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Sorption of sodium dodecyl sulfate by highly basic anion-exchange resins

  • Physical Chemistry of Separation Processes: Chromatography
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Abstract

The interaction in the system of sodium dodecyl sulfate (SDS) solution and AB-17 highly basic anion-exchange resins in OH and Cl forms were considered, and the distribution coefficients (K d) of the substance in the resin-solution ion exchange system were calculated. It was found that K d decreases with increasing concentration of the initial solution, reaching a maximum value at the critical micelle concentration (CMC) of SDS. The effective diffusion coefficients of the surfactant in the anion-exchange resin phase were calculated; based on the IR spectroscopy data, the mechanism of SDS absorption was proposed.

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Correspondence to S. I. Karpov.

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Original Russian Text © E.V. Bondareva, S.I. Karpov, V.F. Selemenev, V.N. Verezhnikov, E.V. Krokhina, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 12, pp. 2339–2346.

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Bondareva, E.V., Karpov, S.I., Selemenev, V.F. et al. Sorption of sodium dodecyl sulfate by highly basic anion-exchange resins. Russ. J. Phys. Chem. 83, 2136–2143 (2009). https://doi.org/10.1134/S0036024409120243

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  • DOI: https://doi.org/10.1134/S0036024409120243

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