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Mn–Ce/beta “bifunctional” catalyst for the selective catalytic reduction of nitrogen oxides with ammonia

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Abstract

The properties of the Mn–Ce/Beta zeolite catalyst in the selective catalytic reduction (SCR) of NO x have been investigated. The introduction of Ce leads to a marked increase in the NO x conversion at 100–250°C. The data of this study are consistent with the “bifunctional” pathway of SCR suggested for Mn/Beta, which consists of two stages—NO oxidation to NO2 over the oxide component and “fast” SCR over the zeolite. The increased activity of Mn–Ce/Beta at the NO-to-NO2 oxidation stage is due to the formation of MnCeO x mixed oxides enhancing the mobility of lattice oxygen. The determining role is played by the activity of the zeolite component in the “fast” SCR reaction.

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Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    D. S. Krivoruchenko, N. S. Telegina, D. A. Bokarev & A. Yu. Stakheev

Authors
  1. D. S. Krivoruchenko
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  2. N. S. Telegina
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  3. D. A. Bokarev
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  4. A. Yu. Stakheev
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Corresponding author

Correspondence to A. Yu. Stakheev.

Additional information

Original Russian Text © D.S. Krivoruchenko, N.S. Telegina, D.A. Bokarev, A.Yu. Stakheev, 2015, published in Kinetika i Kataliz, 2015, Vol. 56, No. 6, pp. 729–734.

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Krivoruchenko, D.S., Telegina, N.S., Bokarev, D.A. et al. Mn–Ce/beta “bifunctional” catalyst for the selective catalytic reduction of nitrogen oxides with ammonia. Kinet Catal 56, 741–746 (2015). https://doi.org/10.1134/S0023158415060051

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  • DOI: https://doi.org/10.1134/S0023158415060051

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