Abstract
The isothermal-isomorphic dependences of the specific surface energy (σ), its isochoric temperature derivative (σ′), and surface pressure (P sf) on the size of nanodiamonds 12C and 13C at 100 and 4300 K are calculated. It is shown that the ratio σ(12C)/σ(13C) decreases with decreasing size along both isotherms, and σ′(12C)/σ′(13C) increases with decreasing size, and this effect is higher at lower temperatures. The ratio P sf(12C)/P sf(13C) increases with decreasing size. The effect is stronger at higher temperatures.
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Original Russian Text © M.N. Magomedov, 2014, published in Poverkhnost’. Rentgenovskie, Sinkhrotronnye i Neitronnye Issledovaniya, 2014, No. 2, pp. 108–112.
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Magomedov, M.N. Change in the size dependences of the surface properties of nanodiamond upon variation in the isotope composition. J. Surf. Investig. 8, 196–200 (2014). https://doi.org/10.1134/S1027451014010315
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DOI: https://doi.org/10.1134/S1027451014010315