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Hydrothermal Microwave Synthesis of MnO2 in the Presence of Melamine: The Role of Temperature and pH

  • Synthesis and Properties of Inorganic Compounds
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Abstract

Nanocrystalline manganese dioxide have been prepared by hydrothermal microwave treatment of mixed solutions of potassium permanganate and 2,4,6-triamino-1,3,5-triazine (melamine) in pH range 0.5–3. Phase and chemical composition and morphology of the samples was studied by XRD, Raman spectroscopy, and SEM. Conditions (solution pH and temperature) for the formation of single phase MnO2 powders (α-MnO2, γ-MnO2, δ-MnO2, and δ*-MnO2) under hydrothermal microwave treatment were determined.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, 119991, Russia

    O. S. Ivanova, A. D. Yapryntsev, A. E. Baranchikov & V. K. Ivanov

  2. Moscow State University, Moscow, 119991, Russia

    M. A. Teplonogova, A. E. Baranchikov & V. K. Ivanov

  3. Moscow Technological University, Moscow, 119571, Russia

    V. K. Ivanov

Authors
  1. O. S. Ivanova
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  2. M. A. Teplonogova
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  3. A. D. Yapryntsev
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  4. A. E. Baranchikov
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  5. V. K. Ivanov
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Corresponding author

Correspondence to A. E. Baranchikov.

Additional information

Original Russian Text © O.S. Ivanova, M.A. Teplonogova, A.D. Yapryntsev, A.E. Baranchikov, V.K. Ivanov, 2018, published in Zhurnal Neorganicheskoi Khimii, 2018, Vol. 63, No. 6, pp. 678–684.

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Ivanova, O.S., Teplonogova, M.A., Yapryntsev, A.D. et al. Hydrothermal Microwave Synthesis of MnO2 in the Presence of Melamine: The Role of Temperature and pH. Russ. J. Inorg. Chem. 63, 708–713 (2018). https://doi.org/10.1134/S0036023618060128

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  • DOI: https://doi.org/10.1134/S0036023618060128

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