Abstract
The acid and catalytic properties of zeolite catalysts modified with metal nanopowders (Cu, Zn, and W) were studied in the conversion of gas-condensate straight-run gasolines to high-liquid high-octane gasolines that match European standards. It was shown that the highest activity in formation of high-octane gasolines from straight-run gasolines is exhibited by H-ZKE-G zeolite catalyst modified with 1–3 wt% W nanopowders, which finding is in good agreement with the results of examination of the acid properties.
Similar content being viewed by others
References
Ione, K.G., Vestn. Akad. Nauk SSSR, 1983, no. 6, pp. 75–88.
Antsiburova, E.A., Vagin, A.I., Korobitsyna, L.L., and Erofeev, V.I., in Sintez na osnove produktov neftekhimii (Synthesis Based on Petrochemical Products): Sbornik nauchnykh trudov (Coll. of Scientific Works), Novosibirsk: Nauka, 1990, pp. 300–303.
Erofeev, V.I., Antsiburova, E.A., Bodraya, N.V., and Karmadonov, L.N., in Sintez na osnove produktov neftekhimii (Synthesis Based on Petrochemical Products): Sbornik nauchnykh trudov (Coll. of Scientific Works), Novosibirsk: Nauka, 1990, pp. 304–307.
Erofeev, V.I., Vagin, A.I., Barbashin, Ya.E., et al., in Problemy khimii nefti (Problems of Petroleum Chemistry): Sbornik nauchnykh trudov (Coll. of Scientific Works), Novosibirsk: Nauka, 1992, pp. 312–314.
Korobitsyna, L.L., Vagin, A.I., and Erofeev, V.I., in Problemy khimii nefti (Problems of Petroleum Chemistry): Sbornik nauchnykh trudov (Coll. of Scientific Works), Novosibirsk: Nauka, 1992, pp. 314–316.
Minachev, Kh.M. and Dergachev, A.A., Izv. Akad. Nauk SSSR, Ser. Khim., 1993, no. 6, pp. 1018–1027.
Korobitsyna, L.L., Velichkina, L.M., Antonova, N.V., et al., Zh. Fiz. Khim., 1997, vol. 71, no. 1, pp. 60–63.
Vosmerikov, A.V., Velichkina, L.M., Korobitsyna, L.L., et al., Neftepererab. Neftekhim., 1997, no. 2, pp. 16–19.
Barbashin, Ya.E, Ryabov, Yu.V., Vosmerikov, A.V., et al., Neftepererab. Neftekhim., 1998, no. 8, pp. 17–21.
Erofeev, V.I., Adyaeva, L.V., and Ryabov, Yu.V., Zh. Prikl. Khim., 2001, vol. 74, no. 2, pp. 231–234.
Erofeev, V.I., Adyaeva, L.V., and Kukharenko, O.A, Zh. Prikl. Khim., 2001, vol. 74, no. 11, pp. 1791–1794.
Erofeev, V.I. and Adyaeva, L.V., Zh. Prikl. Khim., 2003, vol. 76, no. 7, pp. 1116–1121.
RF Patent 2446882.
RF Patent 2446883.
Breck, D.W., Zeolite Molecular Sieves: Structure, Chemistry, and Use, New York: Wiley, 1973.
Erofeev, V.I., Medvedev, A.S., Koval’, L.M., et al., Zh. Prikl. Khim., 2011, vol. 84, no. 10, pp. 1668–1674.
Topsoe, N.-Y. and Pederson, K., J. Catal., 1981, vol. 70, no. 1, pp. 41–52.
Kazanskii, V.B., Minachev, Kh.M., Nefedov, B.K., et al., Kinet. Katal., 1983, vol. 24, no. 3, pp. 679–682.
Kustov, L.M., Zholobenko, V.L., and Kazanskii, V.B., Kinet. Katal., 1988, vol. 29, no. 4, pp. 928–934.
Choudhary, V.R., Panjala, D., and Banerjee, S., Appl. Catal., A: General, 2002, vol. 231, pp. 243–251.
Jong, S.J. and Cheng, S., Appl. Catal., A.: General, 1995, vol. 126, no. 1, pp. 51–66.
Choudhary, V.R., Mantri, K., and Sivadinarayana, C., Microporous Mesoporous Mater., 2000, vol. 37, p. 1.
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © V.I. Erofeev, A.S. Medvedev, I.S. Khomyakov, E.V. Erofeeva, 2013, published in Zhurnal Prikladnoi Khimii, 2013, Vol. 86, No. 7, pp. 1044–1051.
Rights and permissions
About this article
Cite this article
Erofeev, V.I., Medvedev, A.S., Khomyakov, I.S. et al. Conversion of gas-condensate straight-run gasolines to high-octane gasolines over zeolite catalysts modified with metal nanopowders. Russ J Appl Chem 86, 979–985 (2013). https://doi.org/10.1134/S1070427213070069
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S1070427213070069