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A Study of a Novel Nanocomposite Material Based on Reduced Graphene Oxide and Poly(o-Phenylenediamine)

  • Nanoscale and Nanostructured Materials and Coatings
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Abstract

The formation of a nanocomposite coating based on reduced graphene oxide (RGO) and poly(o-phenylenediamine) (PPD) in the chemical reaction of graphene oxide (GO) and o-phenylenediamine (OPD) has been studied by cyclic voltammetry (CVA), scanning electron microscopy (SEM), and X-ray photoelectron spectroscopy (XPS). It has been shown that the action of cyclic polarization provides a more uniform structure of the nanocomposite films (decrease in the corrugation effect). In addition, it has been found that the polarization of GO films containing the OPD monomer distributed inside to the PPD synthesis potentials leads to the formation of uniformly distributed globular structures, which most probably correspond to a polymer electrochemically synthesized in the space between the GO nanosheets.

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Authors and Affiliations

  1. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, 119071, Russia

    E. Yu. Pisarevskaya, Yu. B. Makarychev & G. P. Girina

  2. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Moscow oblast, Chernogolovka, 142432, Russia

    N. N. Dremova & O. N. Efimov

Authors
  1. E. Yu. Pisarevskaya
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  2. Yu. B. Makarychev
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  3. N. N. Dremova
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  4. G. P. Girina
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  5. O. N. Efimov
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Corresponding author

Correspondence to E. Yu. Pisarevskaya.

Additional information

Original Russian Text © E.Yu. Pisarevskaya, Yu.B. Makarychev, N.N. Dremova, G.P. Girina, O.N. Efimov, 2018, published in Fizikokhimiya Poverkhnosti i Zashchita Materialov, 2018, Vol. 54, No. 3, pp. 251–261.

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Pisarevskaya, E.Y., Makarychev, Y.B., Dremova, N.N. et al. A Study of a Novel Nanocomposite Material Based on Reduced Graphene Oxide and Poly(o-Phenylenediamine). Prot Met Phys Chem Surf 54, 393–401 (2018). https://doi.org/10.1134/S2070205118030127

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  • DOI: https://doi.org/10.1134/S2070205118030127

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