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Destruction of Doped Lithium Tetraborate under Exposure to Ionizing and Laser Radiation

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Abstract

The results of the study of the degradation of thermoluminescent materials Li2B4O7:Be + Mn and Li2B4O7:Zn + Mn under the effect of radiation (pulsed electron beam) and laser radiation are presented. As a result of exposure to high doses of radiation, the structure of the samples under study partially acquires an amorphous character, while the effect of radiation exposure is manifested in the optical properties in the appearance of green luminescence due to manganese centers in the tetrahedral environment. With subsequent irradiation with a laser at a wavelength of 350 nm, luminescence centers decay due to photochemical oxidation of manganese by the reaction of Mn2+ → Mn3+. It is shown that Li2B4O7:Be + Mn has a lower radiation resistance than Li2B4O7:Zn + Mn.

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Funding

A. Selyukov is grateful for the support of the Russian Foundation for Basic Research within the framework of project no. 18-02-00811 A. The work is supported partly within the State Assignment of the Institute of Spectroscopy of the Russian Academy of Sciences and partly by the Russian Foundation for Basic Research, project no. 18-02-00811 A.

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Authors and Affiliations

  1. Institute of Spectroscopy, Russian Academy of Sciences, 108840, Troitsk, Moscow, Russia

    Yu. G. Vainer & Yu. A. Repeev

  2. National Research University Higher School of Economics, 101000, Moscow, Russia

    Yu. G. Vainer

  3. Lebedev Physical Institute, Russian Academy of Sciences, 119991, Moscow, Russia

    N. Yu. Vereshchagina, M. I. Danilkin, V. M. Korshunov & A. S. Selyukov

  4. Bauman Moscow State Technical University, 105005, Moscow, Russia

    V. M. Korshunov

  5. Moscow Institute of Physics and Technology, 141701, Dolgoprudnyi, Moscow oblast, Russia

    A. S. Selyukov

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  1. Yu. G. Vainer
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Translated by O. Zhukova

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Vainer, Y.G., Vereshchagina, N.Y., Danilkin, M.I. et al. Destruction of Doped Lithium Tetraborate under Exposure to Ionizing and Laser Radiation. Opt. Spectrosc. 127, 113–120 (2019). https://doi.org/10.1134/S0030400X19070257

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