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Thermoelectric properties of a eutectic SnSe2-Bi2Se3 alloy

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Abstract

Data are presented which confirm that the SnSe2-Bi2Se3 system has a eutectic phase diagram, with a eutectic at 67 mol % SnSe2, melting at 831 ± 5 K. The thermoelectric properties of the eutectic alloy in this system have been studied for the first time in the temperature range 300–600 K. The results demonstrate that this alloy is a promising low-temperature thermoelectric material: its minimal thermal conductivity (χmin) and maximum thermoelectric figure of merit (ZT max) are 0.28 W/(m K) (416 K) and 0.56 (593 K), respectively.

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References

  1. Shevel’kov, A.V., Chemical aspects of designing thermoelectric materials, Usp. Khim., 2008, vol. 77, no. 1, pp. 3–21.

    Google Scholar 

  2. Eremina, A.F., Tagirov, V.I., Aliev, S.A., and Shakhtakhtinskii, M.G., Thermal conductivity of the GaSb-Ge system, Phys. Status Solidi A, 1970, vol. 3, no. 1, pp. 33–36.

    Article  CAS  Google Scholar 

  3. Kozma, A.A., Peresh, E.Yu., Barchiy, I.E., Sabov, M.Yu., Betsa, V.V., and Tsygyka, V.V., Thermoelectric properties of eutectic TlBiSe2-SnSe2 (Tl2SnSe3, Tl4SnSe4) and Tl4SnSe4-Tl9BiSe6 alloys, Ukr. Khim. Zh., 2011, vol. 77, no. 9, pp. 23–26.

    CAS  Google Scholar 

  4. Leonov, V.V. and Spektor, Yu.E., Thermoelectric properties of a eutectic Ge-GaAs alloy, Izv. Akad. Nauk SSSR, Neorg. Mater., 1980, vol. 16, no. 8, pp. 1358–1360.

    CAS  Google Scholar 

  5. Chizhevskaya, S.N., Shelimova, L.E., and Zaitseva, I.A., Critical analysis and matching of data on the phase diagram of the Bi-Se system, Inorg. Mater., 1994, vol. 30, no. 11, pp. 1285–1292.

    Google Scholar 

  6. Kyung-Min Chung, Wamwangi, D., Woda, M., Wuttig, M., and Bensch, W., Investigation of SnSe, SnSe2 and Sn2Se3 alloys for phase change memory applications, J. Appl. Phys., 2008, vol. 103, no. 8, paper 083 523.

    Google Scholar 

  7. Sher, A.A., Odin, I.N., and Novoselova, A.V., Influence of Cd, Sn and their selenides on the thermoelectric properties of bismuth selenides, Izv. Akad. Nauk SSSR, Neorg. Mater., 1984, vol. 20, no. 8, pp. 1287–1290.

    CAS  Google Scholar 

  8. Nasibov, I.O., Sultanov, T.I., Rustamov, P.G., and Alidzhanov, M.A., Physical properties of solid-solution alloys in the system Ce2Se3-SnSe2, Izv. Akad. Nauk SSSR, Neorg. Mater., 1977, vol. 13, no. 6, pp. 982–985.

    CAS  Google Scholar 

  9. Sher, A.A., Odin, I.N., and Novoselova, A.V., Phase relations in the system Sn-Bi-Se, Izv. Akad. Nauk SSSR, Neorg. Mater., 1978, vol. 14, no. 7, pp. 1270–1276.

    CAS  Google Scholar 

  10. Egunov, V.P., Vvedenie v termicheskii analiz (Introduction to Thermal Analysis), Samara: SamVen, 1996.

    Google Scholar 

  11. Kovba, L.M., Rentgenografiya v neorganicheskoi khimii (X-Ray Diffraction in Inorganic Chemistry), Moscow: Mosk. Gos. Univ., 1991.

    Google Scholar 

  12. Nolze, G. and Kraus, W., Powdercell 2.0 for Windows, Powder Diffr., 1998, vol. 13, no. 4, pp. 255–259.

    Article  Google Scholar 

  13. Harman T.C., Cahn, J.H., and Logan, M.J., Measurement of thermal conductivity by utilization of the Peltier effect, J. Appl. Phys., 1959, vol. 30, no. 9, pp. 1351–1359.

    Article  CAS  Google Scholar 

  14. Goldsmid, H.J., Direct thermoelectric figure of merit measurement experiments, Termoelektrichestvo, 2006, no. 1, pp. 5–15.

    Google Scholar 

  15. Ioffe, A.F., Poluprovodnikovye termoelementy (Semiconductor Thermoelements), Moscow: Fizmatgiz, 1956.

    Google Scholar 

  16. Yamanaka, S., Kurosaki, K., Kosuga, A., Goto, K., and Muta, H., Extremely low thermal conductivity substances as novel thermoelectric materials, MRS Proc., 2005, vol. 886, paper 0886-F09-05.

  17. Cham Kim, Dong Hwan Kim, Yoo Soo Han, Jong Shik Chung, Sang Ha Park, and Hogoung Kim, Fabrication of bismuth telluride nanoparticles using a chemical synthetic process and their thermoelectric evaluations, Powder Technol., 2011, vol. 214, no. 3, pp. 463–468.

    Article  CAS  Google Scholar 

  18. Yan-Ling Pei and Yong Liu, Electrical and thermal transport properties of Pb_based chalcogenides: PbTe, PbSe, and PbS, J. Alloys Compd., 2012, vol. 514, pp. 40–44.

    Article  Google Scholar 

  19. Gol’tsman, B.M., Sarkisyan, V.Sh., Stil’bans, L.S., and Shlykov, V.V., Influence of pores and grain boundaries on the electrical and thermal conductivity of thermoelectric materials, Izv. Akad. Nauk SSSR, Neorg. Mater., 1969, vol. 5, no. 2, pp. 283–286.

    Google Scholar 

  20. Kozma, A.A., Barchiy, I.E., Peresh, E.Yu., Sabov, M.Yu., Betsa, V.V., and Tsygyka, V.V., Ukr. Patent 98368, Byull. Izobret., 2012, no. 9.

    Google Scholar 

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Correspondence to A. A. Kozma.

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Original Russian Text © A.A. Kozma, M.Yu. Sabov, E.Yu. Peresh, I.E. Barchiy, V.V. Tsygyka, 2015, published in Neorganicheskie Materialy, 2015, Vol. 51, No. 2, pp. 131–136.

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Kozma, A.A., Sabov, M.Y., Peresh, E.Y. et al. Thermoelectric properties of a eutectic SnSe2-Bi2Se3 alloy. Inorg Mater 51, 93–97 (2015). https://doi.org/10.1134/S0020168515010082

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  • DOI: https://doi.org/10.1134/S0020168515010082

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