Abstract
New sorbents, polymers with molecular imprints of 2,4-dichlorophenoxyacetic acid (2,4-D), were prepared on the basis of acrylamide. The sorbents were synthesized by thermal polymerization methods with and without the use of ultrasound, photopolymerization, and suspension polymerization. The specific surface area of the products was estimated and their sorption properties were studied. Polymers with molecular imprints prepared by thermal polymerization with the use of ultrasound and by suspension polymerization showed the best ability to repeatedly bind 2,4-D. The selectivity of polymers was estimated for the example of structurally related compounds. It was shown that the method of synthesis decisively influenced not only the ability of sorbents to repeatedly bind 2,4-D but also their selectivity.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
K. Flavin and M. Resmini, Anal. Bioanal. Chem. 393, 437 (2009).
C. Alexander, H. S. Andersson, L. I. Andersson, et al., J. Mol. Recognit. 19, 106 (2006).
E. Turiel and A. Martin-Esteban, Anal. Bioanal. Chem. 378, 1876 (2004).
P. A. G. Cormack and A. Z. Elorza, J. Chromatogr. B 804, 173 (2004).
S. G. Dmitrienko, V. V. Irkha, A. Yu. Kuznetsova, and Yu. A. Zolotov, Zh. Anal. Khim. 59, 902 (2004) [J. Anal. Chem. 59, 808 (2004)].
O. D. Gendrikson, A. V. Zherdev, and B. B. Dzantiev, Usp. Biol. Khim. 46, 149 (2006).
G. V. Lisichkin and Yu. A. Krutyakov, Usp. Khim. 75, 998 (2006).
A. G. Mayes and K. Mosbach, Anal. Chem. 68, 3769 (1996).
A. Beltran, R. V. Marce, P. A. G. Cormac, and F. Borrull, J. Chromatogr. A 1216, 2248 (2009).
X. Kan, Q. Zhao, Z. Zhang, et al., Talanta 75, 22 (2008).
N. Perez-Moral and A. G. Mayes, Anal. Chim. Acta 504, 15 (2004).
S. G. Hu, L. Li, and X. W. He, Anal. Chim. Acta 537, 215 (2005).
S. G. Dmitrienko, V. V. Irkha, Yu. V. Mikhailik, and E. V. Klokova, Vestn. Mosk. Univ., Ser. Khim. 47, 210 (2006).
S. G. Dmitrienko, V. V. Irkha, T. B. Duisebaeva, et al., Zh. Anal. Khim. 61, 18 (2006) [J. Anal. Chem. 61, 14 (2006)].
S. G. Dmitrienko, V. V. Irkha, V. V. Apyari, E. V. Klokova, and Yu. A. Zolotov, Mendeleev Commun. 18, 315 (2008).
S. A. Popov, S. G. Dmitrienko, Yu. A. Chumichkina, and Yu. A. Zolotov, Zh. Fiz. Khim. 83, 649 (2009) [Russ. J. Phys. Chem. A 83, 552 (2009)].
V. A. Kudrinskaya, S. G. Dmitrienko, and Yu. A. Zolotov, Vestn. Mosk. Univ., Ser. Khim. 50(4), 156 (2009).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © S.G. Dmitrienko, S.A. Popov, Yu.A. Chumichkina, Yu.A. Zolotov, 2011, published in Zhurnal Fizicheskoi Khimii, 2011, Vol. 85, No. 3, pp. 542–547.
Rights and permissions
About this article
Cite this article
Dmitrienko, S.G., Popov, S.A., Chumichkina, Y.A. et al. The sorption properties of polymers with molecular imprints of 2,4-dichlorophenoxyacetic acid synthesized by various methods. Russ. J. Phys. Chem. 85, 472–477 (2011). https://doi.org/10.1134/S0036024411020087
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024411020087