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Allylic isomerization of allylbenzene on nanosized gold particles

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Abstract

Nanosized gold particles immobilized on γ-Al2O3 exhibited catalytic activity in the allylic isomerization reaction of allylbenzene. As the size of gold nanoparticles was decreased from 40 to 2 nm, their specific activity per surface gold atom nonmonotonically increased from 0.5 to 110 (mol products) (mol Ausurface)−1 h−1. The particles greater than 40 nm were practically inactive.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119992, Russia

    V. V. Smirnov, S. A. Nikolaev, G. P. Murav’eva & L. A. Tyurina

  2. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

    A. Yu. Vasil’kov

Authors
  1. V. V. Smirnov
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  2. S. A. Nikolaev
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  3. G. P. Murav’eva
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  4. L. A. Tyurina
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  5. A. Yu. Vasil’kov
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Additional information

Original Russian Text © V.V. Smirnov, S.A. Nikolaev, G.P. Murav’eva, L.A. Tyurina, A.Yu. Vasil’kov, 2007, published in Kinetika i Kataliz, 2007, Vol. 48, No. 2, pp. 281–286.

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Smirnov, V.V., Nikolaev, S.A., Murav’eva, G.P. et al. Allylic isomerization of allylbenzene on nanosized gold particles. Kinet Catal 48, 265–270 (2007). https://doi.org/10.1134/S0023158407020103

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  • DOI: https://doi.org/10.1134/S0023158407020103

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