Abstract
XRD phase analysis and thermal analysis are used to confirm the formation of a continuous series of solid solutions in which one cation is substituted for another in the systems Co(II) hydrogen maleate–Ni(II) hydrogen maleate; Fe(II) hydrogen maleate–Co(II) hydrogen maleate; and Fe(II) hydrogen maleate–Ni(II) hydrogen maleate. The unit cell volume of these solid solutions is shown to depend linearly on their composition. The linear character of changes in the initial temperatures of dehydration and thermal decomposition is established. Using the example of the first of these systems, it is shown that when heated, bimetallic nanoparticles embedded in the polymeric matrix of composites obtained via the thermal decomposition of solid solutions of hydrogen maleates undergo a second-order phase transition, resulting in decomposition of the solid solutions of metals at the Curie temperature.
Similar content being viewed by others
References
A. D. Pomogailo, A. S. Rozenberg, and I. E. Uflyand, Metal Nanoparticles in Polymers (Khimiya, Moscow, 2000) [in Russian].
A. D. Pomogailo, G. I. Dzhardimalieva, A. S. Rozenberg, and D. M. Muraviev, J. Nanopart. Res. 5, 497 (2003).
A. D. Pomogailo and V. N. Kestelman, Metallopolymer Nanocomposites (Springer, Berlin, Heidelberg, New York, 2005).
A. S. Fionov, Extended Abstract of Cand. Sci. (Chem.) Dissertation (Inst. Metallurgy and Material Science of RAS, Moscow, 2011).
L. B. Belykh and F. K. Shmidt, Introduction to Nanochemistry. Size Effects in Physicochemistry and Catalysis, Tutorial (Irkutsk. Gos. Univ., Irkutsk, 2013) [in Russian].
V. A. Logvinenko, L. I. Yudanova, N. F. Yudanov, and G. N. Chekhova, J. Therm. Anal. Calorim. 74, 395 (2003).
L. I. Yudanova, V. A. Logvinenko, L. A. Sheludyakova, N. F. Yudanov, G. N. Chekhova, N. I. Alferova, V. I. Alekseev, P. P. Semyannikov, and V. I. Lisoivan, Russ. J. Inorg. Chem. 53, 1459 (2008).
L. I. Yudanova, V. A. Logvinenko, L. A. Sheludyakova, N. F. Yudanov, P. P. Semyannikov, S. I. Kozhemyachenko, I. V. Korol’kov, N. A. Rudina, and A. V. Ishchenko, Russ. J. Inorg. Chem. 59, 1180 (2014).
L. I. Yudanova, V. A. Logvinenko, N. F. Yudanov, N. A. Rudina, A. V. Ishchenko, P. P. Semyannikov, L. A. Sheludyakova, N. I. Alferova, A. I. Romanenko, and O. B. Anikeeva, Inorg. Mater. 49, 1055 (2013).
L. I. Yudanova, V. A. Logvinenko, and N. F. Yudanov, RF Patent No. 2466098, Byull. Izobret. No. 31 (2012), p. 10.
G. B. Bokii, Crystal Chemistry (Nauka, Moscow, 1971), p. 291 [in Russian].
A. G. Kudashov, A. V. Okotrub, L. G. Bulusheva, et al., J. Phys. Chem. B 108, 9048 (2004).
A. G. Kudashov, O. G. Abrosimov, R. Gorbachev, et al., Fullerenes, Nanotubes Carbon Nanostruct. 12, 93 (2004).
V. M. Goldschmidt, Kristallchemie (Gustav Fisher, Jena, 1934).
State Diagrams of Binary Metallic Systems, Reference Book, Ed. by N. P. Lyakishev (Mashinostroenie, Moscow, 2001), Vol. 2 [in Russian].
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © L.I. Yudanova, V.A. Logvinenko, L.A. Sheludyakova, A.V. Ishchenko, N.A. Rudina, 2017, published in Zhurnal Fizicheskoi Khimii, 2017, Vol. 91, No. 1, pp. 136–140.
Rights and permissions
About this article
Cite this article
Yudanova, L.I., Logvinenko, V.A., Sheludyakova, L.A. et al. Thermal decomposition of solid solutions in systems of Fe(II), Co(II), and Ni(II) hydrogen maleates with the formation of bimetallic nanoparticles. Russ. J. Phys. Chem. 91, 136–140 (2017). https://doi.org/10.1134/S0036024417010320
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0036024417010320