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Monolithic polymeric sorbents for high-performance chromatography of synthetic polymers

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Abstract

A number of macroporous monolithic materials based on copolymers of butyl methacrylate or lauryl methacrylate with ethylene glycol dimethacrylate is obtained via thermal free-radical polymerization. The effect of polymerization conditions on pore parameters of the synthesized sorbents is studied. Polymer stationary phases obtained for the efficient analysis of synthetic polymers are tested for the separation of a multicomponent mixture containing polystyrene samples of various molecular masses.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol’shoi pr. 31 (V.O.), St. Petersburg, 199004, Russia

    E. G. Vlakh, E. F. Maksimova & T. B. Tennikova

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  1. E. G. Vlakh
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  2. E. F. Maksimova
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  3. T. B. Tennikova
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Correspondence to T. B. Tennikova.

Additional information

Original Russian Text © E.G. Vlakh, E.F. Maksimova, T.B. Tennikova, 2013, published in Russian in Vysokomolekulyarnye Soedineniya, Ser. B, 2013, Vol. 55, No. 2, pp. 209–217.

This study was supported by the Russian Foundation for Basic Research (project no. 11-03-00829), Program of the Presidium of the Russian Academy of Sciences no. 7, and the personal grant U.M.N.I.K (Participant of the Youth Research and Innovation. Competition) received by E.F. Maksimova in 2011 from the Foundation for Support of Small Companies in High-Technology Areas.

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Vlakh, E.G., Maksimova, E.F. & Tennikova, T.B. Monolithic polymeric sorbents for high-performance chromatography of synthetic polymers. Polym. Sci. Ser. B 55, 55–62 (2013). https://doi.org/10.1134/S1560090413020061

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  • DOI: https://doi.org/10.1134/S1560090413020061

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