Abstract
The channels of single-walled carbon nanotubes (SWNTs) are filled with metallic silver. The synthesized nanocomposites are studied by Raman spectroscopy and optical absorption spectroscopy, and these data indicate a substantial modification of the electronic structure of the nanotubes upon their filling. Moreover, X-ray photoelectron spectroscopy shows that the incorporation of the metal leads to a change in the work function of SWNTs due to the Fermi level upshift and to the transfer of an electron density from inserted nanoparticles to the nanotube walls. Thus, the filling of the channels with silver results in donor doping of the nanotubes.
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References
S. Iijima, Nature (London) 354, 56 (1991).
T. W. Odom, J. L. Huang, P. Kim, and C. M. Lieber, Nature (Londo) 391, 62 (1998).
R. R. He, H. Z. Jin, J. Zhu, Y. J. Yan, and X. H. Chen, Chem. Phys. Lett. 298, 170 (1998).
P. Chen, X. Wu, X. Sun, J. Lin, W. Ji, and K. L. Tan, Phys. Rev. Lett. 82, 2548 (1999).
M. M. J. Treacy, T. W. Ebbesen, and J. M. Gibson, Nature (London) 381, 678 (1996).
S. J. Tans, A. R. M. Verschueren, and C. Dekker, Nature (London) 393, 49 (1998).
Z. Chen, J. Appenzeller, Y.-M. Lin, J. Sippel-Oakley, A. G. Rinzler, J. Tang, S. J. Wind, P. M. Solomon, and P. Avouris, Science (Washington) 311, 1735 (2006).
M. S. Dresselhaus, G. Dresselhaus, and R. Saito, Carbon 33, 883 (1995).
R. Saito, M. Fujita, G. Dresselhaus, and M. S Dresselhaus, Appl. Phys. Lett. 60, 2204 (1992).
R. Krupke, F. Hennrich, H. Lönneysen, and M. M. Kappes, Science (Washington) 301, 344 (2000).
M. J. O’Connell, S. M. Bachilo, C. B. Huffman, V. C. Moore, M. S. Strano, E. H. Haroz, K. L. Rialon, P. J. Boul, W. H. Noon, C. Kittrell, J. Ma, R. H. Hauge, R. B. Weisman, and R. E. Smalley, Science (Washington) 297, 593 (2002).
M. Zheng, A. Jagota, M. S. Strano, A. P. Santos, P. Barone, S. G. Chou, B. A. Diner, M. S. Dresselhaus, R. S. Mclean, G. B. Onoa, G. G. Samsonidze, E. D. Semke, M. Usrey, and D. J. Walls, Science (Washington) 302, 1545 (2003).
P. G. Collins, M. S. Arnold, and P. Avouris, Science (Washington) 292, 706 (2001).
G. G. Samsonidze, S. G. Chou, A. P. Santos, V. W. Brar, G. Dresselhaus, M. S. Dresselhaus, A. Selbst, A. K. Swan, M. S. ünlü, B. B. Goldberg, D. Chattopadhyay, S. N. Kim, and F. Papadimitrakopoulos, Appl. Phys. Lett. 85, 1006 (2004).
P. Ayala, R. Arenal, A. Loiseau, A. Rubio, and T. Pichler, Rev. Mod. Phys. 82, 1843 (2010).
E. Dujardin, T. W. Ebbesen, H. Hiura, and K. Tanigaki, Science (Washington) 265, 1850 (1994).
Y. F. Li, T. Kaneko, T. Ogawa, M. Takahashi, and R. Hatakeyama, Chem. Commun. (Cambridge), No. 3, 254 (2007).
J. Sloan, J. Hammer, M. Zwiefka-Sibley, and M. L. H. Green, Chem. Commun. (Cambridge), No. 3, 347 (1998).
J. Sloan, A. I. Kirkland, J. L. Hutchison, M. L. H. Green, C. R. Phys. 4, 1063 (2003).
A. Kukovecz, T. Pichler, R. Pfeiffer, C. Kramberger, and H. Kuzmany, Phys. Chem. Chem. Phys. 5, 582 (2003).
T. Pichler, X. Liu, M. Knupfer, and J. Fink, New J. Phys. 5, 156 (2003)
A. Penicaud, P. Poulin, A. Derre, E. Anglaret, and P. Petit, J. Am. Chem. Soc. 127, 8 (2005).
R. S. Lee, H. J. Kim, J. E. Fischer, A. Thess, and R. E. Smalley, Nature (London) 388, 255 (1997).
A. M. Rao, P. C. Eklund, S. Bandow, A. Thess, and R. E. Smalley, Nature (London) 388, 257 (1997).
A. A. Eliseev, L. V. Yashina, M. M. Brzhezinskaya, M. V. Chernysheva, M. V. Kharlamova, N. I. Verbitsky, A. V. Lukashin, N. A. Kiselev, A. S. Kumskov, R. M. Zakalyuhin, J. L. Hutchison, B. Freitag, and A. S. Vinogradov, Carbon 48, 2708 (2010).
M. V. Kharlamova, L. V. Yashina, A. A. Volykhov, J. J. Niu, V. S. Neudachina, M. M. Brzhezinskaya, T. S. Zyubina, A. I. Belogorokhov, and A. A. Eliseev, Eur. Phys. J. B 85, 34 (2012).
M. V. Kharlamova, A. A. Eliseev, L. V. Yashina, D. I. Petukhov, Chan-Pu Liu, Chen-Yu Wang, D. A. Semenenko, and A. I. Belogorokhov, JETP Lett. 91(4), 196 (2010).
M. V. Kharlamova, M. M. Brzhezinskaya, A. S. Vinogradov, I. P. Suzdalev, Yu. V. Maksimov, V. K. Imshennik, S. V. Novichikhin, A. V. Krestinin, L. V. Yashina, A. V. Lukashin, Yu. D. Tret’yakov, and A. A. Eliseev, Nanotechnol. Russ. 4(9–10), 634 (2009).
L. J. Li, A. N. Khlobystov, J. G. Wiltshire, G. A. D. Briggs and R. J. Nicholas, Nat. Mater. 4, 481 (2005).
L. V. Yashina, A. A. Eliseev, M. V. Kharlamova, A. A. Volykhov, A. V. Egorov, S. V. Savilov, A. V. Lukashin, R. Püttner, and A. I. Belogorokhov, J. Phys. Chem. C 115, 3578 (2011).
J. Lu, S. Nagase, D. P. Yu, H. Ye, R. Han, Z. Gao, S. Zhang, and L. Peng, Phys. Rev. Lett. 93, 116804 (2004).
T. Takenobu, T. Takano, M. Shiraishi, Y. Murakami, M. Ata, H. Kataura, Y. Achiba, and Y. Iwasa, Nat. Mater. 2, 683 (2003).
H. Shiozawa, T. Pichler, C. Kramberger, A. Grüneis, M. Knupfer, B. Büchner, V. Zólyomi, J. Koltai, J. Kürti, D. Batchelor, and H. Kataura, Phys. Rev. B: Condens. Matter 77, 153402 (2008).
R. J. Baierle, S. B. Fagan, R. Mota, A. J. R. da Silva, and A. Fazzio, Phys. Rev. B: Condens. Matter 64, 085413 (2001).
S. B. Fagan, R. Mota, A. J. R. da Silva, and A. Fazzio, Nano Lett. 4, 975 (2004).
A. A. Eliseev, M. V. Kharlamova, M. V. Chernysheva, A. V. Lukashin, Yu. D. Tretyakov, A. S. Kumskov, and N. A. Kiselev, Rus. Chem. Rev. 78, 833 (2009).
W. Y. Choi, J. W. Kang, and H. J. Hwang, Phys. Rev. B: Condens. Matter 68, 193405 (2003).
S. B. Fagan, A. G. S. Filho, J. M. Filho, P. Corio, and M. S. Dresselhaus, Chem. Phys. Lett. 406, 54 (2005).
K. Hirahara, K. Suenaga, S. Bandow, H. Kato, T. Okazaki, H. Shinohara, and S. Iijima, Phys. Rev. Lett. 85, 5384 (2000).
E. L. Sceats, J. C. Green, and S. Reich, Phys. Rev. B: Condens. Matter 73, 125441 (2006).
S. B. Fagan, R. Mota, A. J. R. da Silva, and A. Fazzio, Phys. Rev. B: Condens. Matter 67, 205414 (2003).
A. A. Eliseev, L. V. Yashina, M. V. Kharlamova, and N. A. Kiselev, in Electronic Properties of Carbon Nanotubes, Ed. by J. M. Marulanda (InTech, Rijeka, Croatia, 2011), Chap. 8, p. 127.
M. S. Dresselhaus, G. Dresselhaus, A. Jorio, A. G. S. Filho, and R. Saito, Carbon 40, 2043 (2002).
A. Jorio, M. Pimenta, A. S. Filho, R. Saito, G. Dresselhaus, and M. S. Dresselhaus, New J. Phys. 5, 139 (2003).
S. H. Lim, Phys. Rev. B: Condens. Matter 73, 045402 (2006).
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Original Russian Text © M.V. Kharlamova, J.J. Niu, 2012, published in Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2012, Vol. 142, No. 3, pp. 547–555.
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Kharlamova, M.V., Niu, J.J. Donor doping of single-walled carbon nanotubes by filling of channels with silver. J. Exp. Theor. Phys. 115, 485–491 (2012). https://doi.org/10.1134/S1063776112080092
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DOI: https://doi.org/10.1134/S1063776112080092