Abstract
Phase transitions in binary and ternary small-volume systems have been simulated by the methods of equilibrium chemical thermodynamics. Considerable dissimilarities of the equilibrium phase compositions of the systems of macroscopic and microscopic sizes have been revealed. A change in the system’s volume is accompanied by a change in the heterogeneity region in the phase diagram. This can increase considerably the solubility of small systems and lead to the emergence of phases that are thermodynamically unstable in macroscopic systems. Such size effects have been considered by the example of phase transformations in NaCl–KCl–H2O and NaCl–KCl systems.
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References
V. B. Fedoseev and M. V. Maksimov, JETP Lett. 101 (6), 390 (2015).
V. B. Fedoseev, Phys. Solid State 57 (3), 599 (2015).
D. Hourlier and P. Perrot, Mater. Sci. Forum 653, 77 (2010).
J. Wang, A. K. Mishra, Q. Zhao, and L. Huang, J. Phys. D: Appl. Phys. 46 (25), 255303 (2013).
V. B. Fedoseev and E. N. Fedoseeva, JETP Lett. 97 (7), 408 (2013).
Yu. K. Tovbin, Russ. J. Phys. Chem. A 86 (9), 1356 (2012).
G. A. Malygin, Phys. Solid State 50 (8), 1538 (2008).
M. P. Kashchenko and V. G. Chashchina, Dynamic Theory of ?–a Martensitic Transformation in Iron-Based Alloys and Solution of the Critical Grain Size Problem (Regular and Chaotic Dynamics, Moscow, 2010) [in Russian].
E. E. Lin, Phys. Solid State 52 (1), 153 (2010).
A. I. Dolinnyi, Polym. Sci., Ser. B 47 (8), 233 (2005).
V. B. Fedoseev and E. N. Fedoseeva, Russ. J. Phys. Chem. A 88 (3), 436 (2014).
A. D. Pelton, A. Gabriel, and J. Sangster, J. Chem. Soc., Faraday Trans. 13, 1167 (1985).
R. Bahadur and L. M. Russell, Aerosol Sci. Technol. 42 (5), 369 (2008).
S. V. Karpenko, A. Kh. Kyarov, and A. I. Temrokov, Phys. Solid State 48 (3), 570 (2006).
O. G. Penyaz’kov, V. I. Saverienko, S. P. Fisenko, and Yu. A. Khodyko, Tech. Phys. 59 (8), 1196 (2014).
V. B. Kogan, V. M. Fridman, and V. V. Kafarov, Handbook on Solubility, Vol. 1: Binary Systems (Academy of Science of the USSR, Moscow, 1961) [in Russian].
S. M. Sterner, I.-M. Chou, R. T. Downs, and K. S. Pitzer, Geochim. Cosmochim. Acta 56 (6), 2295 (1992).
V. B. Fedoseev, E. N. Fedoseeva, and E. K. Titaeva, Prikl. Mekh. Tekhnol. Mashinostr. 1 (22), 96 (2013).
E. K. Titaeva and V. B. Fedoseev, Crystallogr. Rep. 59 (3), 437 (2014).
R. Montenegro and K. Landfester, Langmuir 19 (15), 5996 (2003).
C. X. Wang and G. W. Yang, Mater. Sci. Eng., R 49 (6), 157 (2005).
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Original Russian Text © V.B. Fedoseev, A.V. Shishulin, E.K. Titaeva, E.N. Fedoseeva, 2016, published in Fizika Tverdogo Tela, 2016, Vol. 58, No. 10, pp. 2020–2025.
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Fedoseev, V.B., Shishulin, A.V., Titaeva, E.K. et al. On the possibility of the formation of a NaCl–KCl solid-solution crystal from an aqueous solution at room temperature in small-volume systems. Phys. Solid State 58, 2095–2100 (2016). https://doi.org/10.1134/S1063783416100152
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DOI: https://doi.org/10.1134/S1063783416100152