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Mechanochemical synthesis of colloidal sulfur particles in the Na2S2O3–H2(C4H4O4)–Na2SO3 system

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Abstract

Elemental sulfur nanoparticles (nanosulfur, S 0 n ) have been obtained in a matrix consisting of sodium sulfite (diluent and a final reaction product) and succinic acid (catalyst) by mechanochemical syntheses via the reaction Na2S2O3 · 5H2O + H2(C4H4O4) + zNa2SO3 = (z + 1)Na2SO3 + H2(C4H4O4) + 5H2O+ S 0 n , at z = 19.6. It has been shown that free nanodispersed sulfur can be obtained by dissolving the matrix in water. The prepared samples have been characterized using a set of physical and physicochemical methods.

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Authors and Affiliations

  1. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, pr. Akademika Koptyuga 3, Novosibirsk, 630090, Russia

    F. Kh. Urakaev

  2. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    A. I. Bulavchenko

  3. Al-Farabi Kazakh National University, pr. al-Farabi 71, Almaty, 050040, Kazakhstan

    B. M. Uralbekov, B. B. Tatykayev, A. K. Bolatov, D. N. Dzharlykasimova & M. M. Burkitbayev

  4. Bashkortostan State University, ul. Zaki Validi 32, Ufa, Bashkortostan, 450074, Russia

    I. A. Massalimov

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  1. F. Kh. Urakaev
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  2. A. I. Bulavchenko
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  3. B. M. Uralbekov
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  4. I. A. Massalimov
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  5. B. B. Tatykayev
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  6. A. K. Bolatov
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Correspondence to F. Kh. Urakaev.

Additional information

Original Russian Text © F.Kh. Urakaev, A.I. Bulavchenko, B.M. Uralbekov, I.A. Massalimov, B.B. Tatykayev, A.K. Bolatov, D.N. Dzharlykasimova, M.M. Burkitbayev, 2016, published in Kolloidnyi Zhurnal, 2016, Vol. 78, No. 2, pp. 193–202.

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Urakaev, F.K., Bulavchenko, A.I., Uralbekov, B.M. et al. Mechanochemical synthesis of colloidal sulfur particles in the Na2S2O3–H2(C4H4O4)–Na2SO3 system. Colloid J 78, 210–219 (2016). https://doi.org/10.1134/S1061933X16020150

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  • DOI: https://doi.org/10.1134/S1061933X16020150

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