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The synthesis of clusters of iron oxides in mesopores of monodisperse spherical silica particles

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Abstract

The method of obtaining nanoclusters α-Fe2O3 in the pores of monodisperse spherical particles of mesoporous silica (mSiO2) by a single impregnation of the pores with a melt of crystalline hydrate of ferric nitrate and its subsequent thermal destruction has been proposed. Fe3O4 nanoclusters are synthesized from α-Fe2O3 in the pores by reducing in thermodynamically equilibrium conditions. Then particles containing Fe3O4 were annealed in oxygen for the conversion of Fe3O4 back to α-Fe2O3. In the result, the particles with the structure of the core-shell mSiO2/Fe3O4@mSiO2/α-Fe2O3 are obtained. The composition and structure of synthesized materials as well as the field dependence of the magnetic moment on the magnetic field strength have been investigated.

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Authors and Affiliations

  1. Ioffe Institute, St. Petersburg, Russia

    E. Yu. Stovpiaga, D. A. Eurov, D. A. Kurdyukov, A. N. Smirnov, M. A. Yagovkina & V. G. Golubev

  2. ITMO University, St. Petersburg, Russia

    D. A. Kurdyukov

  3. Peter the Great St. Petersburg Polytechnic University, St. Petersburg, Russia

    V. Yu. Grigorev & V. V. Romanov

  4. Experimentelle Physik 2, Technische Universitat at Dortmund, Dortmund, Germany

    D. R. Yakovlev

Authors
  1. E. Yu. Stovpiaga
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  2. D. A. Eurov
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  3. D. A. Kurdyukov
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  4. A. N. Smirnov
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  5. M. A. Yagovkina
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  6. V. Yu. Grigorev
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  7. V. V. Romanov
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  8. D. R. Yakovlev
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  9. V. G. Golubev
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Corresponding author

Correspondence to E. Yu. Stovpiaga.

Additional information

Original Russian Text © E.Yu. Stovpiaga, D.A. Eurov, D.A. Kurdyukov, A.N. Smirnov, M.A. Yagovkina, V.Yu. Grigorev, V.V. Romanov, D.R. Yakovlev, V.G. Golubev, 2017, published in Fizika Tverdogo Tela, 2017, Vol. 59, No. 8, pp. 1598–1603.

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Stovpiaga, E.Y., Eurov, D.A., Kurdyukov, D.A. et al. The synthesis of clusters of iron oxides in mesopores of monodisperse spherical silica particles. Phys. Solid State 59, 1623–1628 (2017). https://doi.org/10.1134/S1063783417080273

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  • DOI: https://doi.org/10.1134/S1063783417080273

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