Abstract
We have investigated the conductivity of some representatives of different technological forms of fluoride-conducting solid electrolytes R 1–y M y F3–y (M = Ca, Sr, Ba; R are rare earth elements) with an LaF3 structure: single crystals, cold- and hot-pressing ceramics based on a charge prepared in different ways (mechanochemical synthesis, solid-phase synthesis, and fragmentation of single crystals), polycrystalline alloys, etc. It is shown (by impedance spectroscopy), that different technological forms of identical chemical composition (R, M, y) exhibit different electrical characteristics. The maximum conductivity is observed for the single-crystal form of R 1–y M y F3–y tysonite phases, which provides (in contrast to other technological forms) the formation of true volume ion-conducting characteristics.
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N. I. Sorokin and B. P. Sobolev, Crystallogr. Rep. 52 (5), 842 (2007).
N. I. Sorokin, Elektrokhimiya 40 (5), 644 (2004).
N. I. Sorokin, Usp. Khim. 70 (9), 901 (2001).
M. Frant and J. Ross, Science 154 (3736), 1553 (1966).
N. I. Sorokin, E. F. Sudakova, E. A. Krivandina, and B. P. Sobolev, Elektrokhimiya 35 (2), 246 (1999).
N. I. Sorokin, E. A. Krivandina, Z. I. Zhmurova, et al., Proc. All-Russia Conf. “Sensor 2000: Sensors and Microsystems,” St. Petersburg, 21–23 June, 2000, p. 322.
E. F. Sudakova, E. A. Oksengoit-Gruzman, V. P. Topchaev, et al., Patent RF No. RU2094791 (27 October 1997).
E. F. Sudakova, E. A. Oksengoit-Gruzman, V. P. Topchaev, et al., Patent RF no. RU2094793 (27 October 1997).
A. A. Potanin, Zh. Ross. Khim. O-va im. D. I. Mendeleeva 45 (5–6), 58 (2001).
M. Anji Reddy and M. Fichtner, J. Mater. Chem. 21, 17059 (2011).
B. P. Sobolev, The Rare Earth Trifluorides, Part 2: Introduction to Materials Science of Multicomponent Metal Fluoride Crystals (Institute of Crystallography, Moscow, 2001; Institut d’Estudis Catalans, Barcelona, 2001).
P. P. Fedorov, A. A. Luginina, S. N. Kuznetsov, and V. V. Osiko, J. Fluorine Chem. 132, 1012 (2011).
J. Schoonman, G. Oversluizen, and K. E. D. Wapenaar, Solid State Ionics 1, 211 (1980).
N. I. Sorokin, M. V. Fominykh, A. N. Smirnov, and B. P. Sobolev, Inorg. Mater. 35 (7), 759 (1999).
B. P. Sobolev, I. A. Sviridov, V. I. Fadeeva, et al., Crystallogr. Rep. 53 (5), 868 (2008).
N. I. Sorokin, N. A. Ivanovskaya, and B. P. Sobolev, Crystallogr. Rep. 59 (2), 248 (2014).
C. Rongeat, M. Anji Reddy, R. Witter, and M. Fichtner, ACS Appl. Mater. Interfaced 6, 2103 (2014).
A. Duvel, J. Bednarcik, V. Sepelak, and P. Heitjans, J. Phys. Chem. C 118, 7117 (2014).
B. P. Sobolev and N. I. Sorokin, Crystallogr. Rep. 59 (6), 807 (2014).
B. P. Sobolev, N. I. Sorokin, E. A. Krivandina, and Z. I. Zhmurova, Crystallogr. Rep. 59 (4), 550 (2014).
N. I. Sorokin, B. P. Sobolev, E. A. Krivandina, and Z. I. Zhmurova, Crystallogr. Rep. 60 (1), 123 (2015).
A. K. Ivanov-Shits, N. I. Sorokin, P. P. Fedorov, and B. P. Sobolev, Fiz. Tverd. Tela 25 (6), 1748 (1983).
N. I. Sorokin and B. P. Sobolev, Elektrokhimiya 43 (4), 420 (2007).
N. I. Sorokin and B. P. Sobolev, Phys. Solid State 50 (3), 416 (2008).
N. I. Sorokin and B. P. Sobolev, Elektrokhimiya 44 (9), 1111 (2008).
E. A. Krivandina, N. I. Sorokin, Z. I. Zhmurova, and B. P. Sobolev, Proc. IX Natl. Conf. on Crystal Growth, Moscow, 16–20 October, 2000, p. 293.
N. I. Sorokin, Z. I. Zhmurova, E. A. Krivandina, and B. P. Sobolev, Crystallogr. Rep. 57 (3), 461 (2012).
B. P. Sobolev, Crystallogr. Rep. 47 (Suppl. 1), 63 (2002).
F. K. Volynets, Opt.-Mekh. Prom-st, No. 9, 48 (1973).
N. I. Sorokin, A. Smirnov, P. P. Fedorov, and B. P. Sobolev, Elektrokhimiya 45 (5), 641 (2009).
T. Takahashi, H. Iwahara, and T. Ishikava, J. Electrochem. Soc. 124 (2), 280 (1977).
I. V. Murin, O. V. Glumov, and Yu. V. Amelin, Zh. Prikl. Khim. 53 (4), 1474 (1980).
I. V. Murin, O. V. Glumov, and B. P. Sobolev, Vestn. Leningrad Gos. Univ.: Ser. Fiz. Khim., No. 10, 84 (1980).
A. Roos, F. C. M. van de Pol, and J. Schoonman, Solid State Ionics 13, 191 (1984).
N. I. Sorokin, M. V. Fominykh, V. I. Fistul’, et al., Fiz. Tverd. Tela 41 (4), 638 (1999).
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Original Russian Text © N.I. Sorokin, B.P. Sobolev, 2016, published in Kristallografiya, 2016, Vol. 61, No. 3, pp. 468–474.
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Sorokin, N.I., Sobolev, B.P. Fluorine-ion conductivity of different technological forms of solid electrolytes R 1–y M y F3–y (LaF3 Type ) (M = Ca, Sr, Ba; R Are Rare Earth Elements). Crystallogr. Rep. 61, 499–505 (2016). https://doi.org/10.1134/S1063774516020279
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DOI: https://doi.org/10.1134/S1063774516020279