Skip to main content
Log in

Kinetic constants of abnormal grain growth in nanocrystalline nickel

  • Thermal Properties
  • Published:
Physics of the Solid State Aims and scope Submit manuscript

Abstract

The grain growth in nanocrystalline nickel with a purity of 99.5 at % during non-isothermal annealing was experimentally investigated using differential scanning calorimetry and transmission electron microscopy. Nanocrystalline nickel was prepared by electrodeposition and had an average grain size of approximately 20 nm. It was shown that, at a temperature corresponding to the calorimetric signal peak, abnormal grain growth occurs with the formation of a bimodal grain microstructure. Calorimeters signals were processed within the Johnson–Mehl–Avrami formalism. This made it possible to determine the exponent of the corresponding equation, the frequency factor, and the activation energy of the grain growth, which was found to be equal to the activation energy of the vacancy migration. The reasons for the abnormal grain growth in nanocrystalline nickel were discussed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. U. Klement, U. Erb, and K. T. Aust, Nanostruct. Mater. 6, 581 (1995).

    Article  Google Scholar 

  2. K. Neishi, Z. Horita, and T. G. Langdon, Mater. Sci. Eng., A 325, 54 (2002).

    Article  Google Scholar 

  3. V. N. Chuvil’deev, V. I. Kopylov, A. V. Nokhrin, I. M. Makarov, L. M. Malashenko, and V. A. Kukareko, Fiz. Met. Metalloved. 96, 51 (2003).

    Google Scholar 

  4. A. L. Greer, Acta Metall. 30, 171 (1982).

    Article  Google Scholar 

  5. J. W. Graydon, S. J. Thorpe, and D. W. Kirk, J. Non-Cryst. Solids 175, 31 (1994).

    Article  ADS  Google Scholar 

  6. M. Avrami, J. Chem. Phys. 7, 1103 (1939).

    Article  ADS  Google Scholar 

  7. M. Avrami, J. Chem. Phys. 8, 212 (1940).

    Article  ADS  Google Scholar 

  8. D. W. Henderson, J. Non-Cryst. Solids 30, 301 (1979).

    Article  ADS  Google Scholar 

  9. J. Burke, The Kinetics of Phase Transformations in Metals (Pergamon, Oxford, 1965).

    Google Scholar 

  10. W. A. Johnson and R. F. Mehl, Trans. AIME 135, 416 (1939).

    Google Scholar 

  11. J. A. Augis and J. E. Bennet, J. Therm. Anal. 13, 283 (1978).

    Article  Google Scholar 

  12. U. Erb, Nanostruct. Mater. 6, 533 (1995).

    Article  Google Scholar 

  13. C. Cheung, F. Djuanda, U. Erb, and G. Palumbo, Nanostruct. Mater. 5, 513 (1995).

    Article  Google Scholar 

  14. I. I. Novikov and I. L. Rogel’berg, Fiz. Met. Metalloved. 6, 1132 (1958).

    Google Scholar 

  15. C. J. Smithells, Metal Reference Book (Butterworth, London, 1976; Metallurgiya, Moscow, 1980).

    Google Scholar 

  16. G. I. Wollenberger, in Physical Metallurgy, Ed. by R. W. Cahn and P. Haasen (North-Holland, Amsterdam, 1983; Metallurgiya, Moscow, 1987), Vol. 3, p. 5.

  17. S. Z. Bokshtein, Structure and Properties of Metal Alloys (Metallurgiya, Moscow, 1977) [in Russian].

    Google Scholar 

  18. Y. Estrin, G. Gottstein, and L. S. Shvindlerman, Acta Mater. 47, 3541 (1999).

    Article  Google Scholar 

  19. B. S. Bokshtein, Ch. V. Kopetskii, and L. S. Shvindlerman, Thermodynamics and Kinetics of Grain Boundaries in Metals (Metallurgiya, Moscow, 1986) [in Russian].

    Google Scholar 

  20. B. S. Bokshtein, S. Z. Bokshtein, and A. A. Zhukhovitskii, Thermodynamics and Kinetics of Diffusion in Solids (Metallurgiya, Moscow, 1974) [in Russian].

    Google Scholar 

  21. A. N. Aleshin and L. S. Shvindlerman, Deffus. Defect Data, Part A 194–199, 55 (2001).

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. N. Aleshin.

Additional information

Original Russian Text © A.N. Aleshin, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 2, pp. 401–408.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Aleshin, A.N. Kinetic constants of abnormal grain growth in nanocrystalline nickel. Phys. Solid State 58, 413–420 (2016). https://doi.org/10.1134/S1063783416020049

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063783416020049

Keywords

Navigation