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Determination of 1,2,3-benzotriazole in aqueous solutions and air by reaction-gas-liquid chromatography

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Abstract

A procedure is developed for the gas-chromatographic determination of 1,2,3-benzotriazole including preliminary derivatization with acetic anhydride in an aqueous solution followed by the extraction the derivative with toluene. The procedure is applied to the analysis of water samples, process solutions for treating metals, air of the working zone, and industrial emissions. Determination limits in water media are 0.01 mg/L and in the air of the working zone, 0.1 mg/m3.

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References

  1. Patsalides, E., J. Chromatogr., 1985, vol. 331, p. 149.

    Article  CAS  Google Scholar 

  2. Weiss, S. and Reemstma, T., Anal. Chem., 2005, vol. 77, p. 7415.

    Article  CAS  Google Scholar 

  3. Gigienicheskie normativy khimicheskikh veshchestv v okruzhayushchei srede (Hygienic Standards for Chemical Substances in the Environment), Rakhmanin, Yu.A. and Semenova, V.V., Eds., St. Petersburg: Professional, 2007.

    Google Scholar 

  4. Giger, W., Schaffner, C., and Kohler, H.-P.E., Environ. Sci. Technol., 2006, vol. 40, p. 7186.

    Article  CAS  Google Scholar 

  5. Weiss, S., Jakobs, J., and Reemtsma, T., Environ. Sci. Technol., 2006, vol. 40, p. 7193.

    Article  CAS  Google Scholar 

  6. Nemodruk, A.A. and Gorbunova, G.N., Zavod. Lab., 1982, vol. 48, no. 9, p. 23.

    CAS  Google Scholar 

  7. Dolmanova, I.F., Popova, I.M., Shekhovtsova, T.N., and Ugarova, N.N., Zhurn. anal. khim., 1981, vol. 36, no. 5, p. 976.

    CAS  Google Scholar 

  8. Cancilla, D.A., Hotkamp, A., Matassa, L., and Fang, X., Environ. Toxicol. Chem., 1997, no. 16, p. 430.

  9. Cancilla, D.A., Martinez, J., and van Aggelen, G.C., Environ. Sci. Technol., 1998, vol. 32, p. 3834.

    Article  CAS  Google Scholar 

  10. MUK (Instructional Guidelines) 4.1.1208-03: Chromatographic Determination of 1,2,3-Benzotriazol in Water.

  11. MUK (Instructional Guidelines) 3947-85: Methodical Guidelines on Chromatographic Measurements of the Concentration of Benzotriazol in the Work Zone Air.

  12. Dilli, S. and Patsalides, E., J. Chromatogr., 1983, vol. 280, p. 59.

    Article  CAS  Google Scholar 

  13. Zaikin, V.G. and Mikaya, A.I., Khimicheskie metody v mass-spektrometrii organicheskikh soedinenii (Chemical Methods in Mass Spectrometry of Organic Compounds), Moscow: Nauka, 1987.

    Google Scholar 

  14. Fagel, J.E. and Ewing, G.W., J. Am. Chem. Soc., 1951, vol. 73, p. 4360.

    Article  CAS  Google Scholar 

  15. O’sullivan, D.G., J. Chem. Soc., 1960, p. 3653.

  16. Staab, H.A., Chem. Ber., 1957, vol. 90, p. 1320.

    Article  CAS  Google Scholar 

  17. Rebound-Ravaux, M., J. Am. Chem. Soc., 1980, vol. 102, p. 1039.

    Article  Google Scholar 

  18. Korenman, Ya.I., Koeffitsienty raspredeleniya organicheskikh soedinenii (Partition Coefficients of Organic Compounds), Voronezh: Voronezh. Gos. Univ., 1992.

    Google Scholar 

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Authors and Affiliations

  1. Postovskii Institute of Organic Synthesis, Ural Division, Russian Academy of Sciences, ul. S. Kovalevskoi, 22/20, Yekaterinburg, 620041, Russia

    M. G. Pervova, V. E. Kirichenko & V. I. Saloutin

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  1. M. G. Pervova
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  2. V. E. Kirichenko
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  3. V. I. Saloutin
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Original Russian Text © M.G. Pervova, V.E. Kirichenko, V.I. Saloutin, 2010, published in Zhurnal Analiticheskoi Khimii, 2010, Vol. 65, No. 3, pp. 281–284.

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Pervova, M.G., Kirichenko, V.E. & Saloutin, V.I. Determination of 1,2,3-benzotriazole in aqueous solutions and air by reaction-gas-liquid chromatography. J Anal Chem 65, 276–279 (2010). https://doi.org/10.1134/S1061934810030111

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  • DOI: https://doi.org/10.1134/S1061934810030111

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