Abstract
The effect of the template on the physicochemical properties of zeolitic catalysts and on the yield and selectivity of formation of aromatic hydrocarbons in conversion of the propane–butane fraction was examined. The zeolitic catalyst sample synthesized with an alcohol fraction as template is characterized by the highest values of the acid site concentration, adsorption capacity, micropore volume, and specific surface area. Therefore, this catalyst ensures the highest, compared to the other samples, conversion of the propane–butane fraction and yield of aromatic hydrocarbons.
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References
Nefedov, B.K., Katal. Prom–sti, 2001, no. 1, pp. 48–56.
Parmon, V.N. and Noskov, A.S., Katal. Prom–sti, 2001, no. 1, pp. 6–17.
Rigutto, M.S., van Veen, R., and Laurent, H., Stud. Surf. Sci. Catal., 2007, vol. 168, pp. 855–913.
Erofeev, V I., Khomyakov, I.S., and Egorova, L.A., Theor. Found. Chem. Eng., 2014, vol. 48, no. 1, pp. 71–76.
RF Patent 2236289, Publ. 2004.
RF Patent 2312063, Publ. 2007.
RF Patent 2313486, Publ. 2007.
Vigdergauz, M.S., Gazovaya khromatografiya kak metod issledovaniya nefti (Gas Chromatography as a Method for Studying Oil), Moscow: Nauka, 1973. 256 c.
Stepanov, V.G., Mastikhin, V.M., and Ione, K.G., Izv. Akad. Nauk SSSR, Ser. Khim., 1982, no. 3, pp. 619–625.
Viswanadham, N. and Kamble, R., Catal. Today, 2009, vol. 141, pp. 182–186.
Karnaukhov, A.P., Adsorbtsiya. Tekstura dispersnykh i poristykh materialov (Adsorption. Texture of Disperse and Porous Materials), Novosibirsk: Nauka, 1999.
Koval, L.M., Goivoronskaya, Yu. I., Potudanskaya, M.N., et al., Russ. J. Phys. Chem. A, 2009, vol. 83, no. 5, pp. 741–744.
Jin, F. and Li, Y., Catal. Today, 2008, nos. 1–2, pp. 1–7.
Bin Xu, Carsten Sievers, 2006, vol. 244, no. 2, pp. 163–168.
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Original Russian Text © G.S. Bozhenkova, I.S. Khomyakov, T.A. Gerasina, 2016, published in Zhurnal Prikladnoi Khimii, 2016, Vol. 89, No. 2, pp. 230-234.
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Bozhenkova, G.S., Khomyakov, I.S. & Gerasina, T.A. Pore structure and acid properties of high-silica zeolites synthesized with different templates and their catalytic performance in conversion of the propane–butane fraction. Russ J Appl Chem 89, 238–242 (2016). https://doi.org/10.1134/S1070427216020129
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DOI: https://doi.org/10.1134/S1070427216020129