Abstract
Phase formation of Bi4(V1 − x Cu x )2O11 − z solid solutions (BICUVOX) with x = 0.00–0.20 and Δx = 0.02 was studied. The concentration stability ranges were determined for the α, β, and γ polymorphs of BICUVOX solid solutions at room temperature, and their unit cell parameters were revised. The following was found to occur as x rises: the α ai β phase transition temperature between the monoclinic and orthorhombic phases shifts down, the β ai γ phase transition temperature to the high-temperature tetragonal phase shifts down, and the order-disorder phase transition temperature between γ′ ai γ tetragonal phases shifts up.
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Original Russian Text © V.V. Murasheva, N.A. Poletaeva, E.A. Fortalnova, M.G. Safronenko, E.D. Politova, V.V. Kurilkin, N.U. Venskovskii, 2010, published in Zhurnal Neorganicheskoi Khimii, 2010, Vol. 55, No. 12, pp. 1980–1986.
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Murasheva, V.V., Poletaeva, N.A., Fortalnova, E.A. et al. Phase formation of BICUVOX solid solutions. Russ. J. Inorg. Chem. 55, 1867–1873 (2010). https://doi.org/10.1134/S0036023610120090
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DOI: https://doi.org/10.1134/S0036023610120090