Skip to main content
Log in

Preconcentration of gold, silver, palladium, platinum, and ruthenium with organophosphorus extractants

  • Inorganic Synthesis and Industrial Inorganic Chemistry
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Extraction of noble metals in acid media with new tertiary phosphines and phosphine chalcogenides was examined. Tristyrylphosphine, tristyrylphosphine sulfide tris(2-phenylethyl)phosphine oxide, tris-(2-phenylethyl)phosphine sulfide, bis(2-phenylethyl)[2-(propylthio)ethyl]phosphine oxide, bis(2-phenylethyl)-[2-(butylthio)ethyl]phosphine oxide, and tris[2-(butylthio)ethyl]phosphine oxide were used as extractants. The suitability of the extractants for determination of Au, Ag, and Pd in rock and ore samples was elucidated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Analiticheskaya khimiya metallov platinovoi gruppy (Analytical Chemistry of Platinum Group Metals), Zolotov, Yu.A., Varshal, G.M., and Ivanov, V.M., Eds., Moscow: Editorial URSS, 2003.

    Google Scholar 

  2. Kuz’min, N.M. and Zolotov, Yu.A., Kontsentrirovanie sledov elementov (Preconcentration of Traces of Elements), Moscow: Nauka, 1988.

    Google Scholar 

  3. Ginzburg, S.I., Ezerskaya, I.A., Prokof’eva, I.V., et al., Analiticheskaya khimiya platinovykh metallov (Analytical Chemistry of Platinum Metals), Moscow: Nauka, 1972.

    Google Scholar 

  4. Douglas, S.F., J. Organomet. Chem., 2005, vol. 690, pp. 2426–2428.

    Article  Google Scholar 

  5. Zolotov, Yu.A. and Kuz’min, N.M., Ekstraktsionnoe kontsentrirovanie (Extraction Preconcentration), Moscow: Khimiya, 1971.

    Google Scholar 

  6. Zolotov, Yu.A. and Kuz’min, N.M., Kontsentrirovanie mikroelementov (Preconcentration of Trace Elements), Moscow: Khimiya, 1982.

    Google Scholar 

  7. Fishkova, N.L., Zh. Anal. Khim., 1974, vol. 29, no. 11, pp. 2121–2123.

    CAS  Google Scholar 

  8. Yudelevich, I.G. and Startseva, E.A., Atomno-absorbtsionnoe opredelenie blagorodnykh metallov (Atomic Absorption Determination of Noble Metals), Novosibirsk: Nauka, 1981.

    Google Scholar 

  9. Senise, P. and Levi, F., Anal. Chim. Acta, 1964, vol. 30, pp. 422–426.

    Article  CAS  Google Scholar 

  10. Seeverens, P.S.H., Klassen, E.J.M., and Maessen, F.J.M.J., Spectrochim. Acta, 1983, vol. 38B, no. 516, pp. 727–737.

    CAS  Google Scholar 

  11. Serebryanyi, B.L., Fishkova, N.L., Petrukhin, O.M., and Rakovskii, E.E., Zh. Prikl. Khim., 1973, vol. 28, no. 12, pp. 2333–2335.

    Google Scholar 

  12. Fishkova, N.L. and Petrikhin, O.M., Zh. Anal Khim., 1973, vol. 28, no. 4, pp. 645–647.

    CAS  Google Scholar 

  13. Petrukhin, O.M., Zolotov, Yu.A., and Izosenkova, L.A., Zh. Neorg Khim., 1971, vol. 16, no. 12, pp. 3285–3289.

    CAS  Google Scholar 

  14. Mojski, M., Talanta, 1980, vol. 27, pp. 7–10.

    Article  CAS  Google Scholar 

  15. Kryukov, S.V. and Garifzyanov, A.R., Razvedka Okhrana Nedr, 2000, no. 9, pp. 20–22.

  16. Medved’, T.Ya., Polikarpov, Yu.M., Bertina, L.E., et al., Usp. Khim., 1975, vol. 44, no. 6, pp. 1003–1006.

    CAS  Google Scholar 

  17. Busev, A.I. and Ivanov, V.M., Analiticheskaya khimiya zolota (Analytical Chemistry of Gold), Moscow: Nauka, 1973.

    Google Scholar 

  18. Pyatnitskii, I.V. and Sukhan, V.V., Analiticheskaya khimiya serebra (Analytical Chemistry of Silver), Moscow: Nauka, 1975.

    Google Scholar 

  19. Yukhin, Yu.M., Udalova, T.A., and Tsymbalist, V.G., Zh. Anal. Khim., 1985, vol. 40, no. 5, pp. 850–855.

    CAS  Google Scholar 

  20. Malysheva, S.F. and Arbuzova, S.N., Sovremennyi organicheskii sintez (Modern Organic Synthesis), Moscow: Khimiya, 2003, pp. 160–177.

    Google Scholar 

  21. Trofimov, B.A., Sukhov, B.G., Malysheva, S.F., and Gusarova, N.K., Kataliz v Prom-sti, 2006, no. 4, pp. 18–23.

  22. Arbuzova, S.N., Gusarova, N.K., and Trofimov, B.A., Arkivok, 2006, pp. 12–36.

  23. Torgov, V.G. and Khlebnikova, A.A., Zh. Anal. Khim., 1977, vol. 32, no. 5, pp. 960–963.

    CAS  Google Scholar 

  24. Khlebnikova, A.A. and Torgov, V.G., Zh. Anal. Khim., 1976, vol. 31, no. 6, pp. 1090–1093.

    CAS  Google Scholar 

  25. Men’shikov, V.I., Khlebnikova, A.A., Tsykhanskii, V.D., and Malykh, V.D., Zh. Anal. Khim., 1977, vol. 32, no. 5, pp. 954–957.

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Original Russian Text © V.I. Men’shikov, I.Yu. Voronova, O.A. Proidakova, S.F. Malysheva, N.I. Ivanova, N.A. Belogorlova, N.K. Gusarova, B.A. Trofimov, 2009, published in Zhurnal Prikladnoi Khimii, 2009, Vol. 82, No. 2, pp. 189–195.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Men’shikov, V.I., Voronova, I.Y., Proidakova, O.A. et al. Preconcentration of gold, silver, palladium, platinum, and ruthenium with organophosphorus extractants. Russ J Appl Chem 82, 183–189 (2009). https://doi.org/10.1134/S1070427209020025

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427209020025

Keywords

Navigation