Skip to main content
Log in

Conversion of gas-condensate straight-run gasolines to high-octane gasolines over zeolite catalysts modified with metal nanopowders

  • Organic and Petrochemical Processes
  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

The acid and catalytic properties of zeolite catalysts modified with metal nanopowders (Cu, Zn, and W) were studied in the conversion of gas-condensate straight-run gasolines to high-liquid high-octane gasolines that match European standards. It was shown that the highest activity in formation of high-octane gasolines from straight-run gasolines is exhibited by H-ZKE-G zeolite catalyst modified with 1–3 wt% W nanopowders, which finding is in good agreement with the results of examination of the acid properties.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Ione, K.G., Vestn. Akad. Nauk SSSR, 1983, no. 6, pp. 75–88.

    Google Scholar 

  2. Antsiburova, E.A., Vagin, A.I., Korobitsyna, L.L., and Erofeev, V.I., in Sintez na osnove produktov neftekhimii (Synthesis Based on Petrochemical Products): Sbornik nauchnykh trudov (Coll. of Scientific Works), Novosibirsk: Nauka, 1990, pp. 300–303.

    Google Scholar 

  3. Erofeev, V.I., Antsiburova, E.A., Bodraya, N.V., and Karmadonov, L.N., in Sintez na osnove produktov neftekhimii (Synthesis Based on Petrochemical Products): Sbornik nauchnykh trudov (Coll. of Scientific Works), Novosibirsk: Nauka, 1990, pp. 304–307.

    Google Scholar 

  4. Erofeev, V.I., Vagin, A.I., Barbashin, Ya.E., et al., in Problemy khimii nefti (Problems of Petroleum Chemistry): Sbornik nauchnykh trudov (Coll. of Scientific Works), Novosibirsk: Nauka, 1992, pp. 312–314.

    Google Scholar 

  5. Korobitsyna, L.L., Vagin, A.I., and Erofeev, V.I., in Problemy khimii nefti (Problems of Petroleum Chemistry): Sbornik nauchnykh trudov (Coll. of Scientific Works), Novosibirsk: Nauka, 1992, pp. 314–316.

    Google Scholar 

  6. Minachev, Kh.M. and Dergachev, A.A., Izv. Akad. Nauk SSSR, Ser. Khim., 1993, no. 6, pp. 1018–1027.

    Google Scholar 

  7. Korobitsyna, L.L., Velichkina, L.M., Antonova, N.V., et al., Zh. Fiz. Khim., 1997, vol. 71, no. 1, pp. 60–63.

    CAS  Google Scholar 

  8. Vosmerikov, A.V., Velichkina, L.M., Korobitsyna, L.L., et al., Neftepererab. Neftekhim., 1997, no. 2, pp. 16–19.

    Google Scholar 

  9. Barbashin, Ya.E, Ryabov, Yu.V., Vosmerikov, A.V., et al., Neftepererab. Neftekhim., 1998, no. 8, pp. 17–21.

    Google Scholar 

  10. Erofeev, V.I., Adyaeva, L.V., and Ryabov, Yu.V., Zh. Prikl. Khim., 2001, vol. 74, no. 2, pp. 231–234.

    Google Scholar 

  11. Erofeev, V.I., Adyaeva, L.V., and Kukharenko, O.A, Zh. Prikl. Khim., 2001, vol. 74, no. 11, pp. 1791–1794.

    Google Scholar 

  12. Erofeev, V.I. and Adyaeva, L.V., Zh. Prikl. Khim., 2003, vol. 76, no. 7, pp. 1116–1121.

    Google Scholar 

  13. RF Patent 2446882.

  14. RF Patent 2446883.

  15. Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry, and Use, New York: Wiley, 1973.

    Google Scholar 

  16. Erofeev, V.I., Medvedev, A.S., Koval’, L.M., et al., Zh. Prikl. Khim., 2011, vol. 84, no. 10, pp. 1668–1674.

    Google Scholar 

  17. Topsoe, N.-Y. and Pederson, K., J. Catal., 1981, vol. 70, no. 1, pp. 41–52.

    Article  CAS  Google Scholar 

  18. Kazanskii, V.B., Minachev, Kh.M., Nefedov, B.K., et al., Kinet. Katal., 1983, vol. 24, no. 3, pp. 679–682.

    CAS  Google Scholar 

  19. Kustov, L.M., Zholobenko, V.L., and Kazanskii, V.B., Kinet. Katal., 1988, vol. 29, no. 4, pp. 928–934.

    CAS  Google Scholar 

  20. Choudhary, V.R., Panjala, D., and Banerjee, S., Appl. Catal., A: General, 2002, vol. 231, pp. 243–251.

    Article  CAS  Google Scholar 

  21. Jong, S.J. and Cheng, S., Appl. Catal., A.: General, 1995, vol. 126, no. 1, pp. 51–66.

    Article  CAS  Google Scholar 

  22. Choudhary, V.R., Mantri, K., and Sivadinarayana, C., Microporous Mesoporous Mater., 2000, vol. 37, p. 1.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. I. Erofeev.

Additional information

Original Russian Text © V.I. Erofeev, A.S. Medvedev, I.S. Khomyakov, E.V. Erofeeva, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 7, pp. 1044–1051.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Erofeev, V.I., Medvedev, A.S., Khomyakov, I.S. et al. Conversion of gas-condensate straight-run gasolines to high-octane gasolines over zeolite catalysts modified with metal nanopowders. Russ J Appl Chem 86, 979–985 (2013). https://doi.org/10.1134/S1070427213070069

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070427213070069

Keywords

Navigation