Skip to main content
Log in

Cross-linked poly(methyl methacrylate) particles with surface amino groups

  • Published:
Colloid Journal Aims and scope Submit manuscript

Abstract

Positively charged monodisperse particles have been synthesized via emulsifier-free emulsion copolymerization of methyl methacrylate with vinylformamide and ethylene glycol dimethacrylate. The effect of the cross-linking agent on the conversion of the monomers, as well as on the shape, size distribution, and surface characteristics of the obtained particles, has been determined. Addition of the cross-linking agent (5 wt %) to the reaction system has been shown to result in the formation of particles, which, after hydrolysis, have positive ζ potentials at pH 2–10.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Men’shikova, A.Yu., Nanotechnol. Russ., 2010, vol. 5, nos. 1–2, p. 35.

    Article  Google Scholar 

  2. Zubov, V.P., Ivanov, A.E., Zhigis, L.S., Rapoport, E.M., Markvicheva, E.A., Lukin, Yu.V., and Zaitsev, S.Yu., Bioorg. Khim., 1999, vol. 25, p. 868.

    CAS  Google Scholar 

  3. Men’shikova, A.Yu., Shevchenko, N.N., Bugakov, I.V., Yakimanskii, A.V., and Sel’kin, A.V., Phys. Solid State, 2011, vol. 53, p. 1091.

    Google Scholar 

  4. Men’shikova, A.Yu., Bilibin, A.Yu., Shevchenko, N.N., Shabsel’s, B.M., Evseeva, T.G., Bazhenova, A.G., and Sel’kin, A.V., Polym. Sci., Ser. A, 2006, vol. 48, p. 910.

    Article  Google Scholar 

  5. Yakimanskii, A.V., Men’shikova, A.Yu., Evseeva, T.G., Shevchenko, N.N., and Bilibin, A.Yu., Ross. Nanotekhnol., 2006, vol. 1, nos. 1–2, p. 183.

    Google Scholar 

  6. Prokopov, N.I., Gritskova, I.A., Cherkasov, V.R., and Chalykh, A.E., Usp. Khim., 1996, vol. 65, p. 178.

    Article  CAS  Google Scholar 

  7. Suzawa, T., Shirahama, H., and Fujimoto, T., J. Colloid Interface Sci., 1982, vol. 86, p. 144.

    Article  CAS  Google Scholar 

  8. Suen, C.-H. and Morawetz, H., Makromol. Chem., 1985, vol. 186, p. 255.

    Article  CAS  Google Scholar 

  9. Dawson, D.J., Gless, R.D., and Wingard, R.E., J. Am. Chem. Soc., 1976, vol. 98, p. 5996.

    Article  CAS  Google Scholar 

  10. Gu, L., Zhu, S., and Hrymak, A.N., J. Appl. Polym. Sci., 2002, vol. 86, p. 3412.

    Article  CAS  Google Scholar 

  11. Gless, R.D., US Patent 4018286, 1977.

  12. Men’shikova, A.Yu., Evseeva, T.G., Chekina, N.A., and Ivanchev, S.S., Russ. J. Appl. Chem., 2001, vol. 74, p. 489.

    Article  Google Scholar 

  13. Shevchenko, N.N., Pankova, G.A., Evseeva, T.G., Shabsel’s, B.M., Baigil’din, V.A., and Men’shikova, A.Yu., Polym. Sci., Ser. B, 2014, vol. 56, p. 132.

    Article  CAS  Google Scholar 

  14. Gordon, A.J. and Ford, R.A., The Chemist’s Companion. A Handbook of Practical Data, Techniques and Reeferences, New York: Wiley, 1972.

    Google Scholar 

  15. Lishanskii, I.S., Men’shikova, A.Yu., Evseeva, T.G., Komarovskaya, E.E., Shubin, V.E., and Sakharova, N.A., Vysokomol. Soedin., Ser. B, 1991, vol. 33, p. 413.

    CAS  Google Scholar 

  16. Voskresenskii, P.I., Tekhnika laboratornykh rabot (Technique of Laboratory Works), Moscow: Goskhimizdat, 1962.

    Google Scholar 

  17. Soxhlet, F., Dingl Polyt. J., 1879, vol. 232, p. 461.

    Google Scholar 

  18. Covolan, V.L., Galembeck, F., De Paula Leite, C.A., Ruggeri, G., and Chiellini, E., J. Colloid Interface Sci., 2004, vol. 273, p. 121.

    Article  CAS  Google Scholar 

  19. Men’shikova, A.Yu., Inkin, K.S., Evseeva, T.G., Skurkis, Yu.O., Shabsel’s, B.M., Shevchenko, N.N., and Ivanchev, S.S., Colloid J., 2011, vol. 73, p. 76.

    Article  Google Scholar 

  20. Odian, G., Principles of Polymerization, New York: McGraw-Hill, 1970.

    Google Scholar 

  21. Whitney, R.S. and Burchard, W., Makromol. Chem., 1980, vol. 181, p. 869.

    Article  CAS  Google Scholar 

  22. Ho, A.K., Iin, I., Gurr, P.A., Mills, M.F., and Qiao, G.G., Polymer, 2005, vol. 46, p. 6727.

    Article  CAS  Google Scholar 

  23. Copolymerization, Ham, G.E., Ed., New York: Wiley, 1964.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to N. N. Shevchenko.

Additional information

Original Russian Text © V.A. Baigil’din, G.A. Pankova, T.G. Evseeva, A.Yu. Men’shikova, N.N. Shevchenko, 2015, published in Kolloidnyi Zhurnal, 2015, Vol. 77, No. 1, pp. 9–13.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Baigil’din, V.A., Pankova, G.A., Evseeva, T.G. et al. Cross-linked poly(methyl methacrylate) particles with surface amino groups. Colloid J 77, 6–10 (2015). https://doi.org/10.1134/S1061933X15010020

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061933X15010020

Keywords

Navigation