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Synthesis of Ferrocyanide Sorbents in Polysaccharide Matrices

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

The data on the possibility of obtaining transition metal ferrocyanides, which are highly selective compounds with respect to cesium, in polysaccharide matrices (cellulose, chitin, chitosan) are systematized and generalized. Based on the electron microscopy data, it has been found that the distribution of the sorption active component (nickel ferrocyanide) in the chitosan matrix is fairly uniform. The crystallite sizes calculated from X-ray powder diffraction data are significantly higher for Zn–K chitosan/ferrocyanide sorbent as compared to Ni–K and Cu–K chitosan/ferrocyanide sorbents. A comparative analysis of the sorption properties and stabilities of the Zn–K, Zn–Ni, and Cu–K chitosan/ferrocyanide sorbents and sorbent Thermoxide-35 in the extraction of cesium from alkaline mineralized solutions and seawater has been carried out.

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ACKNOWLEDGMENTS

The authors thank head of the laboratory for micro- and nano-studies of the Far Eastern Geological Institute, Far Eastern Branch of the Russian Academy of Sciences, leading researcher Cand. Sci. (Geol. Mineral.) V.V. Ivanov for the electron microscopic studies.

Funding

The work was carried out in accordance with the research plan of the Institute of Chemistry, Far Eastern Branch of the Russian Academy of Sciences, topic no. 0205-20210002.

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Authors and Affiliations

  1. Institute of Chemistry, Far Eastern Branch, Russian Academy of Sciences, 690022, Vladivostok, Russia

    L. A. Zemskova, A. M. Egorin & E. A. Tokar

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  1. L. A. Zemskova
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  2. A. M. Egorin
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  3. E. A. Tokar
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Correspondence to L. A. Zemskova.

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Translated by V. Avdeeva

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Zemskova, L.A., Egorin, A.M. & Tokar, E.A. Synthesis of Ferrocyanide Sorbents in Polysaccharide Matrices. Russ. J. Inorg. Chem. 66, 1268–1274 (2021). https://doi.org/10.1134/S0036023621090175

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