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Transition-metal bimaleates and their solid solutions: Synthesis, structural, and thermoanalytical study

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Abstract

Transition-metal hydrogen maleates of composition M(C4H3O4)2 · 4H2O, where M = Mn, Fe, Co, and Ni, and their solid solutions were synthesized and characterized by X-ray crystallography, IR spectroscopy, mass spectrometry, and thermal analysis. X-ray crystallography and IR spectroscopy showed that both intramolecular and intermolecular H-bonds exist in these compounds. The generation of continuous substitutional solid solutions with cation substitution in these compounds was studied. The thermolysis mechanism was studied for both transition-metal hydrogen maleates and their solid solutions. The composite produced by thermolysis is stable up to 1200°C in flowing helium.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    L. I. Yudanova, V. A. Logvinenko, L. A. Sheludyakova, N. F. Yudanov, G. N. Chekhova, N. I. Alferova, V. I. Alekseev, P. P. Semyannikov & V. I. Lisoivan

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  1. L. I. Yudanova
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  2. V. A. Logvinenko
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  3. L. A. Sheludyakova
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  4. N. F. Yudanov
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  5. G. N. Chekhova
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  6. N. I. Alferova
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  7. V. I. Alekseev
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  8. P. P. Semyannikov
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  9. V. I. Lisoivan
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Additional information

Original Russian Text © L.I. Yudanova, V.A. Logvinenko, L.A. Sheludyakova, N.F. Yudanov, G. N. Chekhova, N.I. Alferova, V.I. Alekseev, P.P. Semyannikov, V.I. Lisoivan, 2008, published in Zhurnal Neorganicheskoi Khimii, 2008, Vol. 53, No. 9, pp. 1559–1565.

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Yudanova, L.I., Logvinenko, V.A., Sheludyakova, L.A. et al. Transition-metal bimaleates and their solid solutions: Synthesis, structural, and thermoanalytical study. Russ. J. Inorg. Chem. 53, 1459–1464 (2008). https://doi.org/10.1134/S0036023608090180

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  • DOI: https://doi.org/10.1134/S0036023608090180

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