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Development and synthesis of bulk and membrane catalysts based on framework phosphates and molybdates

  • Inorganic Synthesis and Industrial Inorganic Chemistry
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Abstract

The scientific principles were formulated that underlie an integrated approach to development and synthesis of bulk and membrane catalysts for methanol transformation to dimethyl ether and hydrogen which are environmentally friendly fuels. The results were summarized for studies into relationships in formation of phosphates MZr2(PO4)3 (M = Na, K, Rb, Cs, Mg0.5, Ca0.5, Sr0.5, Ba0.5, Zr0.25), Cu0.5(1+y)Fe y Zr2−y (Po4)3, molybdate phosphates Na1−y Zr2(Moo4) y (Po4)3−y , and molybdate Ni0.3Cr0.4Fe1.4(Moo4)3 with the desired structure and properties controllable by variation of their chemical composition and synthesis parameters. The surface characteristics and catalytic properties of the resulting systems and the yields of the target product formed from methanol transformations in inert and oxidizing atmospheres were analyzed in relation to the catalyst synthesis condition.

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Authors and Affiliations

  1. Lobachevky Nizhni Novgorod State University, Nizhni Novgorod, Russia

    V. I. Pet’kov & M. V. Sukhanov

  2. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia

    M. M. Ermilova, N. V. Orekhova & G. F. Tereshchenko

Authors
  1. V. I. Pet’kov
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  2. M. V. Sukhanov
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  3. M. M. Ermilova
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  4. N. V. Orekhova
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  5. G. F. Tereshchenko
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Additional information

Original Russian Text © V.I. Pet’kov, M.V. Sukhanov, M.M. Ermilova, N.V. Orekhova, G.F. Tereshchenko, 2010, published in Zhurnal Prikladnoi Khimii, 2010, Vol. 83, No. 10, pp. 1591–1601.

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Pet’kov, V.I., Sukhanov, M.V., Ermilova, M.M. et al. Development and synthesis of bulk and membrane catalysts based on framework phosphates and molybdates. Russ J Appl Chem 83, 1731–1741 (2010). https://doi.org/10.1134/S1070427210100022

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  • DOI: https://doi.org/10.1134/S1070427210100022

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