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Synthesis of nanocrystalline silicon carbide using the sol-gel technique

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Highly disperse silicon carbide is synthesized using a hybrid method comprising the sol-gel step to provide the SiO2-C starting mixture involving the formation of a transparent gel and carbothermal synthesis under relatively soft conditions, namely, at temperatures of 1200–1500°C under a dynamic vacuum. The elemental and phase compositions of the products and their thermal behavior in air are studied. A relationship is found to exist between the microstructure of the product, on the one hand, and the temperature and time of heat treatment, on the other.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    E. P. Simonenko, N. P. Simonenko, A. V. Derbenev, V. A. Nikolaev, V. G. Sevastyanov & N. T. Kuznetsov

  2. Moscow State University of Fine Chemical Technologies, pr. Vernadskogo 86, Moscow, 119571, Russia

    E. P. Simonenko

  3. All-Russia Institute of Aircraft Materials, Moscow, Russia

    D. V. Grashchenkov & E. N. Kablov

Authors
  1. E. P. Simonenko
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  2. N. P. Simonenko
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  3. A. V. Derbenev
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  4. V. A. Nikolaev
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  5. D. V. Grashchenkov
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  6. V. G. Sevastyanov
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  7. E. N. Kablov
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  8. N. T. Kuznetsov
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Additional information

Original Russian Text © E.P. Simonenko, N.P. Simonenko, A.V. Derbenev, V.A. Nikolaev, D.V. Grashchenkov, V.G. Sevastyanov, E.N. Kablov, N.T. Kuznetsov, 2013, published in Zhurnal Neorganicheskoi Khimii, 2013, Vol. 58, No. 10, pp. 1279–1288.

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Simonenko, E.P., Simonenko, N.P., Derbenev, A.V. et al. Synthesis of nanocrystalline silicon carbide using the sol-gel technique. Russ. J. Inorg. Chem. 58, 1143–1151 (2013). https://doi.org/10.1134/S0036023613100215

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  • DOI: https://doi.org/10.1134/S0036023613100215

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