Abstract
The interaction in the system of sodium dodecyl sulfate (SDS) solution and AB-17 highly basic anion-exchange resins in OH− and Cl− forms were considered, and the distribution coefficients (K d) of the substance in the resin-solution ion exchange system were calculated. It was found that K d decreases with increasing concentration of the initial solution, reaching a maximum value at the critical micelle concentration (CMC) of SDS. The effective diffusion coefficients of the surfactant in the anion-exchange resin phase were calculated; based on the IR spectroscopy data, the mechanism of SDS absorption was proposed.
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S. I. Karpov, M. V. Matveeva, and V. F. Selemenev, Zh. Fiz. Khim. 75, 323 (2001) [Russ. J. Phys. Chem. A 75, 266 (2001)].
G. V. Samsonov, Ion Exchange. Sorbtion of Organic Substances (Nauka, Leningrad, 1969) [in Russian].
G. S. Libinson, E. M. Savitskaya, and B. P. Bruns, Ion Exchange Technology, Collected vol. (Nauka, Moscow, 1965), p. 126 [in Russian].
G. S. Libison, E. M. Savitskaya, and B. P. Bruns, Ion Exchange Technology, Collected vol. (Nauka, Moscow, 1965), p. 141 [in Russian].
G. S. Libinson and E. M. Savitskaya, Zh. Fiz. Khim. 37, 2706 (1963).
O. V. Kovaleva, in Proc. of the 3rd Intern. Sci. Conf. (Belg. Gos. Univ., Belgorod, 2008).
A. M. Koganovskii, T. M. Levchenko, and V. A. Kirichenko, Adsorption of Solved Substances (Nauk. Dumka, Kiev, 1977) [in Russian].
A. M. Koganovskii and N. A. Klimenko, Physicochemical Methods for Removal of Surface-Active Substances From Industrial Waste Waters (Nauk. Dumka, Kiev, 1974) [in Russian].
O. S. Sadomtseva, Extended Abstract of Candidate’s Dissertation in Chemistry (Makhachkala, 2006).
N. S. Kurolap and V. P. Meleshko, Teor. Prakt. Sorbtsion. Prots., No. 5, 55 (1971).
V. P. Meleshko and N. S. Kurolap, Teor. Prakt. Sorbtsion. Prots., No. 3, 10 (1969).
N. S. Kurolap and V. P. Meleshko, Teor. Prakt. Sorbtsion. Prots., No. 2, 18 (1968).
N. S. Kurolap, Candidate’s Dissertation in Chemistry (Voron. Gos. Univ., Voronezh, 1970).
V. F. Selemenev, G. V. Slavinskaya, V. Yu. Khokhlov, et al., Practical Guide on Ion Exchange, the Schoolbook (Voron. Gos. Univ., Voronezh, 2004) [in Russian].
Surface Phenomena and Surface Active Substances, The Handbook, Ed. by A. A. Abramzon and E. D. Shchukin (Khimiya, Leningrad, 1984) [in Russian].
Yu. V. Shostenko, E. S. Vysotskaya, T. N. Gubina, et al., Teor. Prakt. Sorbtsion. Prots., No. 17, 52 (1985).
Surface Active Substances, The Handbook, Ed. by A. A. Abramzon and G. M. Gaevoi (Khimiya, Leningrad, 1979) [in Russian].
Adsorption from Solutions on Solid Surfaces, Ed. by V. I. Lygin (Mir, Moscow, 1986) [in Russian].
A. I. Rusanov, Micell Formation in Solutions of Surface Active Substances (Khimiya, St. Petersburg, 1992) [in Russian].
Yu. A. Kokotov, P. P. Zolotarev, and G. E. El’kin, Theoretic Bases of Ion Exchange (Khimiya, Leningrad, 1986) [in Russian].
G. V. Samsonov and A. T. Melenevskii, Sorbtion and Chromatographical Methods of Physicochemical Biotechnology (Nauka, Leningrad, 1986) [in Russian].
R. Griesbach, Theory and Practice of Ion Exchange (Academie, Berlin, 1957; Inostr. Liter., Moscow, 1963).
Yu. P. Znamenskii, A. I. Kasperovich, and N. V. Bychkov, Zh. Fiz. Khim. 42, 2017 (1968).
L. A. Kazitsyna and N. B. Kupletskaya, Application of UV-, IR-, NMR-, and Mass-Spectroscopy in Organic Chemistry (Mosk. Gos. Univ., Moscow, 1979) [in Russian].
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Original Russian Text © E.V. Bondareva, S.I. Karpov, V.F. Selemenev, V.N. Verezhnikov, E.V. Krokhina, 2009, published in Zhurnal Fizicheskoi Khimii, 2009, Vol. 83, No. 12, pp. 2339–2346.
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Bondareva, E.V., Karpov, S.I., Selemenev, V.F. et al. Sorption of sodium dodecyl sulfate by highly basic anion-exchange resins. Russ. J. Phys. Chem. 83, 2136–2143 (2009). https://doi.org/10.1134/S0036024409120243
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DOI: https://doi.org/10.1134/S0036024409120243