiseev.

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Original Russian Text © N.V. Moiseev, P.A. Popov, P.P. Fedorov, E.A. Garibin, V.M. Reiterov, 2013, published in Neorganicheskie Materialy, 2013, Vol. 49, No. 3, pp. 333–336.

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Moiseev, N.V., Popov, P.A., Fedorov, P.P. et al. Thermodynamic properties of Ca1 − x Er x F2 + x and Ca1 − x Yb x F2 + x heterovalent solid solutions. Inorg Mater 49, 325–328 (2013). https://doi.org/10.1134/S0020168513030126

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  • DOI: https://doi.org/10.1134/S0020168513030126

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