Abstract
Solid-solution fields in the generally accepted type-IV phase diagrams are shown to exhibit a tendency toward separation, which causes the formation of separation microstructures. Numerous examples of separation in solid solutions are given; this separation occurs at temperatures both above and below the fields of chemical compounds. Separation and ordering fields are separated by metastable-solid-solution regions in phase diagrams. At the temperatures corresponding to these regions, an ordering-separation phase transition takes place. New versions of the Fe-Cr, Fe-Co, and Fe-V phase diagrams are presented.
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Original Russian Text © Yu.I. Ustinovshikov, 2007, published in Metally, 2007, No. 3, pp. 94–105.
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Ustinovshikov, Y.I. Ordering and separation in phase diagrams. Russ. Metall. 2007, 249–258 (2007). https://doi.org/10.1134/S0036029507030147
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DOI: https://doi.org/10.1134/S0036029507030147