Abstract
Floatability of pyrolusite from an Iranian low grade manganese ore (13.6% MnO) containing calcite as the main gangue mineral was investigated with Armac C as a cationic collector. In the single mineral flotation experiments, the maximum recovery of pyrolusite is obtained at 82.2%, using 2000 g/t Armac C at a pH of 9, while at these conditions the flotation recovery of calcite is almost 78%. Quebracho and sodium hexa methaphosphate (SH) depress both minerals strongly at a wide range of dosages while low dosages of sodium silicate and zinc oxide depress the calcite mineral more than pyrolusite. Ca2+ ions affect the flotation recovery of pyrolusite negatively. The effective depression of calcite occurs using 1000–2000 g/t sodium silicate. However, in the ore flotation experiments, the favorable selective flotation of pyrolusite does not occur but the optimal concentrate containing 21.5% MnO with 51% recovery is obtained using 2000 g/t collector and 1000 g/t sodium silicate. A concentrate containing 37% MnO is achieved by carrying out flotation experiments on the jigging pre-concentrate under optimal conditions including pH = 9, 1000 g/t Armac C, 1000 g/t sodium silicate and 120 g/t pin oil.
Similar content being viewed by others
References
Delian Fan and Peiji Yang, Introduction to and Classification of Manganese Deposits of China, Ore Geology Reviews, 1999, vol, 15, pp. 1–13.
Corathers L.A. and Machamer J.F., Manganese, Industrial Minerals and Rocks, Jessica Elzea Kogel, Nikhil C. Trivedi, James M. Barker and Stanley T. Krukowsk (Eds.), 2006, pp. 631–637.
Fuerstenau, M. C., Han, K.N., and Miller, J.D., Flotation Behavior of Chromium and Manganese Minerals, Proc. Arbiter Symposium, Advances in Mineral Processing, 1986, pp. 289–307.
Wensheng Zhang and Chu Yong Cheng, Manganese Metallurgy Review. Part I: Leaching of Ores/Secondary Materials and Recovery of Electrolytic/Chemical Manganese Dioxide, Hydrometallurgy, 2007, vol. 89, pp. 137–159.
Bochkarev, G.R., Pushkareva, G.I., and Kovalenko, K.A., Sorption Properties of Manganese Ores, J. Min. Sci., 2011, vol. 47, no. 6, pp. 837–841.
Abeidu A.M., The Feasibility of Activation of Manganese Minerals Flotation, Trans. JIM, 1972, vol. 14, pp. 45–49.
Mishra, P.P., Mohapatra, B.K., and Mahanta, K., Upgradation of Low-Grade Siliceous Manganese Ore from Bonai-Keonjhar Belt, Orissa, India, Journal of Minerals & Materials Characterization & Engineering, 2009, 8(1), pp. 47–56.
Fuerstenau, D.W. and Shibata, J., On Using Electrokinetics to Interpret the Flotation and Interfacial Behavior of Manganese Dioxide, International Journal of Mineral processing, 1999, vol. 57, pp. 205–217.
Fuerstenau, D.W. and Pradip, T., Zeta Potentials in the Flotation of Oxide and Silicate Minerals, Advances in Colloid and Interface Science, 2005, vol. 114–115, pp. 9–26.
Fuerstenau, M.C. and Palmer, B.R., Anionic Flotation of Oxide and Silicates, Flotation. A.M. Gaudin Memorial Volume, Fuerstenau, M.C. (Ed.), AIME, New York, 1976, Chap. 7, pp. 148–196.
Natarajan, R. and Fuerstenau, D.W., Adsorption and Flotation Behavior of Manganese Dioxide in the Presence of Octyl Hydroxamate, International Journal of Mineral Processing, 1983, vol. 11, pp. 139–153.
Mehdilo. A., Hojjati-rad. M.R., and Irannajad, M., Process Mineralogical Studies of Charagah Manganese Ore, Proc. International Mining Congress and Exhibition, 2010, Tehran, Iran.
Irannajad, M., Beneficiation of Charagah Manganese Ore, Report of Research Project, 2010, Amirkabir University of Technology, Tehran, Iran.
Srdjan, M. Bulatovic, Handbook of Flotation Reagents Chemistry, Theory and Practice: Flotation of Sulfide Ores, Elsevier Science & Technology Books, 2007.
Donald L. Pavia, Gary M. Lampman, George S. Kriz, and James R. Vyvyan, Introduction to Spectroscopy, Fourth Edition, Brooks/Cole, Cengage Learning, 2009.
Russell M. Potter and George R. Rossman, The Tetravalent Manganese Oxides: Identification, Hydration, and Structural Relationships by Infrared Spectroscopy, Amer. Mineralogist, 1979, vol. 64, pp. 1199–1218.
http://minerals.gps.caltech.edu/FILES/Infrared-MIR/index.htm.
Hans H. Adler and Paul F. Kerr, Infrared Study of Aragonite and Calcite, Amer. Mineralogist, 1962, vol. 47, pp. 700–717.
Author information
Authors and Affiliations
Corresponding author
Additional information
The article is published in the original.
Rights and permissions
About this article
Cite this article
Mehdilo, A., Irannajad, M. Evaluation of pyrolusite flotation behavior using a cationic collector. J Min Sci 50, 982–993 (2014). https://doi.org/10.1134/S1062739114050184
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1062739114050184