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Hydrogenation of phenols in ionic liquids on rhodium nanoparticles

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Abstract

A new catalyst system based on rhodium nanoparticles stabilized by polyacrylic acid have been suggested for the hydrogenation of phenols in ionic liquids. It has been shown that high near-quantitative yields of reaction products are achieved in ionic liquids containing a tetraalkylammonium cation. By the TEM and XPS techniques it has been revealed that the use of ionic liquids substantially decreases the particle size and reduces the aggregation of nanoparticles through the inclusion of the ionic liquid cations into the surface layer along with polyacrylic acid.

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References

  1. C. Zhao, J. He, A. A. Lemonidou, X. Li, J. A. Lercher, J. Catal. 280, 8 (2011).

    Article  CAS  Google Scholar 

  2. N. Yan, Y. Yuan, R. Dykeman, Y. Kou, P. J. Dyson, Angew. Chem. Int. Ed. 49, 5549 (2010).

    Article  CAS  Google Scholar 

  3. G. Neri, A. M. Visco, A. Donato, C. Milone, M. Malentacchi, G. Gubitosa, Appl. Catal. A: Gen. 110, 49 (1994).

    Article  CAS  Google Scholar 

  4. D. V. Sokol’skii and N. I. Popova, Zh. Obshch. Khim. (1975).

    Google Scholar 

  5. Yu. S. Spagovskii, M. M. Strelets, and V. V. Borisov, (Izd. SO AN SSSR, Novosibirsk, 1973) [in Russian].

  6. S. Watanabe and V. Arunajatesan, Top. Catal. 53, 1150 (2010).

    Article  CAS  Google Scholar 

  7. A. A. Krichko, N. I. Artemova, A. V. Artemov, and Yu. I. Petrov, Kinet. Katal. 29, 155 (1988).

    CAS  Google Scholar 

  8. J. Tobicik and L. Cerveny, J. Mol. Catal. A: Chem. 194, 249 (2003).

    Article  CAS  Google Scholar 

  9. S. Velu, M. P. Kapoor, S. Inagaki, and K. Suzuki, Appl. Catal. A: Gen. 245, 317 (2003).

    Article  CAS  Google Scholar 

  10. M. Chatterjee, H. Kawanami, M. Sato, et al., Adv. Synth. Catal. 351, 1912 (2009).

    Article  CAS  Google Scholar 

  11. C. Zhao, H. Wang, N. Yan, et al., J. Catal. 250, 33 (2007).

    Article  CAS  Google Scholar 

  12. X. Yang, N. Yan, Z. Fei, et al., Inorg. Chem. 47, 7444 (2008).

    Article  CAS  Google Scholar 

  13. G. S. Fonseca, A. P. Umpierre, P. F. P. Fichtner, et al., Chem. Eur. J. 9, 3263 (2003).

    Article  CAS  Google Scholar 

  14. E. A. Karakhanov, V. S. Pshezhetskii, and A. G. Dedov, Dokl. Akad. Nauk SSSR (1984).

    Google Scholar 

  15. E. A. Karakhanov, A. G. Dedov, A. S. Loktev, and V. S. Pshezhetskii, USSR Inventor’s Certificate No. 1 002 292; Byull. Izobret., No. 9 (1983).

    Google Scholar 

  16. J. S. Wilkes, J. A. Levisky, R. A. Wilson, and C. L. Hussey, Inorg. Chem. 21, 1263 (1982).

    Article  CAS  Google Scholar 

  17. P. A. Z. Suarez, J. E. L. Dullius, S. Einloft, et al., Polyhedron 15, 1219 (1996).

    Article  Google Scholar 

  18. T. Floris, P. Kluson, L. Bartek, and H. Pelantova, Appl. Catal. A: Gen. 366, 160 (2009).

    Article  CAS  Google Scholar 

  19. A. M. Dennis, R. A. Howard, K. M. Kadish, et al., Inorg. Chim. Acta 44, 139 (1980).

    Article  Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, Moscow, 119991, Russia

    A. L. Maksimov, S. N. Kuklin, Yu. S. Kardasheva & E. A. Karakhanov

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  1. A. L. Maksimov
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  2. S. N. Kuklin
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  3. Yu. S. Kardasheva
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  4. E. A. Karakhanov
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Corresponding author

Correspondence to Yu. S. Kardasheva.

Additional information

Original Russian Text © A.L. Maksimov, S.N. Kuklin, Yu.S. Kardasheva, E.A. Karakhanov, 2013, published in Neftekhimiya, 2013, Vol. 53, No. 3, pp. 177–184.

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Maksimov, A.L., Kuklin, S.N., Kardasheva, Y.S. et al. Hydrogenation of phenols in ionic liquids on rhodium nanoparticles. Pet. Chem. 53, 157–163 (2013). https://doi.org/10.1134/S0965544113030043

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  • DOI: https://doi.org/10.1134/S0965544113030043

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