Abstract
Mechanisms of mass transfer intensification in the process of membrane cleaning using supercritical fluids were investigated. Transport properties, hydrodynamics of the solvent flow, mutual solubility of the solvent and the oil contaminant, and capillary effects occurring inside the porous membrane as factors affecting the overall process performance were studied. The analysis was performed using empirical correlations for the transport property coefficients and a model of the process implemented to CFD code developed using the OpenFOAM environment. Supercritical carbon dioxide exhibits favourable transport properties, which are highly tunable with process parameters and contribute to low mass transfer resistance. The investigated process is controlled by diffusive mass transfer inside the membrane pores, so increasing solvent flow rate has limited impact on the overall process rate. Mutual solubility of the oil and solvent phase leads to the effect of swelling of the oil phase, which promotes faster completion of cleaning. Capillary effects inside the pores may be another factor of process acceleration which requires further investigation.
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References
Anastas, P. and Eghbali, N., Green chemistry: principles and practice, Chem. Soc. Rev., 2010, vol. 39, p. 301.
Li, Z., Tang, H., Liu, X., Xia, Y., and Jiang, J., Preparation and characterization of microporous poly(vinyl butyral) membranes by supercritical CO2-induced phase separation, J. Membr. Sci., 2008, vol. 312, p. 115.
Xinli, Z., Xiaoling, H., Ping, G., and Guozheng, L., Preparation and pore structure of porous membrane by supercritical fluid, J. Supercrit. Fluids, 2009, vol. 49, p. 111.
Zhang, C.F., Zhu, B.K., Ji, G.L., and Xu, Y.Y., Supercritical carbon dioxide extraction in membrane formation by thermally induced phase separation, J. Appl. Polym. Sci., 2007, vol. 103, p. 1632.
Ferro, L., Scialdone, O., and Galia, A., Preparation of pH sensitive poly(vinylidene fluoride) porous membranes by grafting of acrylic acid assisted by supercritical carbon dioxide, J. Supercrit. Fluids, 2012, vol. 66, p. 241.
Krzysztoforski, J., Krasinski, A., Henczka, M., and Piatkiewicz, W., Enhancement of supercritical fluid extraction in membrane cleaning process by addition of organic solvents, Chem. Process Eng., 2013, vol. 34, no. 3, p. 403.
Michalek, K., Krzysztoforski, J., Henczka, M., da Ponte, M.N., and Bogel-Lukasik, E., Cleaning of microfiltration membranes from industrial contaminants using “greener” alternatives in a continuous mode, J. Supercrit. Fluids, 2015, vol. 102, p. 115.
Tarabasz, K., Krzysztoforski, J., Szwast, M., and Henczka, M., Investigation of the effect of treatment with supercritical carbon dioxide on structure and properties of polypropylene microfiltration membranes, Mater. Lett., 2016, vol. 163, p. 54.
Krzysztoforski, J. and Henczka. M., Modeling of microporous membrane cleaning using supercritical fluids, Czasopismo Techniczne PK, 2014, no. 2, p. 63.
Jokic, S., Svilovic, S., Zekovic, Z., Vidovic, S., and Velic, D., Solubility and kinetics of soybean oil and fatty acids in supercritical CO2, Eur. J. Lipid Sci. Technol., 2011, vol. 113, p. 644.
Heidaryan, E., Hatami, T., Rahimi, M., and Moghadasi, J., Viscosity of pure carbon dioxide at supercritical region: measurement and correlation approach, J. Supercrit. Fluids, 2011, vol. 56, p. 144.
Green, D.W. and Perry, R.H., Perry’s Chemical Engineers’ Handbook, New York: McGraw-Hill, 1997.
https://www.openfoam.org
Jasak, H., OpenFOAM: open source CFD in research and industry, Int. J. Naval Architect. Ocean Eng., 2009, vol. 1, p. 89.
Kwiatkowski, K., Zuk, P. J., Dudynski, M., and Bajer, K., Pyrolysis and gasification of single biomass particle—new OpenFoam solver, J. Phys.: Conf. Ser., 2014, vol. 530, p. 012015.
Özbakir, Y. and Erkey, C., Experimental and theoretical investigation of supercritical drying of silica alcogels, J. Supercrit. Fluids, 2015, vol. 98, p. 153.
Horgue, P., Soulaine, C., Franc, J., Guibert, R., and Debenest, G., An open-source toolbox for multiphase flow in porous media, Comput. Phys. Commun., 2015, vol. 187, p. 217.
Yiotis, A.G., Stubos, A.K., Boudouvis, A.G., and Yortsos, Y.C., A 2-D pore-network model of the drying of single-component liquids in porous media, Adv. Water Res., 2011, vol. 24, no. 3, p. 439.
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Krzysztoforski, J., Jenny, P. & Henczka, M. Mass transfer intensification in the process of membrane cleaning using supercritical fluids. Theor Found Chem Eng 50, 907–913 (2016). https://doi.org/10.1134/S0040579516060099
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DOI: https://doi.org/10.1134/S0040579516060099