Skip to main content
SpringerLink
Log in

Effect of the nature of the active component and support on the activity of catalysts for the hydrolysis of sodium borohydride

  • Young Scientists’ School
  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The effect of the nature of an active component and a support on the rate of hydrolysis of aqueous sodium borohydride solutions was studied. It was found that the activity of supported catalysts, which were reduced in a reaction medium of sodium borohydride, decreased in the order Rh > Pt ≈ Ru ≫ Pd regardless of the nature of the support (γ-Al2O3, a Sibunit carbon material, or TiO2). The catalysts based on TiO2 exhibited the highest activity. As found by UV-vis diffuse reflectance spectroscopy, the composition and structure of the supported precursor of an active component depend on the nature of the support. It is likely that rhodium clusters with different reaction properties were formed on various supports under the action of a reaction medium.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Brown, H.C. and Brown, C.A., J. Am. Chem. Soc., 1962, vol. 84, p. 1493.

    Article  CAS  Google Scholar 

  2. Amendola, S.C., Sharp-Goldman, S.L., Janjua, M.S., Spencer, N.C., Kelly, M.T., Petillo, P.J., and Binger, M., Int. J. Hydrogen Energy, 2000, vol. 25, p. 969.

    Article  CAS  Google Scholar 

  3. Amendola, S.C., Sharp-Goldman, S.L., Janjua, M.S., Kelly, M.T., Petillo, P.J., and Binger, M., J. Power Sources, 2000, vol. 85, p. 186.

    Article  CAS  Google Scholar 

  4. Kojima, Y., Suzuki, K., Fukumoto, K., Sasaki, M., Yamamoto, T., Kawai, Y., and Hayashi, H., Int. J. Hydrogen Energy, 2002, vol. 27, p. 1029.

    Article  CAS  Google Scholar 

  5. Kojima, Y., Kawai, Y., Nakanishi, H., and Matsumoto, S., J. Power Sources, 2004, vol. 135, p. 36.

    Article  CAS  Google Scholar 

  6. Krishnan, P., Yang, T.H., Lee, W.Y., and Kim, C.S., J. Power Sources, 2005, vol. 143, p. 17.

    Article  CAS  Google Scholar 

  7. Hua, D., Hanxi, Y., Xinping, A., and Chuansin, C., Int. J. Hydrogen Energy, 2003, vol. 28, p. 1095.

    Article  Google Scholar 

  8. Kim, J.H., Lee, H., Han, S.C., Kim, H.S., Song, M.S., and Lee, J.Y., Int. J. Hydrogen Energy, 2004, vol. 29, p. 263.

    Article  Google Scholar 

  9. US Patent 4978649, 1990.

  10. Schlesinger, H.I., Brown, H.C., Finholt, A.E., Gilbreath, J.R., Hockstra, H.R., and Hyde, E.K., J. Am. Chem. Soc., 1953, vol. 75, p. 215.

    Article  CAS  Google Scholar 

  11. Prokopchik, A.Yu., Val’syunene, Ya.I., and Vinkyavichyus, I.I., Tr. Akad. Nauk Lit. SSR, Ser. C, 1976, vol. 93, no. 4, p. 3.

    Google Scholar 

  12. Dragieva, I.D., Stoynov, Z.B., and Klabunde, K.J., Scr. Mater., 2001, vol. 44, p. 2187.

    Article  CAS  Google Scholar 

  13. Prokopchik, A.Yu. and Val’syunene, Ya.I., Tr. Akad. Nauk Lit. SSR, Ser. C, 1974, vol. 83, no. 4, p. 11.

    Google Scholar 

  14. Prokopchik, A.Yu., Val’syunene, Ya.I., and Kashkyalis, A.S., Tr. Akad. Nauk Lit. SSR, Ser. C, 1977, vol. 103, no. 6, p. 3.

    Google Scholar 

  15. Prokopchik, A.Yu., Val’syunene, Ya.I., and Norgailaite, A.Yu., Tr. Akad. Nauk Lit. SSR, Ser. C, 1974, vol. 84, no. 5, p. 17.

    Google Scholar 

  16. Carson, A.W., Flanagan, T.B., and Lewis, F.A., Trans. Faraday Soc., 1960, vol. 56, p. 371.

    Article  CAS  Google Scholar 

  17. Dragieva, I., Mehandjiev, D., Lefterova, E., Stoycheva, M., and Stoynov, Z., J. Magn. Magn. Mater., 1995, vol. 140–144, p. 455.

    Article  Google Scholar 

  18. Varushchenko, V.M., Polkovnikov, B.D., Bogdanovskii, G.A., and Akimov, V.M., Izv. Akad. Nauk SSSR, Ser. Khim., 1972, no. 7, p. 1662.

  19. Lever, A.B.P., Inorganic Electronic Spectroscopy, Amsterdam: Elsevier, 1987, p. 2.

    Google Scholar 

  20. Paulhiac, J.L. and Clause, O., J. Am. Chem. Soc., 1993, vol. 115, p. 11 602.

    Article  CAS  Google Scholar 

  21. Hwang, C.P., Yeh, C.T., and Zhu, Q., Catal. Today, 1999, vol. 51, p. 93.

    Article  CAS  Google Scholar 

  22. Herrmann, J.M., J. Catal., 1984, vol. 89, p. 404.

    Article  CAS  Google Scholar 

  23. Hess, A. and Kemnitz, E., Appl. Catal., A, 1997, vol. 149, p. 379.

    Google Scholar 

  24. Ivanov, A.V., Kustov, L.M., Vasina, T.V., Kazanskii, V.B., and Zoiten, P., Kinet. Katal., 1997, vol. 38, no. 3, p. 438 [Kinet. Catal. (Engl. Transl.), vol. 38, no. 3, p. 403].

    Google Scholar 

  25. Stakheev, A.Yu. and Kustov, L.M., Appl. Catal., A, 1999, vol. 188, p. 3.

    Article  CAS  Google Scholar 

  26. Komova, O.V., Simakov, A.V., Rogov, V.A., Kochubei, D.I., Odegova, G.V., Kriventsov, V.V., Paukshtis, E.A., Ushakov, V.A., Sazonova, N.N., and Nikoro, T.A., J. Mol. Catal. A: Chem., 2000, vol. 161, p. 191.

    Article  CAS  Google Scholar 

  27. Odegova, G.V. and Slavinskaya, E.M., Kinet. Katal., 2004, vol. 45, no. 1, p. 146 [Kinet. Catal. (Engl. Transl.), vol. 45, no. 1, p. 133].

    Google Scholar 

  28. Komova, O.V., Cand. Sci. (Chem.) Dissertation, Novosibirsk: Inst. of Catalysis, 2000.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. I. Simagina, O. V. Netskina, O. V. Komova, G. V. Odegova, T. Yu. Samoilenko & A. G. Gentsler

  2. State Research Institute of Chemistry and Technology of Organoelement Compounds, Moscow, 111123, Russia

    P. A. Storozhenko

Authors
  1. V. I. Simagina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. A. Storozhenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. O. V. Netskina
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. O. V. Komova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. G. V. Odegova
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. T. Yu. Samoilenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. A. G. Gentsler
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Original Russian Text © V.I. Simagina, P.A. Storozhenko, O.V. Netskina, O.V. Komova, G.V. Odegova, T.Yu. Samoilenko, A.G. Gentsler, 2007, published in Kinetika i Kataliz, 2007, Vol. 48, No. 1, pp. 177–184.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Simagina, V.I., Storozhenko, P.A., Netskina, O.V. et al. Effect of the nature of the active component and support on the activity of catalysts for the hydrolysis of sodium borohydride. Kinet Catal 48, 168–175 (2007). https://doi.org/10.1134/S0023158407010223

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0023158407010223

Keywords

Search

Navigation