Abstract
We have studied the spectral properties of mixtures formed by CdS colloidal quantum dots with an average diameter of 2.5 nm and methylene blue molecules and that are dispersed into gelatin. We have revealed that, in the presence of CdS quantum dots, the luminescence intensity of methylene blue increases. We suggest a model of this effect, which is based on electronic excitation energy transfer from luminescence centers of CdS quantum dots to methylene blue molecules.
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K. R. Choudhury, F. So, and Z. Kafafi, Compreh. Nanosci. Technol. 4(7), 193 (2011).
M. Nyk, K. Palewska, L. Kepinski, K. A. Wilk, W. Strek, and M. Samos, J. Lumin. 130(12), 2487 (2010).
V. M. Agranovich, Yu. N. Gartstein, and M. Litinskaya, Chem. Rev. 111, 5179 (2011).
A. Rakovich, D. Savateeva, T. Rakovich, J. F. Donegan, Y. P. Rakovich, V. Kelly, V. Lesnyak, and A. Eychmuller, Nanoscale Res. Lett. 5, 753 (2010).
Jhonsi M. Asha, A. Kathiravan, and R. Renganathan, J. Mol. Struct. 921(1–3), 279 (2009).
J. E. Halpert, J. R. Tischler, G. Nair, B. J. Walker, W. Liu, V. Bulovic, and M. G. Bawendi, J. Phys. Chem. 113(23), 9986 (2009).
B. J. Walker, V. Bulovic, and M. G. Bawendi, Nano Lett. 10(10), 3995 (2010).
B. J. Walker, G. Nair, L. F. Marshall, V. Bulovic, and M. G. Bawendi, J. Am. Chem. Soc. 131(28), 9694 (2009).
F. L. Xue, J. Y. Chen, J. Guo, C. C. Wang, W. L. Yang, P. N. Wang, and D. R. Lu, J. Fluoresc. 17(2), 149 (2007).
Y. Zhang, L. Mi, R. Xiong, P. N. Wang, J.-Y. Chen, W. Yang, C. Wang, and Q. Peng, Nanoscale Res. Lett. 4(7), 606 (2009).
E. I. Zenkevich, T. Blaudeck, A. M. Shulga, F. Cichos, and C. von Borczyskowski, J. Lumin. 122–123, 784 (2007).
E. I. Zen’kevich, E. I. Sagun, A. A. Yarovoi, A. M. Shul’ga, V. N. Knyukshto, A. V. Stupak, and K. Bortsiskovski, Opt. Spektrosk. 103(6), 998 (2007).
A. O. Orlova, V. G. Maslov, A. A. Stepanov, I. Gounko, and A. V. Baranov, Opt. Spektrosk. 105(6), 998 (2008).
O. Schmeltz, A. Mews, T. Basche, A. Hermann, and K. Mullen, Langmuir 17, 2867 (2001).
A. V. Baranov, Yu. P. Rakovich, J. F. Donegan, T. S. Perova, R. A. Moore, D. V. Talapin, A. L. Rogach, Y. Masumoto, and I. Nabiev, Phys. Rev. 68, 165306 (2003).
P. Reiss, M. Protiere, and L. Li, Small 5(2), 154 (2009).
M. Idowu, Ji-Y. Chenab, and T. Nyokong, New J. Chem. 32, 290 (2008).
O. E. Rayevska, G. Ya. Grodzyuk, V. M. Dzhcagan, et al., J. Phys. Chem. 114(51), 22478 (2010).
O. V. Ovchinnikov, M. S. Smirnov, B. I. Shapiro, A. N. Latyshev, T. S. Shatskikh, E. E. Bordyuzha, and S. A. Soldatenko, Teor. Eksp. Khim. 48(1), 43 (2012).
M. S. Smirnov, O. V. Ovchinnikov, E. A. Kosyakova, A. N. Latyshev, A. F. Klinskikh, E. P. Tat’yanina, and P. V. Novikov, Physica B: Cond. Mat. 404, 5013 (2009).
A. I. Ekimov, I. A. Kudryavtsev, M. G. Ivanov, and Al. L. Efros, J. Lumin. 46, 83 (1990).
S. K. Lee and A. Mills, J. Fluorescence 13(5), 375 (2003).
S. Basu, S. Panigrahi, S. Praharaj, S. K. Chosh, S. Pande, S. Jana, A. Pal, and T. Pal, J. Phys. Chem. A 111, 578 (2007).
K. Bergman and C. T. O’Konski, J. Phys. Chem. 67, 2169 (1963).
G. S. Singhal and E. Rabinowitch, J. Phys. Chem. 71(10), 3347 (1967).
P. A. R. Tafulo, R. B. Queiros, and G. Gonzalez-Aguilar, Spectrochimica Acta A 73, 295 (2009).
W. H. Melhuish, J. Am. Chem. Soc. 65, 229 (1993).
J. Cenens and R. A. Schoonheydt, Clays Clay Miner. 36(3), 214 (1988).
Kh. L. Arvan and V. E. Kholmogorov, Dokl. Akad. Nauk SSSR 169(2), 365 (1966).
A. N. Terenin, Photonics of Dye Molecules and Related Organic Compounds (Nauka, Leningrad, 1967).
C. N. R. Rao, Ultra-Violet and Visible Spectroscopy: Chemical Applications (Butterworths, London, 1961; Mir, Moscow, 1964).
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Original Russian Text © O.V. Ovchinnikov, M.S. Smirnov, B.I. Shapiro, T.S. Shatskikh, A.N. Latyshev, Pham Thi Hai Mien, V.Yu. Khokhlov, 2013, published in Optika i Spektroskopiya, 2013, Vol. 115, No. 3, pp. 389–397.
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Ovchinnikov, O.V., Smirnov, M.S., Shapiro, B.I. et al. Spectral manifestations of hybrid association of CdS colloidal quantum dots with methylene blue molecules. Opt. Spectrosc. 115, 340–348 (2013). https://doi.org/10.1134/S0030400X1309018X
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DOI: https://doi.org/10.1134/S0030400X1309018X